tritium fluoride | 53347-65-2

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 卤代有机物
• 英文名称: tritium fluoride
• CAS: 53347-65-2
• 化学式: FH
• 分子量: 21.9984
• InChiKey: KRHYYFGTRYWZRS-MNYXATJNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  1
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  tritium fluoride 、 水 以 not given 为溶剂， 生成 氢氧化氚
  参考文献：
  名称：

  Dissociation and Exchange Equilibria of the Tritium Halides

  摘要：

  The ratios of the partition functions of the tritium halides to their respective protium halides have been calculated. These are combined with one another to give the exchange equilibria between the six pairs of tritium and protium halides. The exchange equilibria with water are calculated. From the exchange equilibria between the tritium halides and protium and the free energy of dissociation of the protium halides, the dissociation equilibria of the tritium halides have been calculated. The experimental data on the dissociation of HI are reviewed and it is shown that the data of Taylor and Crist on DI and HI are self-consistent as well as in good agreement with theory. The heat of formation of HI at absolute zero, ΔH00, is found to be − 1007±10 calories per mole.

  DOI：

  10.1063/1.1747665
• 作为产物：
  描述：

  三氟氚甲烷 生成 tritium fluoride
  参考文献：
  名称：

  TAKEUCHI, KAZUO;SATOOKA, SAKAE, J. NUCL. SCI. AND TECHNOL., 25,(1988) N 5, C. 489-494

  摘要：

  DOI：

文献信息

• Infrared spectrum and molecular constants of gaseous tritium fluoride
  作者：Llewellyn H. Jones、Maxwell Goldblatt

  DOI：10.1016/0022-2852(57)90008-5

  日期：1957.1

  have been observed with ≈1 cm −1 and ≈2.5 cm −1 resolution, respectively. Molecular constants were calculated from the observed frequencies. Within the accuracy of measurement the observed constants agree with those previously reported ( 1 ) for hydrogen fluoride ( g ). The “least squares” values of the molecular constants in cm −1 are: ν 1←0 = 2443.86, ν 2←0 = 4823.8, ω e = 2508.5, x e ω e = 32.5, B e

  摘要 氟化氚( g ) 的ν 1←0 和ν 2←0 振动-旋转线已经分别以≈1 cm -1 和≈2.5 cm -1 的分辨率被观测到。从观察到的频率计算分子常数。在测量的准确度内，观察到的常数与先前报道的氟化氢 (g) 的常数 (1) 一致。以 cm -1 为单位的分子常数的“最小二乘”值是： ν 1←0 = 2443.86, ν 2←0 = 4823.8, ω e = 2508.5, xe ω e = 32.5, B e = 7.69, α e = 0.176 , De = 2.5 × 10 -4 。键距为 0.917 A，力常数为 9.65 × 10 5 达因/厘米。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: SVol.3, 2.1.1.4, page 18 - 19
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: O: MVol.6, 85, page 2054 - 2056
  作者：

  DOI：——

  日期：——