N-(m-nitrophenyl)(m-phenoxyphenyl)methanimine | 300695-20-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(m-nitrophenyl)(m-phenoxyphenyl)methanimine
• 英文别名: N-(3-Phenoxybenzylidene)-3-nitroaniline；N-(3-nitrophenyl)-1-(3-phenoxyphenyl)methanimine
• CAS: 300695-20-9
• 化学式: C₁₉H₁₄N₂O₃
• 分子量: 318.332
• InChiKey: XNPUVXPVFGGDRE-UHFFFAOYSA-N

物化性质

• 沸点：
  491.9±30.0 °C(Predicted)
• 密度：
  1.18±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  67.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N-(m-nitrophenyl)(m-phenoxyphenyl)methanimine 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 5.0h， 以68%的产率得到N-(m-nitrophenyl)-m-phenoxybenzylamine
  参考文献：
  名称：

  Synthesis and Reactions of Azomethines Containing a m-Phenoxyphenyl Group: II. Chemical Transformations >of N-Aryl-m-phenoxyphenylmethanimines and Arylhydrazones of m-Phenoxybenzaldehyde

  摘要：

  Chemical transformations of N-aryl-m-phenoxyphenylmethanimines and m-phenoxybenzaidehyde arythydrazones were studied by examples of reduction thereof with complex metal hydrides and reactions with dialkyl phosphates and dialkyl phosphites.

  DOI：

  10.1023/b:rujo.0000043714.74375.30
• 作为产物：
  描述：

  间苯氧基苯甲醛 、 间硝基苯胺 反应 2.0h， 以66%的产率得到N-(m-nitrophenyl)(m-phenoxyphenyl)methanimine
  参考文献：
  名称：

  含间苯氧基苯基的席夫碱的合成与反应：I. N-芳基-间苯氧基苄叉亚胺和N-芳基-N'-（间苯氧基苄叉基）肼

  摘要：

  Condensation of m-phenoxybenzaldehyde with aromatic amines and hydrazines gave the corresponding Schiff bases and m-phenoxybenzaldehyde arylhydrazones. The products are promising as biologically active substances, polyfunctional additives to rubber compounds, and inhibitors of acid corrosion.

  DOI：

  10.1023/a:1012443600020

文献信息

• Popov, Yu. V.; Korchagina, T. K.; Chicherina, G. V., Russian Journal of General Chemistry, 2000, vol. 70, # 12, p. 1935 - 1936
  作者：Popov, Yu. V.、Korchagina, T. K.、Chicherina, G. V.

  DOI：——

  日期：——
• Synthesis and Reactions of Azomethines Containing a m-Phenoxyphenyl Group: II. Chemical Transformations >of N-Aryl-m-phenoxyphenylmethanimines and Arylhydrazones of m-Phenoxybenzaldehyde
  作者：Yu. V. Popov、T. K. Korchagina、G. V. Chicherina、T. A. Ermakova

  DOI：10.1023/b:rujo.0000043714.74375.30

  日期：2004.5

  Chemical transformations of N-aryl-m-phenoxyphenylmethanimines and m-phenoxybenzaidehyde arythydrazones were studied by examples of reduction thereof with complex metal hydrides and reactions with dialkyl phosphates and dialkyl phosphites.
• ——
  作者：Yu. V. Popov、T. K. Korchagina、G. V. Chicherina

  DOI：10.1023/a:1012443600020

  日期：——

  Condensation of m-phenoxybenzaldehyde with aromatic amines and hydrazines gave the corresponding Schiff bases and m-phenoxybenzaldehyde arylhydrazones. The products are promising as biologically active substances, polyfunctional additives to rubber compounds, and inhibitors of acid corrosion.