9,10-bis(2-hydroxyethoxy)anthracene | 874674-31-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9,10-bis(2-hydroxyethoxy)anthracene
• 英文别名: 2,2'-(Anthracene-9,10-diylbis(oxy))diethanol；2-[10-(2-hydroxyethoxy)anthracen-9-yl]oxyethanol
• CAS: 874674-31-4
• 化学式: C₁₈H₁₈O₄
• 分子量: 298.339
• InChiKey: PRDISNSOFCDGJQ-UHFFFAOYSA-N

物化性质

• 沸点：
  554.3±30.0 °C(Predicted)
• 密度：
  1.276±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  58.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  9,10-bis(2-hydroxyethoxy)anthracene 、 异氰酸正丁酯 在 三乙胺 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 2.0h， 以2.9 g的产率得到9,10-bis{2-(n-butylaminocarbonyloxy)ethoxy}anthracene
  参考文献：
  名称：

  ９，１０−ビス｛２−（置換アミノカルボニルオキシ）アルコキシ｝アントラセン化合物、その製造法及びその用途

  摘要：

  【问题】提供一种新的光重合增感剂，使保存时难以发生迁移。 【解决方法】提供以下一般式（1）表示的9,10-双{2-（取代氨基甲酰氧基）氧代基}蒽化合物。 【选择图】无。

  公开号：

  JP2017193523A
• 作为产物：
  描述：

  碳酸乙烯酯 、 氫蒽醌 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以70 %的产率得到9,10-bis(2-hydroxyethoxy)anthracene
  参考文献：
  名称：

  CN115433145

  摘要：

  公开号：

文献信息

• Process for producing anthracene diether
  申请人：Honda Hiroyuki

  公开号：US20060079721A1

  公开（公告）日：2006-04-13

  An industrially advantageous process is presented whereby a high purity anthracene diether can be produced in good yield. An aqueous medium containing an alkali salt of 9,10-anthracenediol is added to an organic solvent containing an etherifying agent in the presence or absence of a quaternary ammonium compound or a quaternary phosphonium compound, to carry out the etherifying reaction to produce the anthracene diether.

  提出了一种工业上有利的过程，可以在良好的产率下生产高纯度蒽二醚。在有机溶剂中加入含有9,10-蒽二酚的碱盐的水介质，同时存在或不存在季铵化合物或季膦化合物，进行醚化反应以生产蒽二醚。
• Inkjet ink, printed matters, and inkjet recording method
  申请人：Toshiba Tec Kabushiki Kaisha

  公开号：EP1621593A1

  公开（公告）日：2006-02-01

  There is proposed an inkjet ink comprising a compound represented by the following general formula (1), a cationic photopolymerization initiator, a cationic photopolymerizable compound, and a pigment having an average particle diameter of 300 nm or less, wherein the cationic photopolymerization initiator is included at a ratio of 0.5% by weight to 8% by weight based on 100% by weight.of the cationic photopolymerizable compound, and the inkjet ink has a viscosity of 50 mPa·sec or less at ordinary temperature,     (wherein R is a monovalent organic group having 1 to 5 carbon atoms, R1 and R2 may be the same or different and are individually hydrogen atom or alkyl group, alkyl sulfonyl group or alkoxy group each having 1 to 3 carbon atoms).

  建议采用一种喷墨墨水，该墨水由以下通式（1）表示的化合物、阳离子光聚合引发剂、阳离子可光聚合化合物和平均颗粒直径为 300 纳米或更小的颜料组成，其中阳离子光聚合引发剂的含量比例为 0.5%（按重量计）至 8%（按重量计）（基于阳离子可光聚合化合物的 100%（按重量计）），并且该喷墨墨水在常温下的粘度为 50 毫帕-秒或更小、 (其中 R 是具有 1 至 5 个碳原子的单价有机基团，R1 和 R2 可以相同或不同，且各自为氢原子或烷基、烷基磺酰基或烷氧基，每个基团具有 1 至 3 个碳原子)。
• Acting energy radiation curable ink-jet ink, ink-jet recoring method, and printed matter
  申请人：Konica Minolta IJ Technologies, Inc.

  公开号：EP2228415A1

  公开（公告）日：2010-09-15

  The present invention provides an actinic energy radiation curable ink-jet ink exhibiting excellent ink storage stability, nozzle ink repellency, and ejection stability, and also exhibiting excellent curability, anti-abrasion properties, solvent resistance, flexibility, weather resistance, and substrate adhesion properties even under various ambience factors and irradiation conditions, as well as an ink-jet recording method and printed matter using the same. In an actinic energy radiation curable ink-jet ink containing a cationically polymerizable compound and a photo-cationic polymerization initiator, an actinic energy radiation curable ink-jet ink wherein a cationically polymerizable compound having a vinyl ether group as a reactive group is contained at 50.0% by mass or more and the halogen ion content is 1.0 µg/g of the ink - 100 µg/g of the ink.

