2-propyl-anthraquinone | 63690-55-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2-propyl-anthraquinone
• 英文别名: 2-Propyl-anthrachinon；9.10-Dioxo-2-propyl-9.10-dihydro-anthracen；2-Propylanthracene-9,10-dione
• CAS: 63690-55-1
• 化学式: C₁₇H₁₄O₂
• 分子量: 250.297
• InChiKey: ZPQUFYIADDJOEF-UHFFFAOYSA-N

物化性质

• 熔点：
  98-99 °C(Solv: ethanol (64-17-5))
• 沸点：
  425.5±35.0 °C(Predicted)
• 密度：
  1.201±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-propyl-anthraquinone 在 硫酸 、 硝酸 作用下， 生成 1-nitro-2-propyl-anthraquinone
  参考文献：
  名称：

  Scholl; Potschiwauscheg; Lenko, Monatshefte fur Chemie, 1911, vol. 32, p. 700

  摘要：

  DOI：
• 作为产物：
  描述：

  2-丙基-蒽酮 在 溴 、 溶剂黄146 作用下， 生成 2-propyl-anthraquinone
  参考文献：
  名称：

  Scholl; Potschiwauscheg; Lenko, Monatshefte fur Chemie, 1911, vol. 32, p. 700

  摘要：

  DOI：

文献信息

• PREPARATION OF DIAZO AND DIAZONIUM COMPOUNDS
  申请人：Raines Ronald Thaddeus

  公开号：US20100125132A1

  公开（公告）日：2010-05-20

  A method for making diazo-compounds, diazonium salts thereof and other protected forms of these compounds. Diaz-compounds are prepared by reaction of a tertiary phosphine reagent carrying a reactive carbonyl group with an azide. The reaction can also generate an acyl triazene which can be converted thermally or by addition of base to form the diazo-compound or the acyl triazene can be isolated. The method is particularly useful for conversion of azides carrying one or more electron withdrawing groups to diazo-compounds. The method can be carried out in aqueous medium under mild conditions and is particularly useful for conversion of azido sugars to diazo-compound and diazonium salts thereof under physiological conditions. Tertiary phosphine reagents, particularly those that are water-soluble, and precursors for preparation of the reagents are provided.

  一种制备重氮化合物、其重氮盐和这些化合物的其他保护形式的方法。通过将携带反应性羰基基团的三级膦试剂与偶氮化物反应来制备重氮化合物。该反应还可以生成酰基三氮烯，可以通过热转化或加入碱来形成重氮化合物，或者可以分离出酰基三氮烯。该方法特别适用于将携带一个或多个电子吸引基团的偶氮化物转化为重氮化合物。该方法可以在温和条件下在水性介质中进行，并且特别适用于在生理条件下将偶氮糖转化为重氮化合物和其重氮盐。提供了三级膦试剂，特别是那些水溶性的试剂，以及用于制备这些试剂的前体。
• Acid- and radical-generating agent and method for generating acid and radical
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：US10451967B2

  公开（公告）日：2019-10-22

  It is a subject of the present invention to provide an acid- and radical-generating agent which has high sensitivity to an active energy ray having a wavelength of around 300 to 450 nm, and can exert both high acid-generating performance and high radical-generating performance, and has heat resistance; and a method for generating an acid and a radical. The present invention relates to a compound represented by the general formula (A); an acid- and radical-generating agent comprising the compound; and a method for generating an acid and a radical: wherein n pieces of R1 each independently represent an alkyl group, which may have a specific functional group in the chain, or in which a hydrogen atom may be substituted by a halogen atom; an alkoxy group, in which a hydrogen atom may be substituted by a halogen atom; an aryl group or an aryloxy group, in which a hydrogen atom may be substituted by a halogen atom, an alkyl group or a haloalkyl group; or an arylalkyl group or an arylalkyloxy group, in which a hydrogen atom may be substituted by a halogen atom, an alkyl group or a haloalkyl group; n pieces of R2 and R3 each independently represent a hydrogen atom, an alkyl group or an alkoxycarbonyl group; R4 to R7 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an alkenyl group, an aryl group, an alkoxycarbonyl group, a dialkylamino group or a nitro group; Y represents an oxygen atom, a sulfur atom, or a carbonyl group; n pieces of Z each independently represent a sulfonyl group or an alkoxyphosphoryl group; n represents 1 or 2.

