1,4-diiodo-1,3-cyclohexadiene | 68882-61-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,4-diiodo-1,3-cyclohexadiene
• 英文别名: 1,4-Diiodcyclohexa-1,3-dien；1,4-diiodocyclohexa-1,3-diene
• CAS: 68882-61-1
• 化学式: C₆H₆I₂
• 分子量: 331.923
• InChiKey: SSWGKORDSUTCHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,4-diiodo-1,3-cyclohexadiene 在 二氮烯 作用下， 反应 2.0h， 生成 2,5-Dimethylene-bicyclo[4.2.0]octane
  参考文献：
  名称：

  Bicyclo[4.2.2]deca-1,5-diene, a bridgehead diene

  摘要：

  DOI：

  10.1021/ja00492a050
• 作为产物：
  描述：

  cyclohexane-1,4-dione-dihydrazone 在 碘 、 三乙胺 作用下， 生成 1,4-diiodo-1,3-cyclohexadiene
  参考文献：
  名称：

  Bicyclo[4.2.2]deca-1,5-diene, a bridgehead diene

  摘要：

  DOI：

  10.1021/ja00492a050

文献信息

• Studies on the oxidation of hydrazones with iodine and with phenylselenenyl bromide in the presence of strong organic bases; an improved procedure for the synthesis of vinyl iodides and phenyl-vinyl selenides
  作者：Derek H.R. Barton、George Bashiardes、Jean-Louis Fourrey

  DOI：10.1016/s0040-4020(01)85102-4

  日期：1988.1

  The oxidation of hydrazones by iodine in the presence of strong organic bases (guanidines) has been studied. Improved yields of vinyl iodides can be obtained by inverse addition using dry solvents and with a final heating period where appropriate. The reaction has been extended to various dihydrazones with interesting results.

  已经研究了在强有机碱（胍）存在下碘化对oxidation的氧化作用。可以通过使用干燥溶剂进行逆向添加并在适当的时候进行最终加热来提高碘乙烯的收率。该反应已扩展到各种二hydr，结果令人感兴趣。
• WISEMAN J. R.; VANDERBILT J. J., J. AMER. CHEM. SOC., 1978, 100, NO 24, 7730-7731
  作者：WISEMAN J. R.、 VANDERBILT J. J.

  DOI：——

  日期：——
• Microporous Polymers, Methods for the Preparation Thereof, and Uses Thereof
  申请人：Cooper Andrew

  公开号：US20100240781A1

  公开（公告）日：2010-09-23

  A method for preparing a conjugated microporous polymer comprises the coupling of an alkynyl aryl monomer having a plurality of terminal alkyne groups with an iodo- or bromo-aryl monomer having a plurality of halogen atoms in the presence of a palladium (0) catalyst. The conjugated microporous polymer comprises nodes comprising at least one aryl unit and struts comprising at least one alkyne unit and at least one aryl unit, wherein a node is bonded from its aryl unit or units to at least two struts via alkyne units. Such polymers are useful in numerous areas such as separations, controlled release, gas storage and supports for catalysts.
• ORGANIC EL ELEMENT AND METHOD FOR PRODUCING SAME
  申请人：Panasonic Corporation

  公开号：US20130092918A1

  公开（公告）日：2013-04-18

  The present invention is to provide a method of favorably forming an organic EL device with the inverted structure by the wet process. On that account, an organic EL device includes a cathode, an electron injection layer, a light emitting layer, a hole transport layer, a hole injection layer, an anode are formed in this order on a substrate. The electron injection layer is formed by applying ink between banks and drying the ink. The ink is formed by dissolving a polymer compound having an organic phosphine oxide skeleton in an alcohol solvent. The light emitting layer is formed by applying ink between components of the bank and the drying the ink. The ink is formed by dissolving material for light emitting layer such as polyphenylene vinylene (PPV) derivative or polyfluorene derivative in a nonpolar solvent.
• US8809409B2
  申请人：——

  公开号：US8809409B2

  公开（公告）日：2014-08-19