[Mo(CO)2(2,6-bis(di-tert-butylphosphinomethyl)pyridine)]2(μ-N2) | 1277163-65-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Mo(CO)2(2,6-bis(di-tert-butylphosphinomethyl)pyridine)]2(μ-N2)
• 英文别名: [Mo(CO)2(2,6-bis(di-tert-butylphosphinomethyl)pyridine)]2(m-N2)；carbon monoxide;ditert-butyl-[[6-(ditert-butylphosphanylmethyl)pyridin-2-yl]methyl]phosphane;molecular nitrogen;molybdenum
• CAS: 1277163-65-1
• 化学式: C₅₀H₈₆Mo₂N₄O₄P₄
• 分子量: 1123.03
• InChiKey: PLOANHSTARATAH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.35
• 重原子数：
  64
• 可旋转键数：
  16
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.72
• 拓扑面积：
  77.4
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  硫酸 、 [Mo(CO)2(2,6-bis(di-tert-butylphosphinomethyl)pyridine)]2(μ-N2) 以 四氢呋喃 为溶剂， 生成 氨
  参考文献：
  名称：

  Synthesis and Protonation of Molybdenum– and Tungsten–Dinitrogen Complexes Bearing PNP-Type Pincer Ligands

  摘要：

  Novel molybdenum- and tungsten dinitrogen complexes bearing PNP-type pincer ligands are prepared and characterized by X-ray analysis. Reactions of these molybdenum- and tungsten-dinitrogen complexes with an excess amount of sulfuric acid in THF at room temperature afford ammonia and hydrazine in good yields.

  DOI：

  10.1021/om300011z
• 作为产物：
  描述：

  一氧化碳 、 [Mo(N₂₎₂(2,6-bis(di-tertbutylphosphinomethyl)pyridine)]₂(μ-N₂) 以 四氢呋喃 为溶剂， 以64%的产率得到[Mo(CO)2(2,6-bis(di-tert-butylphosphinomethyl)pyridine)]2(μ-N2)
  参考文献：
  名称：

  Synthesis and Protonation of Molybdenum– and Tungsten–Dinitrogen Complexes Bearing PNP-Type Pincer Ligands

  摘要：

  Novel molybdenum- and tungsten dinitrogen complexes bearing PNP-type pincer ligands are prepared and characterized by X-ray analysis. Reactions of these molybdenum- and tungsten-dinitrogen complexes with an excess amount of sulfuric acid in THF at room temperature afford ammonia and hydrazine in good yields.

  DOI：

  10.1021/om300011z

文献信息

• Synthesis and Protonation of Molybdenum– and Tungsten–Dinitrogen Complexes Bearing PNP-Type Pincer Ligands
  作者：Kazuya Arashiba、Kouitsu Sasaki、Shogo Kuriyama、Yoshihiro Miyake、Haruyuki Nakanishi、Yoshiaki Nishibayashi

  DOI：10.1021/om300011z

  日期：2012.3.12

  Novel molybdenum- and tungsten dinitrogen complexes bearing PNP-type pincer ligands are prepared and characterized by X-ray analysis. Reactions of these molybdenum- and tungsten-dinitrogen complexes with an excess amount of sulfuric acid in THF at room temperature afford ammonia and hydrazine in good yields.