3-[6-[2,7-Dibromo-9-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]fluoren-9-yl]hexoxymethyl]-3-ethyloxetane | 873661-49-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-[6-[2,7-Dibromo-9-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]fluoren-9-yl]hexoxymethyl]-3-ethyloxetane
• 英文别名: 3-[6-[2,7-dibromo-9-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]fluoren-9-yl]hexoxymethyl]-3-ethyloxetane
• CAS: 873661-49-5
• 化学式: C₃₇H₅₂Br₂O₄
• 分子量: 720.625
• InChiKey: PJZQAUVZSWQDCC-UHFFFAOYSA-N

物化性质

• 沸点：
  699.9±45.0 °C(Predicted)
• 密度：
  1.242±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.4
• 重原子数：
  43
• 可旋转键数：
  20
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,7-二溴芴 在 sodium hydride 、 potassium iodide 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 生成 3-[6-[2,7-Dibromo-9-[6-[(3-ethyloxetan-3-yl)methoxy]hexyl]fluoren-9-yl]hexoxymethyl]-3-ethyloxetane
  参考文献：
  名称：

  Excimer Formation by Electric Field Induction and Side Chain Motion Assistance in Polyfluorenes

  摘要：

  For poly(9,9-di(6-(2-(3-oxetanyl)butoxyl)hexyl)-2,7-fluorene) (POBOHF), measurements on field induction-thermally stimulated current (FI-TSC) and electroluminescence (EL) under a wide temperature range demonstrate that electric field induction (FI) accompanied by side chain motion can lead to a formation of excimers, which contribute to a growth of a green component in the EL spectrum. This phenomenon also happens to poly(9,9-di-n-octyl-2,7-fluorene) (PFO), especially under long-term operations with higher electric fields (1 x 10(6) V/cm), copolymers of OBOHF and FO (PF-1/1 and PF-1/3), and even cross-linked POBOHF. The higher polarity of the side chain in the polyfluorenes (PFs) can cause a more pronounced FI effect. For POBOHF, the green component can even dominate after a few cycles of device operation. Lowering the content of cross-linkable commoner in the copolymers from 50 to 25 mol % only moderately suppresses the formation of FI excimers.

  DOI：

  10.1021/ma051594z

文献信息

• Excimer Formation by Electric Field Induction and Side Chain Motion Assistance in Polyfluorenes
  作者：Hsin-Hung Lu、Ching-Yang Liu、Tzu-Hao Jen、Jin-Long Liao、Hao-En Tseng、Chih-Wei Huang、Ming-Chin Hung、Show-An Chen

  DOI：10.1021/ma051594z

  日期：2005.12.1

  For poly(9,9-di(6-(2-(3-oxetanyl)butoxyl)hexyl)-2,7-fluorene) (POBOHF), measurements on field induction-thermally stimulated current (FI-TSC) and electroluminescence (EL) under a wide temperature range demonstrate that electric field induction (FI) accompanied by side chain motion can lead to a formation of excimers, which contribute to a growth of a green component in the EL spectrum. This phenomenon also happens to poly(9,9-di-n-octyl-2,7-fluorene) (PFO), especially under long-term operations with higher electric fields (1 x 10(6) V/cm), copolymers of OBOHF and FO (PF-1/1 and PF-1/3), and even cross-linked POBOHF. The higher polarity of the side chain in the polyfluorenes (PFs) can cause a more pronounced FI effect. For POBOHF, the green component can even dominate after a few cycles of device operation. Lowering the content of cross-linkable commoner in the copolymers from 50 to 25 mol % only moderately suppresses the formation of FI excimers.