2-己基癸基4-羟基苯甲酸酯 | 148348-12-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-己基癸基4-羟基苯甲酸酯
• 英文名称: 2-hexyldecyl 4-hydroxybenzoate
• 英文别名: 2-Hexyldecyl p-hydroxybenzoate
• CAS: 148348-12-3
• 化学式: C₂₃H₃₈O₃
• 分子量: 362.553
• InChiKey: AWTUIOQHXHBRDW-UHFFFAOYSA-N

物化性质

• 沸点：
  471.9±18.0 °C(Predicted)
• 密度：
  0.970±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  26
• 可旋转键数：
  16
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4,7-二溴-5,6-二氟-苯并噻二唑 、 2-己基癸基4-羟基苯甲酸酯 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以96 %的产率得到4,7-dibromo-5,6-di(4-carbo(2-hexyldecyloxy)phenoxy)benzothiadiazole
  参考文献：
  名称：

  [EN] DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS DISUBSTITUTED WITH THIENOTHIOPHENE GROUPS
  [FR] COMPOSÉS DIARYLOXYBENZOHÉTÉRODIAZOLE DI-SUBSTITUÉS PAR DES GROUPES THIÉNOTHIOPHÈNE

  摘要：

  Diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I): wherein: - Z represents a sulfur atom, an oxygen atom, a selenium atom; or a NR5group wherein R5is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, or from aryl groups optionally substituted; - R1and R2, identical to or different from each other, represent a hydrogen atom; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, cycloalkyl groups optionally substituted, aryl groups optionally substituted, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted, -COOR6groups wherein R6is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, or is a cyano group; - R3and R4, identical to or different from each other, represent a hydrogen atom; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted, -COOR7or -OCOR7groups wherein R7is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, thioether groups -R8-S-R9wherein R8and R9, identical to or different from each other, are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing 74 heteroatoms; - A represents an electron acceptor group having general formula (II): wherein X1and X2, identical to or different from each other, represent a hydrogen atom, or a halogen atom such as, for example, chlorine, fluorine, bromine, preferably chlorine, fluorine; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted; or are selected from -COOR10ester groups wherein R10is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted. Said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used as an electron acceptor compound in organic photovoltaic devices (or solar devices) selected, for example, from binary, ternary, quaternary, organic photovoltaic cells (or solar cells), having both simple and tandem architecture, organic photovoltaic modules (or solar modules), both on rigid support and on flexible support. Furthermore, said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used in perovskite-based photovoltaic cells (or solar cells) in the layer based on electron transport material ("Electron Transport Layer" - ETL). Moreover, said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used in the construction of organic thin film transistors (OTFTs), or of organic field effect transistors (OFETs).

  公开号：

  WO2023105475A1
• 作为产物：
  描述：

  1-溴-2-己基癸烷 、 对羟基苯甲酸 在 potassium hydrogencarbonate 、 potassium iodide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以66 %的产率得到2-己基癸基4-羟基苯甲酸酯
  参考文献：
  名称：

  [EN] DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS DISUBSTITUTED WITH THIENOTHIOPHENE GROUPS
  [FR] COMPOSÉS DIARYLOXYBENZOHÉTÉRODIAZOLE DI-SUBSTITUÉS PAR DES GROUPES THIÉNOTHIOPHÈNE

  摘要：

  Diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I): wherein: - Z represents a sulfur atom, an oxygen atom, a selenium atom; or a NR5group wherein R5is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, or from aryl groups optionally substituted; - R1and R2, identical to or different from each other, represent a hydrogen atom; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, cycloalkyl groups optionally substituted, aryl groups optionally substituted, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted, -COOR6groups wherein R6is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, or is a cyano group; - R3and R4, identical to or different from each other, represent a hydrogen atom; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted, -COOR7or -OCOR7groups wherein R7is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, thioether groups -R8-S-R9wherein R8and R9, identical to or different from each other, are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing 74 heteroatoms; - A represents an electron acceptor group having general formula (II): wherein X1and X2, identical to or different from each other, represent a hydrogen atom, or a halogen atom such as, for example, chlorine, fluorine, bromine, preferably chlorine, fluorine; or are selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted; or are selected from -COOR10ester groups wherein R10is selected from C1-C30, preferably C1-C20, linear or branched alkyl groups, optionally containing heteroatoms, C1-C30, preferably C1-C20, linear or branched alkoxyl groups, optionally substituted. Said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used as an electron acceptor compound in organic photovoltaic devices (or solar devices) selected, for example, from binary, ternary, quaternary, organic photovoltaic cells (or solar cells), having both simple and tandem architecture, organic photovoltaic modules (or solar modules), both on rigid support and on flexible support. Furthermore, said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used in perovskite-based photovoltaic cells (or solar cells) in the layer based on electron transport material ("Electron Transport Layer" - ETL). Moreover, said diaryloxybenzoheterodiazole compound disubstituted with thienothiophene groups having general formula (I) can be advantageously used in the construction of organic thin film transistors (OTFTs), or of organic field effect transistors (OFETs).

