8,13-Dimethylicosanedioic acid | 78352-84-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 8,13-Dimethylicosanedioic acid
• CAS: 78352-84-8
• 化学式: C₂₂H₄₂O₄
• 分子量: 370.6
• InChiKey: IQWKYRKBHFUUKH-UHFFFAOYSA-N

物化性质

• 沸点：
  643.5±55.0 °C(Predicted)
• 密度：
  1?+-.0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  26
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  8,13-Dimethylicosanedioic acid 、 正丁醇 生成 dibutyl 8,13-dimethylicosanedioate
  参考文献：
  名称：

  KATAFUCHI, TADASHI;MITAZAKI, HIROO;SHIDO, SEIICHI;TOMARI, YASUNORI;ONODER+

  摘要：

  DOI：

文献信息

• METHOD FOR PREPARING QUATERNARY PHOSPHONIUM SALTS
  申请人：Microvast Power Systems Co.,Ltd.

  公开号：US20150166587A1

  公开（公告）日：2015-06-18

  A two-step pathway for preparing high pure quaternary phosphonium salts is disclosed. In the first step, hydrogen phosphide (PH 3 ) or a higher phophine reacts with a protonic compound to produce a phosphonium salt, which then reacts with a carbonic acid diester to produce a quaternary phosphonium salt in the second step. On one hand, hydrogen phosphide (PH 3 ) and higher phophines, including primary phosphines, secondary phosphines, and tertiary phosphines, after neutralization with protonic compound, become sufficiently reactive and can be alkylated by carbonic acid diester to form quaternary phosphonium cations. On the other hand, as an anion-exchange procedure is completely avoided, the process not only gives quaternary phosphonium salts of high purity, but also gives people freedom to design the cation and the anion of a quaternary phosphonium salt synchronously by choosing a preferred phosphine and a protonic compound that can supply a desired anion.

  揭示了一种制备高纯度四元磷铵盐的两步途径。在第一步中，氢磷化物（PH3）或更高的磷化物与质子化合物发生反应，产生磷铵盐，然后在第二步中与碳酸二酯发生反应，产生四元磷铵盐。一方面，氢磷化物（PH3）和更高的磷化物，包括一次磷化物、二次磷化物和三次磷化物，在与质子化合物中和后变得足够活性，可以被碳酸二酯烷基化形成四元磷铵阳离子。另一方面，由于完全避免了阴离子交换程序，该过程不仅提供高纯度的四元磷铵盐，还使人们可以通过选择理想的磷化物和可以提供所需阴离子的质子化合物，同时设计四元磷铵盐的阳离子和阴离子。
• Carboxylic acid glycidyl esters, process for their preparation and their use in resin compositions
  申请人：OKAMURA OIL MILL LIMITED

  公开号：EP0028024A1

  公开（公告）日：1981-05-06

  polycarboxylic acid glycidyl ester represented by the formula wherein -R- is -(CH2)8-, -CH2-CH = CH-(CH2)2-CH = CH-CH2-. or A process for the preparation of said esters, and their use in resin compositons.

  聚羧酸缩水甘油酯，由式（其中-R-是-(CH2)8-、- -CH = CH-( )2-CH = CH- -）代表。 或 制备上述酯类的工艺及其在树脂组合物中的用途。
• Process for producing quaternary salts
  申请人：MITSUBISHI PETROCHEMICAL CO., LTD.

  公开号：EP0291074A2

  公开（公告）日：1988-11-17

  A process for producing quaternary salts of high purity is disclosed, comprising reacting a tertiary amine or phosphine with a carbonic acid diester to form a correspond­ing quaternary carbonate and further mixing it with an acid to perform decarboxylation. The quaternary salts thus ob­tained are useful compounds which can be used in wide fields as various catalysts, electrolytes, additives, medicaments, etc.

  本发明公开了一种生产高纯度季盐的工艺，包括将叔胺或膦与碳酸二酯反应生成相应的季碳酸盐，并进一步与酸混合进行脱羧反应。由此获得的季盐是有用的化合物，可广泛用作各种催化剂、电解质、添加剂、药物等。
• Gel composition and a use thereof
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2808315A1

  公开（公告）日：2014-12-03

  The first aspect in the present invention provides a composition comprising (A) 100 parts by mass of an organoalkoxysilane represented by the following formula (1) and/or a compound obtained by partial hydrolysis and condensation of said organoalkoxysilane: R1aSi(OR2)4-a ... (1), (B) 0.3 to 20 parts by mass of an aluminum dicarboxylate represented by the following formula (2) : (R3COO)2Al(OH)...(2), and (C) 0.3 to 20 parts by mass of an aliphatic acid having 6 to 24 carbon atoms. The second aspect in the present invention provides a composition comprising the aforesaid components (A), (B) and (C) and further (D) 0.01 to 10 parts by mass of a dicarboxylic acid having 6 to 30 carbon atoms. Further, the present invention provides a method for making a porous material less water-absorptive by applying the composition to a surface of said porous material and a porous material modified by the method.

  本发明的第一方面提供了一种组合物，该组合物包含(A) 100 份（按质量）由下式 (1) 代表的有机烷氧基硅烷和/或由所述有机烷氧基硅烷部分水解和缩合得到的化合物：R1aSi(OR2)4-a......(1)，(B) 0.3 至 20 份（质量份数）由下式(2)代表的二羧酸铝：(R3COO)2Al(OH)......(2)，和(C) 0.3 至 20 份（质量份数）具有 6 至 24 个碳原子的脂肪族酸。本发明的第二个方面提供了一种组合物，该组合物包含上述组分（A）、（B）和（C），以及（D）0.01 至 10 份（按重量计）具有 6 至 30 个碳原子的二羧酸。此外，本发明还提供了一种使多孔材料吸水性降低的方法，即在所述多孔材料和经该方法改性的多孔材料表面涂抹该组合物。
• HYDROCARBYL SOLUBLE QUATERNARY AMMONIUM CARBOXYLATES AND FUEL COMPOSITIONS CONTAINING THEM
  申请人：Afton Chemical Corporation

  公开号：EP2960319A2

  公开（公告）日：2015-12-30

  A fuel additive composition, fuel composition, method of improving the injector performance of a fuel injected engine, method for preventing or cleaning up deposits in an engine or fuel system, method of reducing wear in a fuel system of an engine, and method of improving the demulsibility of a fuel composition. The fuel composition includes from about 5 to about 300 ppm by weight based on a total weight of the fuel composition of a hydrocarbyl soluble quaternary ammonium carboxylate derived from a quaternary ammonium carbonate and an organic acid.

  一种燃料添加剂组合物、燃料组合物、改善喷油发动机喷油器性能的方法、防止或清理发动机或燃料系统中沉积物的方法、减少发动机燃料系统磨损的方法以及改善燃料组合物反乳化性的方法。以燃料组合物的总重量为基准，燃料组合物包括约 5 至约 300 ppm（按重量计）的烃基可溶性季铵羧酸盐，该季铵羧酸盐由季铵碳酸盐和有机酸衍生而来。