4-methyl-4'-(3-(2-pyridyl)pyrazolyl)methyl-2,2'-bipyridyl | 1190832-82-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4-methyl-4'-(3-(2-pyridyl)pyrazolyl)methyl-2,2'-bipyridyl
• 英文别名: 4-methyl-4'-3-(2-pyridyl)pyrazolyl-2,2'-bipyridyl；2-(4-Methylpyridin-2-yl)-4-[(3-pyridin-2-ylpyrazol-1-yl)methyl]pyridine；2-(4-methylpyridin-2-yl)-4-[(3-pyridin-2-ylpyrazol-1-yl)methyl]pyridine
• CAS: 1190832-82-6
• 化学式: C₂₀H₁₇N₅
• 分子量: 327.388
• InChiKey: DJMNAEFGMWDWJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  顺-双(2,2-二吡啶)二氯化钌(II) 水合物 、 4-methyl-4'-(3-(2-pyridyl)pyrazolyl)methyl-2,2'-bipyridyl 以 丙酮 为溶剂， 生成 [Ru(bipy)2(4-methyl-4'-(3-(2-pyridyl)pyrazolyl)methyl-2,2'-bipyridyl)](2+) 、 [(Ru(bipy)2)2(4-methyl-4'-(3-(2-pyridyl)pyrazolyl)methyl-2,2'-bipyridyl)](4+)
  参考文献：
  名称：

  Syntheses and photophysical properties of visible-light-absorbing Ru(II) polypyridyl complexes possessing (pyridylpyrazolyl)metal tethers

  摘要：

  Novel Ru(II) polypyridyl complexes possessing pyridylpyrazolyl tethers were synthesized. Reactions with various organometallic precursors readily afforded multinuclear complexes which possess a light-harvesting Ru(II) core and (pyridylpyrazolyl) metal fragments in high yields. Analysis of the photophysical properties of the obtained multinuclear complexes revealed that the complexes had similar absorption and emission characteristics; however, their emission quantum yields decreased in proportion to the number of metal fragments. The di- and trinuclear complexes were stable under donating solvent such as CH3CN. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.05.024
• 作为产物：
  描述：

  4-(溴甲基)-4-甲基-2,2-联吡啶 、 2-(1H-吡唑-3-基)吡啶 以 甲苯 为溶剂， 反应 15.0h， 以55%的产率得到4-methyl-4'-(3-(2-pyridyl)pyrazolyl)methyl-2,2'-bipyridyl
  参考文献：
  名称：

  Syntheses and photophysical properties of visible-light-absorbing Ru(II) polypyridyl complexes possessing (pyridylpyrazolyl)metal tethers

  摘要：

  Novel Ru(II) polypyridyl complexes possessing pyridylpyrazolyl tethers were synthesized. Reactions with various organometallic precursors readily afforded multinuclear complexes which possess a light-harvesting Ru(II) core and (pyridylpyrazolyl) metal fragments in high yields. Analysis of the photophysical properties of the obtained multinuclear complexes revealed that the complexes had similar absorption and emission characteristics; however, their emission quantum yields decreased in proportion to the number of metal fragments. The di- and trinuclear complexes were stable under donating solvent such as CH3CN. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.05.024

文献信息

• Syntheses and photophysical properties of visible-light-absorbing Ru(II) polypyridyl complexes possessing (pyridylpyrazolyl)metal tethers
  作者：Tomohide Saita、Hiroyuki Nitadori、Akiko Inagaki、Munetaka Akita

  DOI：10.1016/j.jorganchem.2009.05.024

  日期：2009.9

  Novel Ru(II) polypyridyl complexes possessing pyridylpyrazolyl tethers were synthesized. Reactions with various organometallic precursors readily afforded multinuclear complexes which possess a light-harvesting Ru(II) core and (pyridylpyrazolyl) metal fragments in high yields. Analysis of the photophysical properties of the obtained multinuclear complexes revealed that the complexes had similar absorption and emission characteristics; however, their emission quantum yields decreased in proportion to the number of metal fragments. The di- and trinuclear complexes were stable under donating solvent such as CH3CN. (C) 2009 Elsevier B.V. All rights reserved.