  本发明的一个目的是提供一种对波长约为300至450纳米的活性能量射线具有高灵敏度的酸和自由基生成剂，能够发挥高酸生成性能和高自由基生成性能，并具有耐热性；以及一种生成酸和自由基的方法。本发明涉及一种由通式（A）表示的化合物；包括该化合物的酸和自由基生成剂；以及生成酸和自由基的方法：其中n个R1分别独立表示一种烷基基团，该烷基基团可能在链中具有特定的功能基团，或者氢原子可能被卤原子取代；一种烷氧基团，其中氢原子可能被卤原子取代；一种芳基或芳氧基，其中氢原子可能被卤原子，烷基或卤代烷基取代；或一种芳基烷基或芳基氧基，其中氢原子可能被卤原子，烷基或卤代烷基取代；n个R2和R3分别独立表示氢原子，烷基基团或烷氧羰基团；R4到R7分别独立表示氢原子，卤原子，烷基基团，烷氧基团，烯基基团，芳基，烷氧羰基团，二烷基氨基团或硝基；Y表示氧原子，硫原子或羰基；n个Z分别独立表示磺酰基或烷氧基磷酰基；n表示1或2。
• [EN] PROCESS FOR MANUFACTURING A SUBSTITUTED CYCLOHEXANECARBONITRILE<br/>[FR] PROCÉDÉ DE FABRICATION D'UN CYCLOHEXANECARBONITRILE SUBSTITUÉ
  申请人：SOLVAY

  公开号：WO2021048364A1

  公开（公告）日：2021-03-18

  A process for manufacturing a substituted cyclohexanecarbonitrile said process comprising the following steps: - reacting the corresponding substituted cyclohexanecarboxylic acid with thionyl chloride to make the corresponding acyl chloride; and simultaneously or subsequently - reacting the chloride with sulfonamide in sulfolane as solvent to make the substituted cyclohexanecarbonitrile.

  制造一种取代环己基碳腈的过程包括以下步骤：- 将相应的取代环己基羧酸与氯化亚磺酰反应，制得相应的酰氯；同时或随后 - 将氯化物与磺胺酰胺在硫代磺酸乙烷作为溶剂中反应，制得取代环己基碳腈。
• Photocurable resin composition
  申请人：National Starch and Chemical Investment Holding Corporation

  公开号：EP0549228A2

  公开（公告）日：1993-06-30

  A photocurable resin composition comprising the components (a), (b), (c) and (d) or the components (a), (b) and (e) of the following components : (a) a polymerisable compound having at least one ethylenically unsaturated group per molecule ; (b) a photopolymerisation initiator ; (c) at least one compound of the general formula : wherein R1 represents a hydrogen atom or lower alkyl group, A represents -0- or -NH-, R2 represents a C1-8-alkylene group, R3 represents a lower alkyl group, X represents a lower alkoxy group or halogen atom and m represents 0, 1 or 2, or at least one silane group-containing hydrolysis product thereof ; (d) at least one compound of the general formula : wherein R4 represents a glycidoxy or C5-6-epoxycycloalkyl group, R5 represents a C1-6-alkylene group, R6 represents a lower alkyl group, Y represents a lower alkoxy group or halogen atom and n represents 0, 1 or 2, or at least one silane group-containing hydrolysis product thereof ; (e) a silane group-containing hydrolysis product of a mixture of at least one compound of Formula (I) and at least one compound of Formula (II).

  一种光固化树脂组合物，包括组分(a)、(b)、(c)和(d)或组分 (a)、(b)和(e)的组分： (a) 可聚合化合物，每个分子至少有一个乙烯不饱和基团； (b) 一种光聚合引发剂； (c) 至少一种通式为 ： 其中 R1 代表氢原子或低级烷基，A 代表-0-或-NH-，R2 代表 C1-8-亚烷基，R3 代表低级烷基，X 代表低级烷氧基或卤原子，m 代表 0、1 或 2，或至少一种含硅烷基团的水解产物； (d) 至少一种通式为 ： 其中 R4 代表缩水甘油基或 C5-6 环氧环烷基，R5 代表 C1-6 烯基，R6 代表低级烷基，Y 代表低级烷氧基或卤素原子，n 代表 0、1 或 2，或至少一种含硅烷基的水解产物； (e) 至少一种式(I)化合物和至少一种式(II)化合物混合物的含硅烷基团的水解产物。
• UV-curable binder composition for magnetic recording media and photoinitiator mixture
  申请人：EMTEC MAGNETICS GmbH

  公开号：US20020022130A1

  公开（公告）日：2002-02-21

  A UV-curable binder composition, a coating material which contains such a binder composition, a photoiniator mixture suitable for use in these coating materials, and a magnetic recording medium which contains such a UV-curable coating material are described.

  本文描述了一种紫外线固化粘合剂组合物、一种含有这种粘合剂组合物的涂层材料、一种适用于这些涂层材料的光敏剂混合物，以及一种含有这种紫外线固化涂层材料的磁性记录介质。