  公开号：

  WO2023105475A1

文献信息

• Thermoplastic resin composition
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0658602A1

  公开（公告）日：1995-06-21

  A thermoplastic resin composition comprising, (A) 5-90 parts by weight of a polyphenylene ether resin and (B) 95-10 parts by weight of a polyamide resin, and per 100 parts by weight of the sum of (A) and (B), (C) 0.01-30 parts by weight of a mutual compatibilizer, (D) 0.1-100 parts by weight of a plasticizer which gives elasticity to the polyamide and (E) 0-100 parts by weight of a rubber-like material.

  一种热塑性树脂组合物，包括：(A)5-90 重量份的聚苯醚树脂；(B)95-10 重量份的聚酰胺树脂；以及每 100 重量份的(A)和(B)之和；(C)0.01-30 重量份的互容剂；(D)0.1-100 重量份的增塑剂，使聚酰胺具有弹性；以及(E)0-100 重量份的类橡胶材料。
• Hydraulic or pneumatic device comprising tube comprising polyamide resin
  申请人：Ube Industries, Ltd.

  公开号：EP1251148A1

  公开（公告）日：2002-10-23

  A hydraulic or pneumatic device is described, which comprises a tube comprising a polyamide resin composition comprising (A) from 70 to 97% by weight, based on the weight of the polyamide resin composition, of a polyamide resin and (B) from 3 to 30% by weight, based on the weight of the polyamide resin composition, of a plasticizer comprising an ester of p- and/or o-hydroxybenzoic acid with a C12-C22 aliphatic alcohol having a branched chain and a component comprising a rubber compound comprising a polar rubber as a main component, and which exhibits a high reliability over an extended period of time.

  本发明描述了一种液压或气动装置，该装置包括一个由聚酰胺树脂组合物 组成的管子，聚酰胺树脂组合物包括(A)按聚酰胺树脂组合物重量计，70%至 97% 的聚酰胺树脂和(B)按聚酰胺树脂组合物重量计，3%至 30%的增塑剂，增塑剂包括对-和/或邻-羟基苯甲酸与具有支链的 C12-C22 脂肪醇的酯、增塑剂，包括对羟基和/或邻羟基苯甲酸与具有支链的 C12-C22 脂肪醇的酯，以及由极性橡胶作为主要成分的橡胶复合物组成的组分，该增塑剂在较长时间内表现出较高的可靠性。
• Staubarme, pulverförmige Flammschutzmittelzusammensetzung, Verfahren zu deren Herstellung und deren Verwendung, sowie flammgeschützte Polymerformmassen
  申请人：Clariant GmbH

  公开号：EP1396521A1

  公开（公告）日：2004-03-10

  Die Erfindung betrifft eine staubarme, pulverförmige Flammschutzmittelzusammensetzung aus einer phosphororganischer Flammschutzkomponente und mindestens einem Staubreduktionsadditiv, ein Verfahren zur Herstellung solcher Flammschutzmittelzusammensetzungen und Polymer-Formmassen, die solche Flammschutzmittelzusammensetzungen enthalten.

  本发明涉及一种由有机磷阻燃剂成分和至少一种降尘添加剂组成的低尘粉状阻燃组合物、制备这种阻燃组合物的工艺以及含有这种阻燃组合物的聚合物模塑组合物。
• Kompaktierte Flammschutzmittelzusammensetzung
  申请人：Clariant GmbH

  公开号：EP1396523A1

  公开（公告）日：2004-03-10

  Die Erfindung betrifft eine kompaktierte Flammschutzmittelzusammensetzung enthaltend eine phosphororganische Flammschutzkomponente, hergestellt durch Kompaktieren einer phosphororganischen Flammschutzkomponente mit oder ohne Kompaktierhilfsmittel, ein Verfahren zur Herstellung solcher Flammschutzmittelzusammensetzungen und Polymer-Formmassen, die solche Flammschutzmittelzusammensetzungen enthalten.

  本发明涉及一种包含有机磷阻燃剂成分的压实阻燃组合物（通过压实有机磷阻燃剂成分制备）、制备此类阻燃组合物的工艺以及包含此类阻燃组合物的聚合物模塑组合物。
• Granulare Flammschutzmittelzusammensetzung
  申请人：Clariant GmbH

  公开号：EP1396522A1

  公开（公告）日：2004-03-10

  Die Erfindung betrifft eine granulare Flammschutzmittelzusammensetzung aus einer phosphororganischer Flammschutzkomponente und einem Binder, ein Verfahren zur Herstellung solcher Flammschutzmittelzusammensetzungen und Polymer-Formmassen, die solche Flammschutzmittelzusammensetzungen enthalten.

  本发明涉及一种由有机磷阻燃剂成分和粘合剂组成的颗粒状阻燃组合物、制备这种阻燃组合物的工艺以及含有这种阻燃组合物的聚合物模塑组合物。