2-benzyl-N-(pyridine-2-ylmethylene)aniline | 400059-95-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-benzyl-N-(pyridine-2-ylmethylene)aniline
• 英文别名: N-(2-benzylphenyl)-1-pyridin-2-ylmethanimine
• CAS: 400059-95-2
• 化学式: C₁₉H₁₆N₂
• 分子量: 272.349
• InChiKey: LNVOVJVRSFQSND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  25.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-benzyl-N-(pyridine-2-ylmethylene)aniline 、 manganese(ll) chloride 以 四氢呋喃 为溶剂， 反应 48.0h， 以75%的产率得到bis{2-[(2-(phenyl-2-benzyl)imino)methyl]pyridine}Mn(II)Cl2
  参考文献：
  名称：

  Synthesis and crystal structure determination of Mn(II) Schiff base complexes and their performance in ethene polymerization

  摘要：

  Mn(II) complexes 1-10, of which eight are novel, were prepared in high yields by reacting MnCl2 with bidentate N,N'-imine-pyridine and N,N'-imine-quinoline-type donor ligands having different kinds of chemical modifications. The complexes were fully characterized by elemental analysis, mass spectrometry and IR spectroscopy. Crystal structures of 6, 7 and 9 were determined by X-ray crystallography and the results showed that 6 has a dimeric square-pyramidal geometry, whereas 7 and 9 have distorted octahedral structures. Magnetic studies on the high spin complexes 6 and 9 showed that the former exhibits a weak intramolecular antiferromagnetic interaction through the chloride-bridging ligands with a magnetic exchange coupling J = -0.46(6) cm(-1), whereas the latter, as expected for its mononuclear structure, only shows very weak intermolecular interactions and/or zero-field splitting effects. All the complexes were activated with methylaluminoxane and investigated under low pressure (5 bar) for ethene polymerization at 60 degrees C. Complexes 1 and 6-10 showed catalytic activity. The prepared polyethenes exhibited high molar masses (296000-399000 g/mol) and high melting temperatures (133-140 degrees C). The low molar mass distribution values of 2.15-2.55 indicated single-site polymerization behavior. (c) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.03.063
• 作为产物：
  描述：

  吡啶-2-甲醛 、 邻苄基苯胺 以 neat (no solvent) 为溶剂， 以80%的产率得到2-benzyl-N-(pyridine-2-ylmethylene)aniline
  参考文献：
  名称：

  Synthesis and crystal structure determination of Mn(II) Schiff base complexes and their performance in ethene polymerization

  摘要：

  Mn(II) complexes 1-10, of which eight are novel, were prepared in high yields by reacting MnCl2 with bidentate N,N'-imine-pyridine and N,N'-imine-quinoline-type donor ligands having different kinds of chemical modifications. The complexes were fully characterized by elemental analysis, mass spectrometry and IR spectroscopy. Crystal structures of 6, 7 and 9 were determined by X-ray crystallography and the results showed that 6 has a dimeric square-pyramidal geometry, whereas 7 and 9 have distorted octahedral structures. Magnetic studies on the high spin complexes 6 and 9 showed that the former exhibits a weak intramolecular antiferromagnetic interaction through the chloride-bridging ligands with a magnetic exchange coupling J = -0.46(6) cm(-1), whereas the latter, as expected for its mononuclear structure, only shows very weak intermolecular interactions and/or zero-field splitting effects. All the complexes were activated with methylaluminoxane and investigated under low pressure (5 bar) for ethene polymerization at 60 degrees C. Complexes 1 and 6-10 showed catalytic activity. The prepared polyethenes exhibited high molar masses (296000-399000 g/mol) and high melting temperatures (133-140 degrees C). The low molar mass distribution values of 2.15-2.55 indicated single-site polymerization behavior. (c) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.03.063

文献信息

• Synthesis and crystal structure determination of Mn(II) Schiff base complexes and their performance in ethene polymerization
  作者：Anjali Sood、Minna T. Räisänen、Erkki Aitola、Ahlam Sibaouih、Enrique Colacio、Markku Ahlgren、Martin Nieger、Timo Repo、Markku Leskelä

  DOI：10.1016/j.poly.2013.03.063

  日期：2013.6

  Mn(II) complexes 1-10, of which eight are novel, were prepared in high yields by reacting MnCl2 with bidentate N,N'-imine-pyridine and N,N'-imine-quinoline-type donor ligands having different kinds of chemical modifications. The complexes were fully characterized by elemental analysis, mass spectrometry and IR spectroscopy. Crystal structures of 6, 7 and 9 were determined by X-ray crystallography and the results showed that 6 has a dimeric square-pyramidal geometry, whereas 7 and 9 have distorted octahedral structures. Magnetic studies on the high spin complexes 6 and 9 showed that the former exhibits a weak intramolecular antiferromagnetic interaction through the chloride-bridging ligands with a magnetic exchange coupling J = -0.46(6) cm(-1), whereas the latter, as expected for its mononuclear structure, only shows very weak intermolecular interactions and/or zero-field splitting effects. All the complexes were activated with methylaluminoxane and investigated under low pressure (5 bar) for ethene polymerization at 60 degrees C. Complexes 1 and 6-10 showed catalytic activity. The prepared polyethenes exhibited high molar masses (296000-399000 g/mol) and high melting temperatures (133-140 degrees C). The low molar mass distribution values of 2.15-2.55 indicated single-site polymerization behavior. (c) 2013 Elsevier Ltd. All rights reserved.