2-chloromethylanthracene | 885-90-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2-chloromethylanthracene
• 英文别名: 2-(Chlor-methyl)-anthracen；Anthracene, 2-(chloromethyl)-；2-(chloromethyl)anthracene
• CAS: 885-90-5
• 化学式: C₁₅H₁₁Cl
• 分子量: 226.705
• InChiKey: SYEJHLQTTVTXCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-chloromethylanthracene 在 氢氧化钾 、 溶剂黄146 作用下， 以 1,4-二氧六环 、 苯 为溶剂， 生成
  参考文献：
  名称：

  Oligonucleotides having covalently linked anthracene at specific sugar residue: Differential binding to DNA and RNA and fluorescence properties

  摘要：

  Oligonucleotide 15 -mers containing 2-anthracenylmethyl groups at specific sugar residues have been synthesized from the 2'-anthracene-modified uridine. The modified oligonucleotides bind to both the complementary DNA and RNA segments. The induced CD at around 375 nm due to the anthracene chromophore was seen only for the anthracene-modified duplexes with DNA but not for those with RNA, which is in good agreement with the modification-induced stability of the duplexes. The oligonucleotide with anthracene at the specified sugar residue exhibits enhanced fluorescence upon binding to the complementary RNA segment.

  DOI：

  10.1016/0040-4039(95)01707-o
• 作为产物：
  描述：

  蒽醌-2-羧酸 在 lithium aluminium tetrahydride 、 氯化亚砜 、 sodium dithionite 、 铜 、 锌 作用下， 生成 2-chloromethylanthracene
  参考文献：
  名称：

  Oligonucleotides having covalently linked anthracene at specific sugar residue: Differential binding to DNA and RNA and fluorescence properties

  摘要：

  Oligonucleotide 15 -mers containing 2-anthracenylmethyl groups at specific sugar residues have been synthesized from the 2'-anthracene-modified uridine. The modified oligonucleotides bind to both the complementary DNA and RNA segments. The induced CD at around 375 nm due to the anthracene chromophore was seen only for the anthracene-modified duplexes with DNA but not for those with RNA, which is in good agreement with the modification-induced stability of the duplexes. The oligonucleotide with anthracene at the specified sugar residue exhibits enhanced fluorescence upon binding to the complementary RNA segment.

  DOI：

  10.1016/0040-4039(95)01707-o

文献信息

• BLUE LIGHT EMITTING POLYMER, METHOD FOR PRODUCING SAME, AND LIGHT EMITTING DEVICE UTILIZING SAME
  申请人：HIROSE ENGINEERING CO., LTD.

  公开号：EP1642920A1

  公开（公告）日：2006-04-05

  The objective of the present invention is to provide a blue light-emitting polymer capable of emitting blue light for a long time, and further excellent in durability, processes of producing the polymer, and a luminescent element. The blue light-emitting polymer of the invention has a repeating unit represented by formula (1): wherein each of Ar1 and Ar2 is a benzene derivative, a naphthalene derivative, or an anthracene derivative. The present invention also provides processes of producing the blue light-emitting polymer, and a luminescent element including the polymer.

  本发明的目的是提供一种能够长期发射蓝光的蓝色发光聚合物，并进一步提供优异的耐久性、聚合物生产工艺和发光元件。本发明的蓝色发光聚合物具有由式（1）表示的重复单元： 其中 Ar1 和 Ar2 各为苯衍生物、萘衍生物或蒽衍生物。本发明还提供了生产蓝色发光聚合物的工艺，以及包括该聚合物的发光元件。
• Blue light emitting polymer, method for producing same, and light emitting device utilizing same
  申请人：Nakaya Tadao

  公开号：US20060152144A1

  公开（公告）日：2006-07-13

  The objective of the present invention is to provide a blue light-emitting polymer capable of emitting blue light for a long time, and further excellent in durability, processes of producing the polymer, and a luminescent element. The blue light-emitting polymer of the invention has a repeating unit represented by formula (1): wherein each of Ar 1 and Ar 2 is a benzene derivative, a naphthalene derivative, or an anthracene derivative. The present invention also provides processes of producing the blue light-emitting polymer, and a luminescent element including the polymer.

  本发明的目的是提供一种能够长期发射蓝光的蓝色发光聚合物，并进一步提供优异的耐久性、聚合物生产工艺和发光元件。本发明的蓝色发光聚合物具有由式（1）表示的重复单元： 其中 Ar 1 和 Ar 2 是苯衍生物、萘衍生物或蒽衍生物。本发明还提供了生产蓝色发光聚合物的工艺，以及包括该聚合物的发光元件。
• Strained aromatic systems. Synthesis of cyclopropabenzocyclobutenes, cyclopropanaphthocylobutenes, and related compounds
  作者：Dariush Davalian、Peter J. Garratt、Wolfgang Koller、Muzammil M. Mansuri

  DOI：10.1021/jo01309a024

  日期：1980.10
• DAVALIAN D.; GAZZATT P. J.; KOLLER W.; MANSURI M. M., J. ORG. CHEM., 1980, 45, NO 21, 4183-4193
  作者：DAVALIAN D.、 GAZZATT P. J.、 KOLLER W.、 MANSURI M. M.

  DOI：——

  日期：——
• Polymer
  申请人：Hall Richard H.

  公开号：US20080171814A1

  公开（公告）日：2008-07-17

  An alpha-halocarbo aromatic monomer or comonomer and/or an allyl halide monomer or comonomer can be reacted with aluminum or an aluminum-containing catalyst to form a polymer.