2,3,5,6-tetramethyl-N-(pyridin-2-ylethylidene)benzene-1,4-diamine | 870633-65-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3,5,6-tetramethyl-N-(pyridin-2-ylethylidene)benzene-1,4-diamine
• 英文别名: 2,3,5,6-tetramethyl-N-(1-pyridin-2-ylethylidene)-benzene-1,4-diamine；2,3,5,6-tetramethyl-4-(1-pyridin-2-ylethylideneamino)aniline
• CAS: 870633-65-1
• 化学式: C₁₇H₂₁N₃
• 分子量: 267.374
• InChiKey: VJBANBBZHMAUEN-UHFFFAOYSA-N

物化性质

• 沸点：
  452.7±45.0 °C(Predicted)
• 密度：
  1.06±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  51.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  吡啶-2-甲醛 、 2,3,5,6-tetramethyl-N-(pyridin-2-ylethylidene)benzene-1,4-diamine 在 甲酸 作用下， 以 乙醇 为溶剂， 以51%的产率得到N-(1-(pyridin-2-yl)ethylidene)-N'-((pyridin-2-yl)methylene)-2,3,5,6-tetramethylbenzene-1,4-diamine
  参考文献：
  名称：

  [EN] TRANSITION METAL COMPOUNDS FOR OLEFIN POLYMERIZATION AND OLIGOMERIZATION
  [FR] COMPOSES METALLIQUES DE TRANSITION POUR LA POLYMERISATION D'OLEFINES ET L'OLIGOMERISATION

  摘要：

  这项发明涉及由式(I)表示的新过渡金属催化剂化合物，其中：M和M'分别是8、9、10或11族过渡金属，优选为Ni、Co、Pd、Cu或Fe；每个R基分别是氢，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基，且可选地，相邻的R基可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香环或多环取代基；R'是氢，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基，且可选地，相邻的R基可以与R'结合在一起形成取代或未取代的饱和、部分不饱和或芳香环或多环取代基；每个X基分别是氢，卤素，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基，且可选地，相邻的X基可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香环或多环取代基；m和m'分别为0、1、2或3；z和z'分别为0、1、2或3；N为氮；Q为氢，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基；Q'为氢，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基；L为烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基。

  公开号：

  WO2005118605A1
• 作为产物：
  描述：

  2-乙酰基吡啶 、 四甲基对苯二胺 在 甲酸 甲苯 、 氯仿 、 正己烷 作用下， 以 甲苯 为溶剂， 反应 72.5h， 以to give 2,3,5,6-tetramethyl-N-(1-pyridin-2-ylethylidene)-benzene-1,4-diamine as a brown solid (0.31 g, 45%)的产率得到2,3,5,6-tetramethyl-N-(pyridin-2-ylethylidene)benzene-1,4-diamine
  参考文献：
  名称：

  Transition metal compounds for olefin polymerization and oligomerization

  摘要：

  本发明涉及一种新的过渡金属催化剂化合物，其表示为公式(I)：其中：M和M'分别是8、9、10或11族的过渡金属，优选为Ni、Co、Pd、Cu或Fe；每个R基团分别是氢、或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等，且相邻的R基团可以连接在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；R'是氢或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等，且相邻的R基团可以与R'连接在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；每个X基团分别是氢、卤素或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等，且相邻的X基团可以连接在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；m和m'分别为0、1、2或3；z和z'分别为0、1、2或3；N为氮；Q为氢或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等；Q'为氢或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等；L为碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等。

  公开号：

  US07741240B2

文献信息

• Transition Metal Compounds for Olefin Polymerization and Oligomerization
  申请人：Solan A. Gregory

  公开号：US20080033125A1

  公开（公告）日：2008-02-07

  This invention relates to new transition metal catalyst compounds represented by the formula (I): where: M and M′ are, independently, a group 8, 9, 10 or 11 transition metal, preferably Ni, Co, Pd, Cu or Fe; each R group is, independently, is, hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; R′ is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together with R′ to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; each X group is, independently, is, hydrogen, a halogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent X groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; m and m′ are, independently, 0, 1, 2, or 3; z and z′ are, independently, 0, 1, 2, or 3; N is nitrogen; Q is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents; Q′ is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl; substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents; and L is a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent.

