5-(cyclopent-2-enyl)-2,4-toluenediamine | 111962-98-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-(cyclopent-2-enyl)-2,4-toluenediamine
• 英文别名: 4-(Cyclopent-2-en-1-yl)-6-methylbenzene-1,3-diamine；4-cyclopent-2-en-1-yl-6-methylbenzene-1,3-diamine
• CAS: 111962-98-2
• 化学式: C₁₂H₁₆N₂
• 分子量: 188.272
• InChiKey: WHCYMMPFGLGWHD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-(cyclopent-2-enyl)-2,4-toluenediamine 生成 4-(Cyclopenten-1-yl)-6-methylbenzene-1,3-diamine
  参考文献：
  名称：

  BURGOYNE, WILLIAM F. (JR);DIXON, DALE D.

  摘要：

  DOI：
• 作为产物：
  描述：

  二聚环戊二烯 在 氮 作用下， 以 正戊烷 为溶剂， 生成 5-(cyclopent-2-enyl)-2,4-toluenediamine
  参考文献：
  名称：

  Alkenylated toluenediisocyanates for use in preparing polyurethane urea

  摘要：

  本发明涉及一类至少具有一个烯丙基团正交于异氰酸酯基团的甲苯二异氰酸酯。更具体地说，甲苯二异氰酸酯由以下公式表示：##STR1##其中R.sub.1、R.sub.2、R.sub.3、R.sub.4和R.sub.5为氢、C.sub.1-3脂肪基、苯基、卤素或烷氧基，或R.sub.2和R.sub.4或R.sub.5通过一个烷基--(CH.sub.2).sub.y --桥连，其中y=2至5，x为1或2，前提是在所述公式中，至少有一个R.sub.1、R.sub.2、R.sub.3、R.sub.4或R.sub.5为C.sub.1或更大。发现上述所述的烯丙基化甲苯二异氰酸酯非常适合通过提供后交联和聚合的悬挂不饱和度来制备交联缩聚聚合物。它们也非常适合制备聚氨酯和聚氨酯弹性体系统。

  公开号：

  US04794194A1

文献信息

• Alkenylated toluenediamines for use in preparing polyurethane/urea
  申请人：Air Products and Chemicals, Inc.

  公开号：US04714778A1

  公开（公告）日：1987-12-22

  This invention relates to a class of alkenylated toluenediamines having at least one alkenyl group ortho to an amine group. More particularly the toluenediamines are represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are hydrogen, C.sub.1-3 aliphatic, phenyl, halogen or alkoxy radicals, or R.sub.2 and R.sub.4 or R.sub.5 are bridged via an alkylene radical --(CH.sub.2).sub.y -- wherein y=2 to 5, and x is one or two provided that in said formula at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4 or R.sub.5 is C.sub.1 or greater. The above described alkenylated toluenediamines have been found to be well suited as antioxidants and as tri- and tetra functional chain extenders in forming polyurethane/urea elastomers systems and for providing pendant unsaturation for post curing and polymerization.

  本发明涉及一类具有至少一个烯丙基团正交于胺基的甲苯二胺衍生物。更具体地，所述甲苯二胺衍生物由以下公式表示：##STR1## 其中R1，R2，R3，R4和R5为氢、C1-3脂肪基、苯基、卤素或烷氧基，或R2和R4或R5通过烷基--(CH2)y--桥接，其中y=2至5，x为1或2，但在所述公式中至少有一个R1、R2、R3、R4或R5为C1或更大。上述描述的烯丙基化甲苯二胺衍生物已被发现非常适用于作为抗氧化剂以及在形成聚氨酯/脲弹性体系统中作为三元和四元功能链延伸剂，并为后固化和聚合提供侧链不饱和度。
• Alkenylated toluenediamines as antioxidants for organic materials
  申请人：Air Products and Chemicals, Inc.

  公开号：US04985159A1

  公开（公告）日：1991-01-15

  This invention relates to organic materials normally susceptible to gradual degradation in the presence of oxygen during use over an extended period of time and of the type in which it is customary to add an antioxidant thereto to prevent degradation. The improvement constituting the basis of this invention comprises including an alkenylated toluenediamine having one alkenyl group ortho to an amine group. More particularly, the alkenylated toluenediamines suited as antioxidants are represented by the formulas: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are hydrogen, C.sub.1 to C.sub.3 aliphatic, or R.sub.1 and R.sub.2 or R.sub.3 are bridged via an alkylene radical --(CH.sub.2).sub.y -- wherein y=2 to 5, and at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4 or R.sub.5 is C.sub.1 or greater.

  本发明涉及一种有机材料，通常在使用过程中存在氧气时会逐渐降解，并且为了防止降解而通常添加抗氧化剂的类型。本发明的改进基础包括包括一种在胺基正交的烯基化甲苯二胺中含有一个烯基的化合物。更具体地，适用于抗氧化剂的烯基化甲苯二胺由以下公式表示：##STR1##其中R.sub.1、R.sub.2、R.sub.3、R.sub.4和R.sub.5为氢、C.sub.1到C.sub.3脂肪基，或R.sub.1和R.sub.2或R.sub.3通过一个碳链基--(CH.sub.2).sub.y--桥接，其中y=2至5，并且R.sub.1、R.sub.2、R.sub.3、R.sub.4或R.sub.5中至少有一个为C.sub.1或更大。
• Cycloalkenyl aryldiamines
  申请人：Air Products and Chemicals, Inc.

