2-methylamino-5,6-dimethyl-4-hydroxypyrimidine | 78195-30-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 2-methylamino-5,6-dimethyl-4-hydroxypyrimidine
• 英文别名: 2-(methylamino)-5,6-dimethyl-4-hydroxy-pirimidine；4(1H)-Pyrimidinone, 5,6-dimethyl-2-(methylamino)-；4,5-dimethyl-2-(methylamino)-1H-pyrimidin-6-one
• CAS: 78195-30-9
• 化学式: C₇H₁₁N₃O
• 分子量: 153.184
• InChiKey: IFOLNWVBRSCJOJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  53.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  抗蚜威 在 acid mine drainage sludge 作用下， 以 水 、 乙腈 为溶剂， 反应 1.5h， 生成 2-(amino)-5,6-dimethylpyrimidin-4-yldimethylcarbamate 、 脱甲基-抗蚜威 、 2-methylamino-5,6-dimethyl-4-hydroxypyrimidine 、 2-二甲胺基-4-羟基-5,6-二甲基嘧啶
  参考文献：
  名称：

  Environmental application of an industrial waste as catalyst for the electro-Fenton-like treatment of organic pollutants

  摘要：

  酸性矿山排水污泥（AMDS）作为含有高金属含量的工业废物，在处理有机污染废水方面作为电-Fenton类技术的催化剂的应用已经被研究。

  DOI：

  10.1039/c4ra15934a

文献信息

• Photocatalytic oxidation of pirimicarb in aqueous slurries containing binary and ternary oxides of zinc and titanium
  作者：José Fenoll、Isabel Garrido、Pilar Hellín、Pilar Flores、Nuria Vela、Simón Navarro

  DOI：10.1016/j.jphotochem.2014.10.014

  日期：2015.2

  The photocatalytic degradation of pirimicarb in pure water has been studied using zinc oxide (ZnO), titanium dioxide (TiO2) and zinc titanates (Zn2TiO4 and ZnTiO3) under artificial light (300-460 nm) irradiation. Comparison of catalysts showed that TiO2 is the most efficient for the removal of pirimicarb and their transformation products. To obtain a better understanding of the mechanistic details of these ZnO-TiO2-assisted photodegradation of pirimicarb, the transformation products of the processes were identified by liquid chromatography tandem mass spectrometry (LC-MS2) and liquid chromatography time of flight mass spectrometry (LC-TOF/MS) techniques. The probable photodegradation pathways are proposed and discussed. The main steps involved: N-dealkylation of the 2-dimethylamino group to form the carbamate and decarbamoylation of the carbamate moiety with further N-dealkylation of the 2-dimethylamino group to have the hydroxypyrimidines. (C) 2014 Elsevier B.V. All rights reserved.
• Environmental application of an industrial waste as catalyst for the electro-Fenton-like treatment of organic pollutants
  作者：Elena Alfaya、Olalla Iglesias、Marta Pazos、Maria Angeles Sanromán

  DOI：10.1039/c4ra15934a

  日期：——

  The application of acid mine drainage sludge (AMDS), an industrial waste with high metal content, as catalyst for the electro-Fenton-like technology on the treatment of organic polluted effluents has been investigated.

  酸性矿山排水污泥（AMDS）作为含有高金属含量的工业废物，在处理有机污染废水方面作为电-Fenton类技术的催化剂的应用已经被研究。