Dodecyl 3-(2-(3-benzyl-4-ethoxy-2,5-dioxoimidazolidin-1-YL)-4,4-dimethyl-3-oxovaleramido)-4-chlorobenzoate | 92683-20-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Dodecyl 3-(2-(3-benzyl-4-ethoxy-2,5-dioxoimidazolidin-1-YL)-4,4-dimethyl-3-oxovaleramido)-4-chlorobenzoate
• 英文别名: dodecyl 3-[[2-(3-benzyl-4-ethoxy-2,5-dioxoimidazolidin-1-yl)-4,4-dimethyl-3-oxopentanoyl]amino]-4-chlorobenzoate
• CAS: 92683-20-0
• 化学式: C₃₈H₅₂ClN₃O₇
• 分子量: 698.3
• InChiKey: JBTJAJPZXJDKOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10
• 重原子数：
  49
• 可旋转键数：
  22
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  122
• 氢给体数：
  1
• 氢受体数：
  7

安全信息

• 安全说明：
  S61
• 危险类别码：
  R53

文献信息

• Silver halide color light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0133262A2

  公开（公告）日：1985-02-20

  A silver halide color light-sensitive material having excellent properties for a sensitization treatment is described, containing a polymer coupler having an average molecular weight higher than 30,000 and having a polymeric unit derived from a monomeric magenta coupler represented by formula (I): wherein R1 is hydrogen, chlorine, or a lower alkyl group having 1 to 4 carbon atoms; A is a phenylene group, a -CONH- group, or a -COO- group; B is an unsubstituted or substituted alkylene group, an unsubstituted or substituted aralkylene group, or an unsubstituted or substituted phenylene group; Y is -0-, -NH-, -S-, -SO-, -S02-, -CONH-, -COO-, -NHCO-, or -NHCONH-; Q is a residue of a magenta color-forming coupler which forms a dye through coupling with the oxidation product of an aromatic primary amine developer; and m is 1 when n is 1, and m is 0 or 1 when n is 0.

  本发明描述了一种在敏化处理方面具有优异性能的卤化银彩色感光材料，该材料含有一种平均分子量高于 30,000 的聚合物耦合剂，该聚合物耦合剂具有由式 (I) 所表示的单体品红色耦合剂衍生的聚合物单元： 其中 R1 是氢、氯或具有 1 至 4 个碳原子的低级烷基；A 是亚苯基、-CONH- 基团或 -COO- 基团；B 是未取代或取代的亚烷基、未取代或取代的亚芳烷基或未取代或取代的亚苯基；Y 是-0-、-NH-、-S-、-SO-、-S02-、-CONH-、-COO-、-NHCO-或-NHCONH-； Q 是洋红色成色偶联剂的残留物，该偶联剂通过与芳香族伯胺显色剂的氧化产物偶联形成染料；当 n 为 1 时，m 为 1，当 n 为 0 时，m 为 0 或 1。
• Silver halide color photographic light-sensitive material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0157146A2

  公开（公告）日：1985-10-09

  A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing a coupler which releases a compound after the coupling reaction with the oxidation product of a developing agent, the released compound being capable of releasing further a photographically useful group by an oxidation-reduction reaction with the oxidation product of another developing agent. The compound used in the present invention is chemically stable and can release a photographically useful group under control; therefore the silver halide color photographic light-sensitive material containing the compound has good stability during storage and high sensitivity and provides a color image having good image qualities such as sharpness, graininess, color reproducibility, etc.

  一种卤化银彩色感光材料，包括一个支撑体，支撑体上至少有一层卤化银乳剂层，该彩色感光材料含有一种耦合剂，该耦合剂在与一种显影剂的氧化产物发生耦合反应后释放出一种化合物，释放出的化合物能够通过与另一种显影剂的氧化产物发生氧化还原反应进一步释放出一种对照片有用的基团。本发明中使用的化合物化学性质稳定，可在控制下释放出对照片有用的基团；因此，含有该化合物的卤化银彩色感光材料在储存期间具有良好的稳定性和较高的感光度，可提供具有良好图像质量（如锐度、颗粒感、色彩再现性等）的彩色图像。
• Silver halide photographic materials
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0191948A2

  公开（公告）日：1986-08-27

  A silver halide photographic material exhibiting improved interimage effects and having improved sharpness and graininess is disclosed. The material contains at least one compound represented by formula (1) or formula (II): wherein R' represents a straight or branched chain alkylene, alkenylene or aralkylene group, or an arylene group; R2 represents a hydrogen atom, or a substituted or unsubstituted alkyl, aryl, alkenyl or aralkyl group; X represents a hydrogen atom, an alkali metal atom, an ammonium group or a precursor capable of providing a hydrogen atom or an alkali metal atom under an alkaline condition; Z1 and Z2 each represents a polar group; and n represents 0 or 1.

