tris-triphenylphosphine copper(I) iodide | 15709-82-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris-triphenylphosphine copper(I) iodide
• 英文别名: Cu(I)(PPh3)3；[Cu(triphenylphosphine)₃I]；copper(1+);triphenylphosphane;iodide
• CAS: 15709-82-7
• 化学式: C₅₄H₄₅CuIP₃
• 分子量: 977.323
• InChiKey: GQMWLWIPQUJUAY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  11.22
• 重原子数：
  59
• 可旋转键数：
  9
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-巯基噻唑啉 、 tris-triphenylphosphine copper(I) iodide 以 苯 为溶剂， 以72%的产率得到(thiazolidin-2-ylidene-l4-sulfaneyl)bis(triphenyl-l5-phosphaneyl)copper(IV) iodide
  参考文献：
  名称：

  Substitution reactions of [CuI(PPh3)3X] (X = Cl, Br or I) with N,N-dimethyl-N′-phenylthiourea (dmptH), N,N-dibutyl-N′-phenylthiourea (dbptH) and 1,3-thiazolidine-2-thione (tzdtH)

  摘要：

  Reactions of [Cu(PPh3)3X] with the titled ligands yield [GRAPHICS] The complexes have been characterized on the basis of analytical, IR, electronic (UV-vis), H-1, P-31 and C-13 NMR, conductivity and magnetic measurements. In all cases there is a distorted tetrahedral environment around copper(I), and the ligands (LH) bind through the thione sulphur atom to copper(I).

  DOI：

  10.1016/s0277-5387(00)83167-8
• 作为产物：
  描述：

  copper(l) iodide 在 三苯基膦 作用下， 以 二氯甲烷 为溶剂， 生成 tris-triphenylphosphine copper(I) iodide
  参考文献：
  名称：

  Fife, Dennis J.; Moore, William M.; Morse, Karen W., Inorganic Chemistry, 1984, vol. 23, # 12, p. 1684 - 1691

  摘要：

  DOI：
• 作为试剂：
  描述：

  2,6-二氯苯甲腈 N-氧化物 、 1-chloro-4-(iodobuta-1,3-diyn-1-yl)benzene 在 2,6-二甲基吡啶 、 tris-triphenylphosphine copper(I) iodide 作用下， 生成 、 、
  参考文献：
  名称：

  10.1016/j.mencom.2024.06.022

  摘要：

  DOI：

  10.1016/j.mencom.2024.06.022

文献信息

• Synthesis and spectroscopic characterization of new Cu(I) complexes containing triaryl-, tricycloalkylphosphines and heterocyclic anionic or neutral N-donor ligands. Crystal and molecular structure of [(Cy3P)2(pzH)Cu]ClO4·CH3OH (Cy=cyclohexyl, pzH=pyrazole)
  作者：Claudio Pettinari、Fabio Marchetti、Roberta Polimante、Augusto Cingolani、Gustavo Portalone、Marcello Colapietro

  DOI：10.1016/0020-1693(96)05101-8

  日期：1996.8

  [(PCy3)(ImH)2Cu]ClO4 and 1:1:1 [(PPh3) (1-MeimH)CuCl] adducts. With the bidentate donors bis(pyrazol)-1-yl)methane (L1), bis(3,5-dimethylpyrazol-1-yl)methane (L2) and bis(4-methylpyrazol-1-yl)methane (L4), 2:1:1 [(PPh3)2(L)Cu]ClO4 and 1:1:1 [(PCy3)(L)Cu]ClO4 complexes were obtained, whereas the exopolydentate bis (1,2,4-triazol-l-yl) methane (L3) in similar conditions yielded 1:1:1 [(PPh3)(L3)Cu]ClO4