  本发明涉及由公式（I）表示的新过渡金属催化剂化合物：其中：M和M'分别是8、9、10或11族过渡金属，优选为Ni、Co、Pd、Cu或Fe；每个R基团独立地是氢或烃基、取代烃基、卤代烃基、取代卤代烃基、硅基烃基、取代硅基烃基、锗基烃基或取代锗基烃基取代基，并且选择性地，相邻的R基团可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；R'是氢或烃基、取代烃基、卤代烃基、取代卤代烃基、硅基烃基、取代硅基烃基、锗基烃基或取代锗基烃基取代基，并且选择性地，相邻的R基团可以与R'结合在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；每个X基团独立地是氢、卤素或烃基、取代烃基、卤代烃基、取代卤代烃基、硅基烃基、取代硅基烃基、锗基烃基或取代锗基烃基取代基，并且选择性地，相邻的X基团可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；m和m'独立地为0、1、2或3；z和z'独立地为0、1、2或3；N为氮；Q为氢或烃基、取代烃基、卤代烃基、取代卤代烃基、硅基烃基、取代硅基烃基、锗基烃基或取代锗基烃基取代基；Q'为氢或烃基、取代烃基、卤代烃基、取代卤代烃基、硅基烃基、取代硅基烃基、锗基烃基或取代锗基烃基取代基；以及L为烃基、取代烃基、卤代烃基、取代卤代烃基、硅基烃基、取代硅基烃基、锗基烃基或取代锗基烃基取代基。
• [EN] TRANSITION METAL COMPOUNDS FOR OLEFIN POLYMERIZATION AND OLIGOMERIZATION<br/>[FR] COMPOSES METALLIQUES DE TRANSITION POUR LA POLYMERISATION D'OLEFINES ET L'OLIGOMERISATION
  申请人：EXXONMOBIL CHEM PATENTS INC

  公开号：WO2005118605A1

  公开（公告）日：2005-12-15

  This invention relates to new transition metal catalyst compounds represented by the formula (I): where: M and M' are, independently, a group 8, 9, 10 or 11 transition metal, preferably Ni, Co, Pd, Cu or Fe; each R group is, independently, is, hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; R' is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together with R' to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; each X group is, independently, is, hydrogen, a halogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted sililcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent X groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; m and m’ are, independently, 0, 1, 2, or 3; z and z’ are, independently, 0, 1, 2, or 3; N is nitrogen; Q is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents; Q’ is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl or substituted germylcarbyl substituents; and L is a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent.

  这项发明涉及由式(I)表示的新过渡金属催化剂化合物，其中：M和M'分别是8、9、10或11族过渡金属，优选为Ni、Co、Pd、Cu或Fe；每个R基分别是氢，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基，且可选地，相邻的R基可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香环或多环取代基；R'是氢，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基，且可选地，相邻的R基可以与R'结合在一起形成取代或未取代的饱和、部分不饱和或芳香环或多环取代基；每个X基分别是氢，卤素，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基，且可选地，相邻的X基可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香环或多环取代基；m和m'分别为0、1、2或3；z和z'分别为0、1、2或3；N为氮；Q为氢，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基；Q'为氢，或烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基；L为烃基，取代烃基，卤代烃基，取代卤代烃基，硅烃基，取代硅烃基，锗烃基，或取代锗烃基取代基。
• Transition metal compounds for olefin polymerization and oligomerization
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US07741240B2

  公开（公告）日：2010-06-22

  This invention relates to new transition metal catalyst compounds represented by the formula (I): where: M and M′ are, independently, a group 8, 9, 10 or 11 transition metal, preferably Ni, Co, Pd, Cu or Fe; each R group is, independently, is, hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; R′ is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent R groups may join together with R′ to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; each X group is, independently, is, hydrogen, a halogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents, and optionally, adjacent X groups may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; m and m′ are, independently, 0, 1, 2, or 3; z and z′ are, independently, 0, 1, 2, or 3; N is nitrogen; Q is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents; Q′ is hydrogen, or a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituents; and L is a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent.

  本发明涉及一种新的过渡金属催化剂化合物，其表示为公式(I)：其中：M和M'分别是8、9、10或11族的过渡金属，优选为Ni、Co、Pd、Cu或Fe；每个R基团分别是氢、或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等，且相邻的R基团可以连接在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；R'是氢或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等，且相邻的R基团可以与R'连接在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；每个X基团分别是氢、卤素或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等，且相邻的X基团可以连接在一起形成取代或未取代的饱和、部分不饱和或芳香族或多环取代基；m和m'分别为0、1、2或3；z和z'分别为0、1、2或3；N为氮；Q为氢或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等；Q'为氢或取代基的碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等；L为碳氢基、取代基的卤代碳氢基、取代基的卤代硅烷基、取代基的锗烷基等。