  本发明公开了一种卤化银感光材料，它具有更好的临时成像效果，清晰度和颗粒感也得到了改善。该材料至少含有一种由式 (1) 或式 (II) 表示的化合物： 其中 R' 代表直链或支链亚烷基、亚烯基或芳烷基，或芳基；R2 代表氢原子，或取代或未取代的烷基、芳基、烯基或芳烷基；X 代表氢原子、碱金属原子、铵基或在碱性条件下能提供氢原子或碱金属原子的前体；Z1 和 Z2 各代表一个极性基团；n 代表 0 或 1。
• Silver halide color photographic materials
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0217353A2

  公开（公告）日：1987-04-08

  A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, said silver halide emulsion layer containing a pyrazoloazole series magenta coupler represented by general formula [I] wherein, R' and R2 each represents a hydrogen atom or a substituent; and X represents a hydrogen atom or a releasing group which is released at the reaction with the oxidation product of an aromatic primary amine developing agent; at least one of said R' and R2 is an alkyl group having a secondary or tertiary carbon atom directly bonded to the skeleton, at least one of said R, and R2 is a sulfonamidoalkyl group or a sulfamoylalkyl group; and the magenta coupler may form a dimer or more polymer at the position of said R', R2 or X. By the combined use of high boiling point organic solvent and ultraviolet absorbent, light fastness and coloring property are markedly improved.

  一种卤化银彩色感光材料，包括一个支撑体，支撑体上至少有一层卤化银乳剂层，所述卤化银乳剂层含有通式[I]表示的吡唑啉系列品红耦合剂 其中，R'和 R2 各代表一个氢原子或一个取代基；X 代表一个氢原子或一个释放基团，该释放基团在与芳香族伯胺显色剂的氧化产物反应时被释放；所述 R' 和 R2 中至少有一个是烷基，该烷基具有直接键合到骨架上的仲碳原子或叔碳原子，所述 R，和 R2 中至少有一个是磺酰胺基烷基或磺酰基烷基；洋红偶联剂可在所述 R'、R2 或 X 的位置上形成二聚体或更多的聚合物。 通过同时使用高沸点有机溶剂和紫外线吸收剂，耐光牢度和着色性能得到明显改善。
• Image-dye-forming couplers and photographic elements containing them
  申请人：KODAK LIMITED

  公开号：EP0751427A1

  公开（公告）日：1997-01-02

  The present invention comprehends the use of thenoylacetamide materials as image-dye-forming couplers, specifically yellow dye-forming couplers, for use with silver halide based photographic systems. In one aspect, the invention provides a coupler of formula (I):- wherein X is H or a coupling-off group, R1 is H or is a coupler-modifying functional group; Y and Z are the same or different and are H or independently selected from alkyl, aryl or heteroaryl, each of which is unsubstituted or substituted with one or more coupler-modifying functional groups; or Y and Z taken together with the nitrogen atom form a 5-10 membered heterocyclic ring which may contain one or more further heteroatoms selected from N, O and S, said heterocyclic ring being unsubstituted or substituted with one or more coupler-modifying functional groups. Preferred couplers are those where Y is H and Z is a phenyl group, which may be mono- or di-substituted.

  本发明包括使用酰乙酰胺材料作为图像染料形成耦合剂，特别是黄色染料形成耦合剂，用于卤化银基摄影系统。在一个方面，本发明提供了式 (I) 的偶联剂：- X 是 H 或偶联剂。 其中 X 是 H 或耦合关闭基团，R1 是 H 或耦合剂修饰官能团；Y 和 Z 是相同或不同的，并且是 H 或独立选自烷基、芳基或杂芳基，其中每个都未被取代或被一个或多个耦合剂修饰官能团取代；或 Y 和 Z 与氮原子一起形成一个 5-10 个成员的杂环，该杂环可包含一个或多个选自 N、O 和 S 的杂原子，所述杂环未被取代或被一个或多个耦合剂修饰官能团取代。 优选的耦合剂是 Y 为 H、Z 为苯基（可以是单取代或二取代）的耦合剂。