1-(4-aminophenyl)-1-(3,5-dimethyl-4-aminophenyl)-1-(6-oxo-6H-dibenz[c,e][1,2]oxaphosphorin-6-yl)ethane | 1238895-57-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4-aminophenyl)-1-(3,5-dimethyl-4-aminophenyl)-1-(6-oxo-6H-dibenz[c,e][1,2]oxaphosphorin-6-yl)ethane
• 英文别名: 4-[1-(4-Aminophenyl)-1-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl]-2,6-dimethylaniline；4-[1-(4-aminophenyl)-1-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)ethyl]-2,6-dimethylaniline
• CAS: 1238895-57-2
• 化学式: C₂₈H₂₇N₂O₂P
• 分子量: 454.508
• InChiKey: VKSUYTJFHSNEOK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  33
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  78.3
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 4-(1-金刚烷基)苯酚 、 1-(4-aminophenyl)-1-(3,5-dimethyl-4-aminophenyl)-1-(6-oxo-6H-dibenz[c,e][1,2]oxaphosphorin-6-yl)ethane 以 乙醇 、 甲苯 为溶剂， 反应 8.0h， 以70%的产率得到6-[1-[4-[6-(1-Adamantyl)-2,4-dihydro-1,3-benzoxazin-3-yl]-3,5-dimethylphenyl]-1-[4-[6-(1-adamantyl)-2,4-dihydro-1,3-benzoxazin-3-yl]phenyl]ethyl]benzo[c][2,1]benzoxaphosphinine 6-oxide
  参考文献：
  名称：

  Low-k, flame-retardant, bi-functional benzoxazine and method for making the same

  摘要：

  揭示了一种制备低介电常数、阻燃、双官能团苯并噁嗪的方法。该方法包括将具有各种官能团的磷酸二胺、酚基金刚烷和多聚甲醛在72°C至88°C的溶剂中溶解7至9小时，然后冷却并将溶液引入正己烷中，以分离低介电常数、阻燃、磷酸酯、双官能团苯并噁嗪的步骤。

  公开号：

  US08648164B2
• 作为产物：
  描述：

  4-氨基苯乙酮 、 2,6-二甲基苯胺 、 9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物 在 对甲苯磺酸 作用下， 反应 24.0h， 以75%的产率得到1-(4-aminophenyl)-1-(3,5-dimethyl-4-aminophenyl)-1-(6-oxo-6H-dibenz[c,e][1,2]oxaphosphorin-6-yl)ethane
  参考文献：
  名称：

  Organo-soluble phosphinated polyimides from asymmetric diamines

  摘要：

  Two new asymmetric diamines (1-2) were prepared via a facile, one-pot procedure. Based on diamine (1-2), a series of asymmetric polyimides (3-4) were prepared in NMP/xylene by high-temperature solution polymerization. The resulting polyimides are readily soluble in some organic solvents, and can be solution casted into flexible and creasable films. An intramolecular charge complex mechanism was proposed to the structure optical transparency relationship. Polyimides 3-4 display high-Tg (319-401 degrees C), high moduli (2.40-7.20 GPa), moderate coefficient of thermal expansion (38-53 ppm/degrees C), and excellent flame retardancy. These results show that the introduction of the asymmetric structure is an effective way to improve organo-solubility while maintaining thermal properties. Because of these properties, polyimides 3-4 can be considered as excellent high-Tg and flame-retardant materials for microelectronic applications. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2010.05.059

文献信息

• Low-k, flame-retardant, bi-functional benzoxazine and method for making the same
  申请人：Su Wen-Chiung

  公开号：US08648164B2

  公开（公告）日：2014-02-11

  Disclosed is a method for making a low-k, flame-retardant, bi-functional benzoxazine. The method includes the steps of dissolving phosphoric diamine with various functional groups, phenolic adamantane and paraformaldehyde in a solvent at 72° C. to 88° C. for 7 to 9 hours, and cooling and introducing the solution in n-hexane to separate the low-k, flame-retardant, phosphoric, bi-functional benzoxazine.

  揭示了一种制备低介电常数、阻燃、双官能团苯并噁嗪的方法。该方法包括将具有各种官能团的磷酸二胺、酚基金刚烷和多聚甲醛在72°C至88°C的溶剂中溶解7至9小时，然后冷却并将溶液引入正己烷中，以分离低介电常数、阻燃、磷酸酯、双官能团苯并噁嗪的步骤。
• Organo-soluble phosphinated polyimides from asymmetric diamines
  作者：Ching Hsuan Lin、Sheng Lung Chang、Li An Peng、Siao Ping Peng、Yu Hao Chuang

  DOI：10.1016/j.polymer.2010.05.059

  日期：2010.8

  Two new asymmetric diamines (1-2) were prepared via a facile, one-pot procedure. Based on diamine (1-2), a series of asymmetric polyimides (3-4) were prepared in NMP/xylene by high-temperature solution polymerization. The resulting polyimides are readily soluble in some organic solvents, and can be solution casted into flexible and creasable films. An intramolecular charge complex mechanism was proposed to the structure optical transparency relationship. Polyimides 3-4 display high-Tg (319-401 degrees C), high moduli (2.40-7.20 GPa), moderate coefficient of thermal expansion (38-53 ppm/degrees C), and excellent flame retardancy. These results show that the introduction of the asymmetric structure is an effective way to improve organo-solubility while maintaining thermal properties. Because of these properties, polyimides 3-4 can be considered as excellent high-Tg and flame-retardant materials for microelectronic applications. (C) 2010 Elsevier Ltd. All rights reserved.