β-phenylethyl-α-amino-β-phenylethylamine | 1338566-34-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: β-phenylethyl-α-amino-β-phenylethylamine
• 英文别名: 2-phenyl-1-N'-(2-phenylethyl)ethane-1,1-diamine
• CAS: 1338566-34-9
• 化学式: C₁₆H₂₀N₂
• 分子量: 240.348
• InChiKey: BBVIQZOBQGMVNJ-UHFFFAOYSA-N

物化性质

• 沸点：
  385.3±30.0 °C(Predicted)
• 密度：
  1.050±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.35
• 重原子数：
  18.0
• 可旋转键数：
  6.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  38.05
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  苯乙腈 在 30% Ni/C 、 氢气 作用下， 以 异丙醇 为溶剂， 100.0 ℃ 、5.07 MPa 条件下， 反应 4.5h， 生成 β-phenylethyl-α-amino-β-phenylethylamine 、 N,N-双(2-苯基乙基)胺盐酸盐
  参考文献：
  名称：

  Catalysts based on filamentous carbon in the hydrogenation of aromatic compounds

  摘要：

  In order to extend the area of application of the base catalytic system metal-filamentous carbon, the catalytic properties of Ni-filamentous carbon catalysts have been tested in the hydrogenation of aromatic compounds (benzene, benzyl cyanide, benzophenone, and nitrobenzene). The selectivity of the catalysts depends on the outer faceting of the active metal particles. The benzene ring is hydrogenated on the (111) face of the metal nanoparticles, whereas the selective hydrogenation of functional groups in substituted aromatic compounds occurs on the surface of active component nanoparticles in which the (111) face is blocked.

  DOI：

  10.1134/s0023158411050181

文献信息

• Catalysts based on filamentous carbon in the hydrogenation of aromatic compounds
  作者：N. A. Zaitseva、V. V. Goidin、V. V. Molchanov、V. V. Chesnokov、R. A. Buyanov、V. A. Utkin

  DOI：10.1134/s0023158411050181

  日期：2011.9

  In order to extend the area of application of the base catalytic system metal-filamentous carbon, the catalytic properties of Ni-filamentous carbon catalysts have been tested in the hydrogenation of aromatic compounds (benzene, benzyl cyanide, benzophenone, and nitrobenzene). The selectivity of the catalysts depends on the outer faceting of the active metal particles. The benzene ring is hydrogenated on the (111) face of the metal nanoparticles, whereas the selective hydrogenation of functional groups in substituted aromatic compounds occurs on the surface of active component nanoparticles in which the (111) face is blocked.