2,6-dimethyl-N-methylene benzamine | 35203-02-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,6-dimethyl-N-methylene benzamine
• 英文别名: 2,6-dimethyl-N-methyleneaniline；2,6-dimethylmethyleneaniline；isocyanide；N-methylene-2,6-dimethylaniline；Formaldehyd-N-<2,6-dimethyl-anilin>；2,6-Dimethyl-phenylazomethin；Methanimine, N-(2,6-dimethylphenyl)-；N-(2,6-dimethylphenyl)methanimine
• CAS: 35203-02-2
• 化学式: C₉H₁₁N
• 分子量: 133.193
• InChiKey: DVEJPRNXGSWVJV-UHFFFAOYSA-N

物化性质

• 沸点：
  237.3±50.0 °C(Predicted)
• 密度：
  0.88±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2921430090

反应信息

• 作为反应物：
  描述：

  2,6-dimethyl-N-methylene benzamine 生成 1,3,5-Tris-(2,6-dimethyl-phenyl)-[1,3,5]triazinane
  参考文献：
  名称：

  Giumanini, Angelo G.; Verardo, Giancarlo; Polana, Marco, Journal fur praktische Chemie (Leipzig 1954), 1988, vol. 330, # 2, p. 161 - 174

  摘要：

  DOI：
• 作为产物：
  描述：

  1,3,5-Tris-(2,6-dimethyl-phenyl)-[1,3,5]triazinane 以 氘代氯仿 为溶剂， 生成 2,6-dimethyl-N-methylene benzamine
  参考文献：
  名称：

  Giumanini, Angelo G.; Verardo, Giancarlo; Polana, Marco, Journal fur praktische Chemie (Leipzig 1954), 1988, vol. 330, # 2, p. 161 - 174

  摘要：

  DOI：

文献信息

• Tetrahydro-1,3,5-thiadiazin-4-one derivative
  申请人：Nihon Nohyaku Co., Ltd.

  公开号：US04159328A1

  公开（公告）日：1979-06-26

  A tetrahydro-1,3,5-thiadiazin-4-one represented by the general formula, ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, represent each an alkyl group, allyl group, cycloalkyl group, alkoxyalkyl group, benzyl group, phenyl group or substituted phenyl group having as substituents alkyl groups, nitro group, halogen atoms, alkoxy groups, or trifluoromethyl group and R.sup.2 and R.sup.3 may also represent hydrogen atoms, is a new compound and useful for controlling insects and mites.

  由通用公式表示的1,3,5-噻二嗪-4-酮，其中R1、R2和R3相同或不同，每个代表一个烷基、烯丙基、环烷基、烷氧基烷基、苄基、苯基或取代的苯基，取代基可以是烷基、硝基、卤素原子、烷氧基或三氟甲基，R2和R3还可以代表氢原子，这是一个新化合物，用于控制昆虫和螨虫。
• One-Pot Synthesis of Dialkyl Arylaminomethyl- and (Arylamino)arylmethylphosphonates and Their<i>N</i>-Acylated Derivatives
  作者：L. K. Lukanov、A. P. Venkov

  DOI：10.1055/s-1992-26083

  日期：——

  A convenient synthesis of dialkyl arylaminomethyl- and (arylamino) arylmethylphosphonates 3 and their N-acylated derivatives 5 have been developed, starting from azomethines and phosphorus trichloride in the presence of an alcohol.

  开发了一种便利的合成方法，以醛基取代的二烷基芳基氨基甲基磷酸酯 3 及其 N-酰化衍生物 5 为目标，反应从亚胺和三氯化磷在醇的存在下开始。
• [EN] EFFICIENT METHODS FOR Z- OR CIS-SELECTIVE CROSS-METATHESIS<br/>[FR] PROCÉDÉS EFFICACES DE MÉTATHÈSE CROISÉE Z-SÉLECTIVE OU CIS-SÉLECTIVE
  申请人：TRUSTEES BOSTON COLLEGE

  公开号：WO2011097642A1

  公开（公告）日：2011-08-11

  The present invention generally relates to methods for performing metathesis reactions, including cross-metathesis reactions. Methods described herein exhibit enhanced activity and stereoselectivity, relative to known methods, and are useful in the synthesis of a large assortment of biologically and therapeutically significant agents.

  本发明通常涉及进行重要反应的方法，包括交叉重要反应。本文描述的方法相对于已知方法表现出增强的活性和立体选择性，并且在合成大量生物学和治疗上重要的药物方面非常有用。
• Mono- and Dipalladated Derivatives of 2,5-Distyrylbenzene. Reactivity toward XyNC and Alkynes. Synthesis of Complexes with Indacenediide Ligands
  作者：Marı́a-José Fernández-Rodrı́guez、Eloı́sa Martı́nez-Viviente、José Vicente、Peter G. Jones

  DOI：10.1021/om5010034

  日期：2015.6.8

  N′-tetramethylethylenediamine (1b)) have been synthesized by oxidative addition of trans,trans-2,5-distyryl-2,4-dibromobenzene to 2 equiv of “[Pd(dba)2]” (dba = dibenzylideneacetone) in the presence of the N∧N ligands. A similar reaction with N∧N = bpy = 2,2′-bipyridine afforded the mononuclear complex [PdBrC6H2(Br-4)((E)-CH═CHPh)2-2,5}(bpy)] (2). The reaction of 1a,b with PhC≡CPh, MeC≡CMe, and PhC≡CMe in the

  双核配合物小号[C 6 H ^ 2 PDBR（N ∧ N）} 2 -1,4- - （（ë）-CH═CHPh）2 -2,5]（N ∧ N = tbbpy = 4,4'-二-叔丁基-2,2'-联吡啶（1A），TMEDA = ñ，ñ，ñ '，ñ 'N'-四甲基乙二胺（1B））已被氧化加成的合成反，反-2,5-二苯乙烯基2,4-二溴苯到2当量“[加入Pd（DBA）的2在N的存在下]”（DBA =苄基丙酮）∧N个配体。与N A类似的反应∧ N = BPY = 2,2'-联吡啶，得到单核配合物[PDBR C 6 H ^ 2（BR-4）（（ë）-CH═CHPh）2 -2,5}（BPY ）]（2）。的反应1A，b在TlOTf或AgClO的存在下用PhC≡CPh，MeC≡CMe和PhC≡CMe 4得到dipalladated indacenediide配合物[（μ-η，η-C 12 H ^ 2 BN 2
• CATALYSTS FOR METATHESIS REACTIONS INCLUDING ENANTIOSELECTIVE OLEFIN METATHESIS, AND RELATED METHODS
  申请人：Malcolmson Steven J.

  公开号：US20110065915A1

  公开（公告）日：2011-03-17

  The present invention provides compositions comprising metal complexes, and related methods. In some embodiments, metal complexes of the invention may be useful as catalysts for chemical reactions, including metathesis reactions, wherein the catalysts exhibit enhanced activity and stereoselectivity. In some embodiments, the invention may advantageously provide metal complexes comprising a stereogenic metal atom. Such metal complexes may be useful in enantioselective catalysis.

  本发明提供了包括金属配合物的组合物以及相关方法。在某些实施例中，本发明的金属配合物可能作为化学反应的催化剂而有用，包括交换反应，其中催化剂表现出增强的活性和立体选择性。在某些实施例中，本发明可能有利地提供包括具有立体异性金属原子的金属配合物。这种金属配合物可能在对映选择性催化中有用。