9-methoxy-10-phenyl-phenanthrene | 91083-70-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 9-methoxy-10-phenyl-phenanthrene
• 英文别名: methyl-(10-phenyl-[9]phenanthryl)-ether；Methyl-(10-phenyl-[9]phenanthryl)-aether；10-Methoxy-9-phenyl-phenanthren；9-Methoxy-10-phenylphenanthrene
• CAS: 91083-70-4
• 化学式: C₂₁H₁₆O
• 分子量: 284.357
• InChiKey: IKYVOEVZJFAMOE-UHFFFAOYSA-N

物化性质

• 熔点：
  189-190 °C
• 沸点：
  419.3±14.0 °C(Predicted)
• 密度：
  1.151±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9-methoxy-10-phenyl-phenanthrene 在 sodium amalgam 、 乙醚 、 溴 、 溶剂黄146 作用下， 生成 9-bromo-10-phenylphenanthrene
  参考文献：
  名称：

  The Action of Sodium on 9-Methoxy-10-phenylphenanthrene and on 1-Diphenylene-3-phenylindene

  摘要：

  DOI：

  10.1021/ja01317a066
• 作为产物：
  描述：

  (1-甲氧基-2,2-二苯基乙烯基)苯 生成 9-methoxy-10-phenyl-phenanthrene
  参考文献：
  名称：

  乙烯基溴9-（α-溴亚苄基）芴在甲醇中的光解作用。照射波长，甲醇钠和氧气的影响

  摘要：

  定量研究9-（α-溴亚苄基）芴（1）在甲醇中的光溶剂分解结果表明，辐照的波长，甲醇钠的存在和氧的存在强烈影响产物的分布和反应的量子产率。

  DOI：

  10.1016/s0040-4020(01)88173-4

文献信息

• KOt-Bu/DMF promoted intramolecular cyclization of 1,1′-biphenyl aldehydes and ketones: an efficient synthesis of phenanthrenes
  作者：Yan-yan Chen、Niu-niu Zhang、Lin-miao Ye、Jia-hua Chen、Xiang Sun、Xue-jing Zhang、Ming Yan

  DOI：10.1039/c5ra07188g

  日期：——

  A new synthesis of phenanthrene derivatives has been achieved through intramolecular cyclization of 1,1′-biphenyl aldehydes and ketones promoted by KOt-Bu/DMF. A free radical reaction pathway is proposed.

  通过KO t -Bu / DMF促进的1,1'-联苯醛和酮的分子内环化，实现了菲衍生物的新合成。提出了自由基反应途径。
• The one-electron oxidation of biphenyl-2-ylethylenes. Subsequent chemical reactivity controlled by electron return or proton transfer
  作者：Ren� Lapouyade、Patrice Villeneuve、Aziz Nourmamode、Jean-Pierre Morand

  DOI：10.1039/c39870000776

  日期：——

  Biphenyl-2-ylethylenes react with (4-BrC6H4)3N˙+SbCl6– to give the radical cation of the electrocyclization product which initiates a protic catalysis to the related fluorenes or, in presence of 2,6-di-t-butylpyridine or water, lead stoicheiometrically to phenanthrenes; with photochemical oxidants only phenanthrenes or 9,10-dihydrophenanthrenes are obtained, with an efficiency related to the polarity

  联苯-2- ylethylenes与反应（4- BRC 6 ħ 4）3 Ñ +的SbCl 6 - ，得到发起质子催化现有芴，或在2,6-二存在下electrocyclization产物的自由基阳离子-叔丁基吡啶或水，从化学计量学上导致菲；用光化学氧化剂只能得到菲或9，10-二氢菲，其效率与溶剂的极性以及三重态供体和自由基离子对的相对能量有关。
• Degenerate .beta.-aryl rearrangements in photochemically generated triarylvinyl cations
  作者：Tsugio Kitamura、Shinjiro Kobayashi、Hiroshi Taniguchi、Charles Y. Fiakpui、Choi Chuck Lee、Zvi Rappoport

  DOI：10.1021/jo00191a023

  日期：1984.8
• KITAMURA, TSUGIO;KOBAYASHI, SHINJIRO;TANIGUCHI, HIROSHI;FIAKPUI, CH. Y.;L+, J. ORG. CHEM., 1984, 49, N 17, 3167-3170
  作者：KITAMURA, TSUGIO、KOBAYASHI, SHINJIRO、TANIGUCHI, HIROSHI、FIAKPUI, CH. Y.、L+

  DOI：——

  日期：——
• [EN] METHOD FOR PREPARING ELASTOMERIC COPOLYMERS OF ETHYLENE AND a-OLEFINS<br/>[FR] PROCÉDÉ DE FABRICATION DE COPOLYMÈRES ÉLASTOMÈRES DE L'ÉTHYLÈNE ET D'?-OLÉFINES
  申请人：SK ENERGY CO LTD

  公开号：WO2010053264A2

  公开（公告）日：2010-05-14

  Provided is a process for preparing copolymers of ethylene with α-olefin. More specifically, provided are transition metal compound being useful as catalyst for preparing those copolymers, a catalyst composition comprising the same, and a process for preparing elastic copolymers of ethylene with α-olefin, having the density of not more than 0.910, which can be adopted to a wide variety of applications including film,, electric wires, and hot-melt adhesives. The catalyst composition is a catalytic system which comprises transition metal catalyst comprising a cyclopentadiene derivative and at least one anionic ligand(s) of aryloxy group with an aryl derivative at ortho-position, and boron or aluminum compound as an activator. Provided is a process for copolymerizing ethylene with α-olefin to produce copolymer having narrow molecular weight distribution and uniform density distribution with the density of not more than 0.910, with high activity and excellent reactivity on higher α-olefin.