1,2-bis(methacryloylthio)ethane | 117675-95-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 硫代羧酸及其衍生物
• 英文名称: 1,2-bis(methacryloylthio)ethane
• 英文别名: 2-Propenethioic acid, 2-methyl-, S1,S1a(2)-1,2-ethanediyl ester；S-[2-(2-methylprop-2-enoylsulfanyl)ethyl] 2-methylprop-2-enethioate
• CAS: 117675-95-3
• 化学式: C₁₀H₁₄O₂S₂
• 分子量: 230.352
• InChiKey: ZHMRCHSJGBFETA-UHFFFAOYSA-N

物化性质

• 沸点：
  370.8±12.0 °C(Predicted)
• 密度：
  1.120±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  84.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,2-乙二硫醇 、 甲基丙烯酰氯 在 氢氧化钾 、 甲基三辛基氯化铵 、 4-甲氧基苯酚 作用下， 以 氯仿 为溶剂， 反应 0.25h， 以86.1%的产率得到1,2-bis(methacryloylthio)ethane
  参考文献：
  名称：

  Novel Bifunctional Thiolcarboxylic Acid Esters Useful as Crosslinking Agents for Optical Materials

  摘要：

  Novel bifunctional thiolcarboxylic acid esters such as thiodimethacrylates have been prepared in good yield by reaction of dimercaptanes with acid chloride in KOHaq and organic solvent system in the presence of phase transfer catalyst under mild reaction conditions. These bifunctional thiomethacrylates are useful as crosslinking agents having high refractive indices.

  DOI：

  10.1080/00397910008087452

文献信息

• Photochromic composition
  申请人：——

  公开号：US20040173782A1

  公开（公告）日：2004-09-09

  A photochromic composition and a coating composition comprising a molecular compound of a chromene compound and an aromatic compound. The photochromic composition provides a photochromic optical material as a cured product and the coating composition is applied to a lens substrate and cured to provide a photochromic optical material. The above molecular compound is also provided.

  一种光致变色组合物和涂层组合物，包括一种色素化合物和一种芳香化合物的分子化合物。光致变色组合物提供一种光致变色光学材料作为固化产品，涂层组合物被应用于镜片基底并固化以提供光致变色光学材料。上述分子化合物也被提供。
• Method for Preparing a Colloidal Zirconia Solution
  申请人：Chaput Frederic

  公开号：US20100144918A1

  公开（公告）日：2010-06-10

  A method for preparing a colloidal solution of non-aggregated zirconia particles, comprising the following steps: a) providing a zirconium hydroxide sol, b) adding to said sol an inorganic acid according to an [inorganic acid]/[Zr] molar ratio of <0.5, c) performing the hydrothermal treatment of said sol, and d) recovering the colloidal solution of zirconia particles.

  一种制备非聚集氧化锆颗粒胶体溶液的方法，包括以下步骤：a)提供氢氧化锆溶胶，b)向所述溶胶中添加无机酸，使其[inorganic acid]/[Zr]摩尔比小于0.5，c)对所述溶胶进行水热处理，d)回收氧化锆颗粒的胶体溶液。
• Photochromic blue light filtering materials and ophthalmic devices
  申请人：Jani M. Dharmendra

  公开号：US20050254003A1

  公开（公告）日：2005-11-17

  Polymeric compositions have photochromic and blue-light filtering ability and are useful in the manufacture of ophthalmic medical devices. The polymeric compositions comprise a photochromic material incorporated into polymeric host materials and are activatable by blue light having a first wavelength range to become photochromic, and are thereby capable of absorbing blue light in a second wavelength range. Methods of making the compositions comprise incorporating a photochromic material into a polymeric host material.

  聚合物组合物具有光致变色和蓝光过滤能力，并可用于制造眼科医疗器械。该聚合物组合物包括将光致变色材料并入聚合物基材料中，可以通过第一波长范围的蓝光激活变成光致变色，并且因此能够吸收第二波长范围的蓝光。制造该组合物的方法包括将光致变色材料并入聚合物基材料中。
• High refractive index monomers, compositions and uses thereof
  申请人：Craciun Liliana

  公开号：US20080200582A1

  公开（公告）日：2008-08-21

  The invention relates to novel sulfur-containing (meth)acrylic monomers and compositions thereof characterized by a high refractive index, for optical and industrial applications. The invention also relates to a method for preparing high refractive index polymeric materials and more specifically to a method for formation of ultraviolet cast optical lenses and compositions thereof comprising the sulfur-containing (meth)acrylic monomers.

  本发明涉及一种新型含硫（甲基）丙烯酸单体及其组合物，其具有高折射率，适用于光学和工业应用。本发明还涉及一种制备高折射率聚合材料的方法，更具体地涉及一种形成紫外线铸造光学透镜的方法和组合物，其中包括含硫（甲基）丙烯酸单体。
• Resin having high refractive index, process for producing said resin and optical materials composed of said resin
  申请人：Nippon Shokubai Kagaku Kogyo Co., Ltd

  公开号：EP0273710A2

  公开（公告）日：1988-07-06

  A process for producing a resin ahving a high refractive index which comprises radically polymerizing a material monomer, characterized in that said material monomer comprises [I] at least one polymerizable monomer selected from the group consisting of a polyfunctional thioacrylate and a polyfunctional thiomethacrylate (as an indispensable component), and optionally [II] at least one other polymerizable monomer which is radically polymeriz­able with said polymerizable monomer [I], a resin having a high refractive index produced by said process and optical materials, especially lenses and disk substrates prepared from said resin.

  一种生产高折射率树脂的工艺，包括对材料单体进行辐射聚合，其特征在于所述材料单体包括 [I] 至少一种可聚合单体，该单体选自由多官能团硫代丙烯酸酯和多官能团硫代甲基丙烯酸酯（作为不可或缺的组分）组成的组、以及[II]至少一种可与所述可聚合单体[I]进行辐射聚合的其他可聚合单体，通过所述工艺生产的具有高折射率的树脂，以及用所述树脂制备的光学材料，尤其是透镜和盘片基板。