Phenylallylsulfonat | 31515-47-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenylallylsulfonat
• 英文别名: Phenyl 2-propen-1-sulfonat；Phenyl-prop-2-ensulfonat；Phenyl 2-propenesulfonate；phenyl prop-2-ene-1-sulfonate
• CAS: 31515-47-6
• 化学式: C₉H₁₀O₃S
• 分子量: 198.243
• InChiKey: DSEIZAMXRAAJDJ-UHFFFAOYSA-N

物化性质

• 沸点：
  312.0±25.0 °C(Predicted)
• 密度：
  1.219±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Phenylallylsulfonat 在 溴 作用下， 以 四氯化碳 为溶剂， 生成 Phenyl-2,3-dibrompropansulfonat
  参考文献：
  名称：

  Vizgert,R.V.; Skrypnik,Yu.G., Journal of Organic Chemistry USSR (English Translation), 1971, vol. 7, p. 345 - 349

  摘要：

  DOI：
• 作为产物：
  描述：

  2-丙烯-1-磺酰氯 、 potassium phenolate 以 丙酮 为溶剂， 生成 Phenylallylsulfonat
  参考文献：
  名称：

  Vizgert,R.V.; Skrypnik,Yu.G., Journal of Organic Chemistry USSR (English Translation), 1971, vol. 7, p. 345 - 349

  摘要：

  DOI：

文献信息

• Azo pigment and pigment dispersion
  申请人：FUJIFILM Corporation

  公开号：EP2039725A2

  公开（公告）日：2009-03-25

  An azo pigment represented by the following formula (1) or a tautomer thereof: wherein R1 represents an aliphatic group having 1 to 8 carbon atoms in total, an aryl group having 6 to 12 carbon atoms in total or a heterocyclic group having 2 to 12 carbon atoms in total; R2 represents a hydrogen atom or an aliphatic group having 1 to 8 carbon atoms in total; R3 represents a hydrogen atom, an aliphatic group having 1 to 4 carbon atoms in total, an aliphatic amino group having 1 to 8 carbon atoms in total, or an amino group; R4 and R5 each independently represent an aliphatic amino group having 1 to 8 carbon atoms in total, or an amino group; R6 represents a cyano group, a carbamoyl group having 1 to 10 carbon atoms in total, an aliphatic oxycarbonyl group having 1 to 8 carbon atoms in total, an aliphatic sulfonyl group having 1 to 8 carbon atoms in total, or a carboxy group; and X2 represents a nitrogen atom or C-CN.

  以下是该式（1）表示的偶氮颜料或其互变异构体： 其中，R1代表总共具有1至8个碳原子的脂肪族基团，总共具有6至12个碳原子的芳基团或总共具有2至12个碳原子的杂环基团；R2代表氢原子或总共具有1至8个碳原子的脂肪族基团；R3代表氢原子、总共具有1至4个碳原子的脂肪族基团、总共具有1至8个碳原子的脂肪族氨基基团或氨基基团；R4和R5各自独立地代表总共具有1至8个碳原子的脂肪族氨基基团或氨基基团；R6代表氰基、总共具有1至10个碳原子的氨基甲酰基团、总共具有1至8个碳原子的脂肪族氧羰基团、总共具有1至8个碳原子的脂肪族磺酰基团或羧基；X2代表氮原子或C-CN。
• METHOD OF MAKING A SYNTHETIC ALKYLARYL SULFONATE
  申请人：Sinquin Gilles P.

  公开号：US20090163669A1

  公开（公告）日：2009-06-25

  A process for preparing a synthetic petroleum sulfonate comprising (a) reacting a first amount of at least one aromatic compound with a first amount of a mixture of olefins having from about 8 to about 100 carbon atoms, in the presence of a strong acid catalyst, wherein the resulting product comprises at least about 60 weight percent of a 1,2,4-trialkylsubstituted aromatic compound; (b) sulfonating the product of (a); and (c) neutralizing the product of (b) with an alkali or alkaline earth metal hydroxide or ammonia.

  制备合成石油磺酸的过程包括：(a) 在强酸催化剂的存在下，将至少一种芳香化合物的第一量与含有约8至约100个碳原子的烯烃混合物的第一量反应，其中所得产物至少包含约60重量百分比的1,2,4-三烷基取代芳香化合物；(b) 对(a)步骤的产物进行磺化；以及(c) 用碱金属或碱土金属氢氧化物或氨中和(b)步骤的产物。
• Method of making a synthetic alkylaryl sulfonate
  申请人：Campbell Curt B.