  （PPh 3）4 CuClO 4，（PPh 3）2 CuCl，（Cy 3 P）2 CuNO 3和（Cy 3 P）2 CuClO 4与过量的单齿杂环N供体配体（QH）反应详细地：ImH =咪唑，1-MeimH = 1-甲基咪唑，2-MeimH = 2-甲基咪唑，4-Phim = 4-苯基咪唑，BimH =苯并咪唑，1-BzimH = 1-苄基咪唑，pzH =吡唑，pz'H = 3,5-二甲基吡唑）在乙醚或苯中的形成新的2：2：1 [（PPh 3）2（QH）2 Cu] ClO 4（QH = ImH，1-MeimH，2-MeimH，4-PhimH，BimH，pzH）和[（PCy 3）2（QH）2 Cu] NO 3（QH = 4-PhimH，BimH），1：3： 1 [[（PPh 3）（1-BzimH）3 Cu] ClO 4，[（PCy 3）（1-MeimH）3 Cu] ClO 4和[（PCy 3）（QH）3
• Material for organic electroluminescent device and organic electroluminescence device including the same
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US09214638B2

  公开（公告）日：2015-12-15

  A material for an organic electroluminescent (EL) device includes a copper(I) complex represented by the following Formula 1: [CuX(PPh3)2L]  [Formula 1] In the above Formula 1, X is an anion, PPh3 is triphenylphosphine, and L is a substituted or unsubstituted heterocyclic ligand having 5 to 18 ring carbon.

  有机电致发光（EL）器件的材料包括以下化学式1所代表的铜(I)配合物： [CuX(PPh3)2L]  [化学式1] 在上述化学式1中，X是阴离子，PPh3是三苯基膦，L是具有5至18个环碳的取代或未取代杂环配体。
• Preparation and Properties of <i>trans</i>-Pd(Ar)(C⋮CPh)(PEt₃)₂. Intermolecular Alkynyl Ligand Transfer between Copper(I) and Palladium(II) Complexes Relevant to Palladium Complex Catalyzed Cross-Coupling of Terminal Alkyne with Haloarene in the Presence of CuI Cocatalyst
  作者：Kohtaro Osakada、Reiko Sakata、Takakazu Yamamoto

  DOI：10.1021/om970266n

  日期：1997.11.1

  trans-Pd(C6H4Me-p)(I)(PEt3)2 (2a) reacts with [Cu(C⋮CPh)(PPh3)]4 (Pd:Cu = 1:1) at room temperature to give the cross-coupling product PhC⋮CC6H4Me-p (3a) in 74% yield. Reactions of 2a with [Cu(C⋮CPh)(PPh3)]4 at −30 °C as well as of trans-Pd(C6H4X-p)(I)(PEt3)2 (2a, X = Me; 2b, X = OMe; 2c, X = F) with the alkynylcopper complex and additional PPh3 (2 mol/mol of Cu) at room temperature give mixtures of

  在室温下，反式-Pd（C 6 H 4 Me- p）（I）（PEt 3）2（2a）与[Cu（C⋮CPh）（PPh 3）] 4（Pd：Cu = 1：1）反应得到产率为74％的交叉偶联产物PhC⋮CC 6 H 4 Me- p（3a）。在-30°C下2a与[Cu（C⋮CPh）（PPh 3）] 4以及反式-Pd（C 6 H 4 X- p）（I）（PEt 3）2（2a）的反应，X =我; 2b，X = OMe; 2c，X ＝ F）与炔铜配合物和在室温下的另外的PPh 3（2mol / mol的Cu）得到PhC⋮CC 6 H 4 X- p的混合物（3a，X ＝ Me；3b，X ＝ OMe；H，H）。在图3c中，X ＝ F）和反式-Pd（C 6 H 4 X- p）（C⋮CPh）（PEt 3）2（4a，X ＝ Me；4b，X ＝ OMe；4c，X ＝ F）。配合物4a，b已从后面的反应混合物中分离出苯并已充
• Synthesis and Characterization of Copper Complexes with the <i>N</i> ‐(2,6‐Diisopropylphenyl)‐ <i>N′</i> ‐acylthiourea Ligands
  作者：Dan Wang、Su‐Yun Wu、Hai‐Pu Li、Ying Yang、Herbert W. Roesky