  本发明提供了一种在各种环境因素和辐照条件下都能表现出优异的储墨稳定性、喷嘴拒墨性和喷出稳定性，并且还能表现出优异的固化性、抗磨损性、耐溶剂性、柔韧性、耐候性和基材附着性的可辐射固化喷墨墨水，以及使用该墨水的喷墨记录方法和印刷品。在含有阳离子可聚合化合物和光阳离子聚合引发剂的可辐射固化喷墨墨水中，阳离子可聚合化合物中具有乙烯基醚基团作为活性基团的阳离子可聚合化合物的质量含量为 50.0% 或以上，卤素离子含量为 1.0 µg/g - 100 µg/g。
• Actinic energy radiation curable ink-jet ink and ink-jet image forming method
  申请人：Konica Minolta IJ Technologies, Inc.

  公开号：EP2236568A1

  公开（公告）日：2010-10-06

  Provided is an actinic energy radiation curable ink-jet ink, an ink-jet recording method, and printed matter satisfying ink storage stability, ejection stability, weather resistance, flexibility, safety, odorless properties. An actinic energy radiation curable ink-jet ink comprises a cationically polymerizable compound and a photo-cationic polymerization initiator, wherein the cationically polymerizable compound comprises a vinyl ether group as a. reactive group, the photo-cationic polymerization initiator is a photo acid generator, a amount of generation of protonic acid from the photo acid generator is 1 x 10-4 mol/L or less, and comprising a radical polymerization inhibitor; wherein the amount of generation of protonic acid is defined as a difference of a hydrogen ion concentration (mol/L) in dioxane solution between immediately after preparation and after refluxing when 0.02 mol/L of the photo acid generator in dioxane solution are refluxed 20 hours under atmospheric pressure.

  本发明提供了一种可辐射固化的喷墨墨水、一种喷墨记录方法以及满足墨水储存稳定性、弹射稳定性、耐候性、柔韧性、安全性和无味特性的印刷品。一种可辐射固化的喷墨墨水由阳离子可聚合化合物和光阳离子聚合引发剂组成，其中阳离子可聚合化合物由乙烯基醚基作为反应基团，光阳离子聚合引发剂由乙烯基醚基作为反应基团。其中，阳离子可聚合化合物由乙烯基醚基团作为反应基团，光阳离子聚合引发剂是一种光酸发生剂，光酸发生剂生成质子酸的量为 1 x 10-4 mol/L 或更少，还包括一种自由基聚合抑制剂；其中，质子酸的生成量定义为在大气压下将 0.02 mol/L 的光酸发生剂在二噁烷溶液中回流 20 小时后，制备后立即与回流后二噁烷溶液中氢离子浓度（mol/L）之差。
• Image forming method using actinic energy radiation curable ink-jet ink and printed matter obtained thereby
  申请人：Konica Minolta IJ Technologies, Inc.

  公开号：EP2266812A2

  公开（公告）日：2010-12-29

  Provided is an actinic radiation curable inkjet ink capable of high sensitivity and high glossy image; and an image forming method utilizing the same. An actinic radiation curable inkjet ink comprising a photo polymerization initiator and a polymerizable monomer, wherein a surface free energy γs of an ink layer cured by an actinic radiation is in the range of 30 to 50 mJ/m2 and a polar component γsp is in the range of 5 to 15 mJ/m2; wherein γsd, γsp and γsh each represent a non-polar component, a polar component and a hydrogen bond component of a surface free energy of a solid surface based on Young-Fowkes Equation, provided that the surface free energy is represented by γs=γsd+γsp+γsh.

  本发明提供了一种能产生高灵敏度和高光泽度图像的光辐射固化喷墨墨水，以及利用该墨水的图像形成方法。一种光辐射固化喷墨墨水，由光聚合引发剂和可聚合单体组成，其中光辐射固化墨层的表面自由能 γs 在 30 至 50 mJ/m2 之间，极性分量 γsp 在 5 至 15 mJ/m2 之间；其中，γsd、γsp 和 γsh 分别代表基于 Young-Fowkes 方程的固体表面自由能的非极性分量、极性分量和氢键分量，条件是表面自由能由γs=γsd+γsp+γsh 表示。