  公开号：US04845291A1

  公开（公告）日：1989-07-04

  This invention relates to a class of alkenylated toluenediamines and phenylenediamines having at least one alkenyl group ortho to an amine group. More particularly the aryldiamines are represented by the formula: ##STR1## wherein R is hydrogen or C.sub.1 -C.sub.3 aliphatic, R.sub.1 is hydrogen, R.sub.2 is C.sub.2 -C.sub.4, aliphatic and R.sub.1 and R.sub.2 form an alkylene radical (CH.sub.2).sub.y wherein y=3 or 4, and x is one or two. The above described alkenylated aryldiamine, hereafter referred to as diamino-.beta.-alkyl styrenes, have been found to be well suited as antioxidants and as tri-and tetra functional chain extenders in forming polyurethane/urea elastomers systems and for providing pendant unsaturation for post curing and polymerization.

  本发明涉及一类至少具有一个烯基基团正对胺基的甲苯二胺和苯二胺的化合物。更具体地说，这些芳基二胺由以下公式表示：##STR1## 其中R为氢或C.sub.1-C.sub.3脂肪基，R.sub.1为氢，R.sub.2为C.sub.2-C.sub.4脂肪基，且R.sub.1和R.sub.2形成一个碳链基团(CH.sub.2).sub.y，其中y=3或4，x为1或2。上述所述的烯基化芳基二胺，以下简称为二氨基-β-烷基苯乙烯，已被发现非常适用于作为抗氧化剂以及在形成聚氨酯/脲弹性体系统中作为三元和四元功能链延伸剂，并且为后期固化和聚合提供了悬挂不饱和度。
• Alkenylated toluenediamines for use in preparing polyurethane/urea systems
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0235825A2

  公开（公告）日：1987-09-09

  This invention relates to a class of alkenylated toluenediamines having at least one alkenyl group ortho to an amine group. More particularly the toluenediamines are represented by the formula: wherein R1, R2, R3, R4 and Rs are hydrogen. C1-3 aliphatic, phenyl, halogen or alkoxy radicals, or R2 and R4 or Rs are bridged via an alkylene radical -(CH2)y- wherein y=2 to 5, and x is one or two provided that in said formula at least one of R1, R2, R3, R4 or R5 is C1 or greater. The above described alkenylated toluenediamines have been found to be well suited as antioxidants and as tri-and tetra functional chain extenders in forming polyurethane/urea elastomers systems and for providing pendant unsaturation for post curing and polymerization.

  本发明涉及一类至少有一个烯基与胺基正交的烯化甲苯二胺。更具体地说，这些甲苯二胺由式表示： 其中 R1、R2、R3、R4 和 Rs 为氢。C1-3脂肪族、苯基、卤素或烷氧基，或 R2 和 R4 或 Rs 通过亚烷基-(CH2)y-桥接，其中 y=2 至 5，且 x 为 1 或 2，条件是在所述式中，R1、R2、R3、R4 或 R5 中至少有一个是 C1 或更大。 已发现上述烯基化甲苯二胺非常适合作为抗氧化剂和三官能和四官能链延伸剂，用于形成聚氨酯/尿素弹性体体系，并为后固化和聚合提供悬垂不饱和度。
• Diamino-beta-alkylstyrenes for use in preparing polyurethane/urea systems
  申请人：AIR PRODUCTS AND CHEMICALS, INC.

  公开号：EP0272650A1

  公开（公告）日：1988-06-29

  This invention relates to a class of alkenylated toluenediamines and phenylenediamines having at least one alkenyl group ortho to an amine group. More particularly the aryldiamines are represented by the formula: wherein R is hydrogen or C₁-C₃ aliphatic, R₁ is hydrogen, R₂ is C₂-C₄, and R₁ and R₂ form an alkylene radical (CH₂)y wherein y=3 or 4, and x is one or two. The above described alkenylated aryldiamine, hereafter referred to as diamino-β-alkyl styrenes, have been found to be well suited as antioxidants and as tri-and tetra functional chain extenders in forming polyurethane/urea elastomers systems and for providing pendant unsaturation for post curing and polymerization.

  本发明涉及一类至少有一个烯基与一个胺基正交的烯化甲苯二胺和苯二胺。更具体地说，芳基二胺由式表示： 其中 R 是氢或 C₁-C₃ 脂肪族，R₁ 是氢，R₂ 是 C₂-C₄，R₁ 和 R₂ 形成亚烷基 (CH₂)y 其中 y=3 或 4，x 是 1 或 2。 已发现上述烯基芳基二胺（以下称为二氨基-β-烷基苯乙烯）非常适合用作抗氧化剂和三官能和四官能链延伸剂，以形成聚氨酯/尿素弹性体体系，并为后固化和聚合提供悬垂不饱和度。