  DOI：10.1002/ejic.201601451

  日期：2017.3.10

  6-iPr2C6H3; Ar = p-tBuC6H3 (1, L1), Mes (2, L2), 1-Naph (3, L3)) were synthesized and compared with the homologous ligand L0 (Ar = Ph) in terms of their resultant complexes with copper halides. Reactions of L1 with CuCl2 led to the formation of mononuclear L12CuCl (4), while treatment of L1 with CuX (X = Cl, Br) resulted in the adamantane cage complexes (L1CuX)4 (X= Cl, 5; Br, 6). These findings are similar

  三个 N-(2,6-二异丙基苯基)-N'-酰基硫脲配体 (Ar'NHC(S)NHC(O)Ar, Ar' = 2,6-iPr2C6H3; Ar = p-tBuC6H3 (1, L1), Mes (2, L2), 1-Naph (3, L3)) 被合成并与同源配体 L0 (Ar = Ph) 比较它们与卤化铜的复合物。L1 与 CuCl2 的反应导致形成单核 L12CuCl (4)，而用 CuX (X = Cl, Br) 处理 L1 导致金刚烷笼络合物 (L1CuX)4 (X= Cl, 5; Br, 6) . 这些发现与其亲本配体 L0 显示的结果相似。L1 与 CuI 的反应产生了碘化物桥接的二聚体复合物 [L12Cu(μ-I)]2 (7)，与 L0 支持的配体桥接二聚体形成对比。L2 很容易得到由两个或三个配体配位的单核铜 (I) 配合物 (8-10)。L3 得到单体 L33CuX (X =
• Synthesis, Characterisation and Luminescent Properties of Mixed‐Ligand Copper(I) Complexes Incorporating <i>N</i> ‐Thiophosphorylated Thioureas and Phosphane Ligands
  作者：Maria G. Babashkina、Damir A. Safin、Axel Klein、Michael Bolte

  DOI：10.1002/ejic.201000165

  日期：2010.9

  ] (4), or dinuclear complexes [Cu 2 (Ph 2 PCH 2 PPh 2 )L I 2 ] (5), [Cu 2 (PPh 3 ) 2 L II ] (6), [Cu 2 Ph 2 P(CH 2 ) 2 PPh 2 } 2 L II ] (7), [Cu 2 Ph 2 P-(CH 2 ) 3 PPh 2 ) 2 L II ] (8), [Cu 2 Ph 2 P(C 5 H 4 FeC 5 H 4 )PPh 2 } 2 L II ] (9) or [Cu 2 (Ph 2 PCH 2 PPh 2 )L II ] (10). The structures of these compounds were investigated by 1 H and 31 P 1 H} NMR, UV/Vis spectroscopy and elemental analysis

  H 2 NC(S)NHP(S)(OiPr) 2 (H I ) 或 oC 6 H 4[ NHC(S)NHP(S)(OiPr) 2 ] 2 (H 2 L II ) 的钾盐与[Cu(PPh 3 ) 3 I] 或 CuI 和 Ph 2 P(CH 2 ) 1-3 PPh 2 或 Ph 2 P(C 5 H 4 -FeC 5 H 4 )PPh 2 的混合物在 EtOH/CH 2 水溶液中Cl 2 得到单核配合物 [Cu(PPh 3 )LI ] (1), [CuPh 2 P(CH 2 ) 2 PPh 2 }LI ] (2), [CuPh 2 P(CH 2 ) 3 PPh 2 }LI ] (3) 或 [CuPh 2 P(C 5 H 4 FeC 5 H 4 )PPh 2 }-LI ] (4)，或双核配合物 [Cu 2 (Ph 2 PCH 2 PPh 2 )LI 2 ] (5), [Cu 2 (PPh 3