  公开号：US20070282125A1

  公开（公告）日：2007-12-06

  A process for preparing a synthetic petroleum sulfonate comprising (a) reacting a first amount of at least one aromatic compound with a first amount of a mixture of olefins having from about 8 to about 100 carbon atoms, in the presence of a strong acid catalyst; (b) reacting the product of (a) with an additional amount of at least one aromatic compound and an additional amount of strong acid catalyst and, optionally, with an additional amount of a mixture of olefins selected from olefins having from about 8 to about 100 carbon atoms, in the presence of a strong acid catalyst, wherein the resulting product comprises at least about 80 weight percent of a 1,2,4-trialkylsubstituted aromatic compound; (c) sulfonating the product of (b); and (c) neutralizing the product of (b) with an alkali or alkaline earth metal hydroxide or ammonia.

  制备合成石油磺酸盐的过程包括：(a) 在强酸催化剂的存在下，将至少一种芳香化合物的第一量与具有约8至约100个碳原子的烯烃混合物的第一量反应；(b) 将(a)的产物与至少一种芳香化合物的额外量和额外的强酸催化剂的额外量反应，并在强酸催化剂的存在下，可选地与选择自具有约8至约100个碳原子的烯烃的烯烃混合物的额外量反应，其中所得产物包含至少约80重量百分比的1,2,4-三烷基取代芳香化合物；(c) 对(b)的产物进行磺化；以及(d) 用碱或碱土金属氢氧化物或氨中和(b)的产物。
• Method and composition for rejuvinating cells, tissues organs, hair and nails
  申请人：——

  公开号：US20020188015A1

  公开（公告）日：2002-12-12

  In one embodiment, the present invention relates to compounds and compositions including pharmaceutical compositions containing the compounds and associated methods that uncouple sugar-mediated coupling of proteins, lipids, nucleic acids, and other biomaterials, and any combination thereof. In another embodiment, the compositions and associated methods have utility in vivo to reduce the deleterious effects of sugar-mediated coupling processes in an organism, when the organism is exposed to the compound or composition internally, by ingestion, transdermal application, or other means. In yet another embodiment, the compositions and associated methods are useful for the ex-vivo treatment of organs, cells and tissues and external treatment of hair, nails and skin to rejuvenate them by changing deformability and increase the tissue diffusion coefficient. In a further embodiment, the present invention relates to novel compounds and pharmaceutical compositions.

  在一个实施例中，本发明涉及包含药物组合物的化合物和组合物，其中药物组合物包含这些化合物，并且相关方法解耦蛋白质、脂质、核酸和其他生物材料以及它们的任意组合的糖介导偶联。在另一个实施例中，这些组合物和相关方法在体内具有实用性，用于减少生物体暴露于内部摄入、经皮应用或其他方式的化合物或组合物时，糖介导偶联过程的有害影响。在另一个实施例中，这些组合物和相关方法对器官、细胞和组织的离体处理以及头发、指甲和皮肤的外部处理具有用处，通过改变可变性和增加组织扩散系数来使它们恢复活力。在另一个实施例中，本发明涉及新颖的化合物和药物组合物。
• Copper-Catalyzed Asymmetric Cyanation of Alkenes via Carbonyl-Assisted Coupling of Alkyl-Substituted Carbon-Centered Radicals
  作者：Song Zhou、Guoyu Zhang、Liang Fu、Pinhong Chen、Yibiao Li、Guosheng Liu

  DOI：10.1021/acs.orglett.0c02085

  日期：2020.8.21

  the first copper-catalyzed asymmetric cyanation of alkyl-substituted alkenes has been developed. The reaction, featuring mild reaction conditions and excellent functional group compatibilities, provides an easy access to a wide array of structurally diverse enantioenriched alkyl nitriles in good yields. Notably, an unstable carbon-centered radical generated by trifluoromethyl radical addition across terminal

  基于铜催化的自由基中继策略，已经开发了烷基取代的烯烃的第一个铜催化的不对称氰化反应。该反应具有温和的反应条件和出色的官能团相容性，可轻松获得大量结构多样的对映体富集的烷基腈，收率很高。值得注意的是，通过在末端烯烃上的三氟甲基自由基加成而产生的不稳定的以碳为中心的自由基可以在羰基的帮助下被手性L * Cu（CN）2对映选择性地捕获。