2-(4-Tert-butyl-2,6-dimethylphenyl)iminoacenaphthylen-1-one | 936562-76-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-(4-Tert-butyl-2,6-dimethylphenyl)iminoacenaphthylen-1-one
• CAS: 936562-76-4
• 化学式: C₂₄H₂₃NO
• 分子量: 341.453
• InChiKey: XKTATSHJXKOTBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  26
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  29.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  iron(II) chloride tetrahydrate 、 2-(4-Tert-butyl-2,6-dimethylphenyl)iminoacenaphthylen-1-one 、 2-((4-(tertbutyl)phenyl)thio)ethan-1-amine 以 环己烷 为溶剂， 以73%的产率得到
  参考文献：
  名称：

  Oligomerization of Ethylene Using New Tridentate Iron Catalysts Bearing α-Diimine Ligands with Pendant S and P Donors

  摘要：

  Stoichiometric Schiff base condensations of sterically bulky primary amines with acenaphthene quinone yield isolable monoimines In the presence of iron(II) chloride the remaining ketone reacts with a second primary amine bearing a pendant donor atom to give asymmetric tridentate a diimine complexes that possess remarkable structural variability A series of NNP and NNS tridentate iron(II) complexes are prepared these coordination compounds become active catalysts for ethylene oligomerization when activated with methylalumoxanes X ray crystallographic studies of the precatalyst complexes confirm that the ligand binds in a tridentate fashion Correlations between the precatalyst solid state structures and catalyst activity and a olefin product distribution are explored

  DOI：

  10.1021/om1007743
• 作为产物：
  描述：

  1-叔丁基-3,5-二甲苯 在 甲酸 、 硫酸 、 水 、 硝酸 、 溶剂黄146 、 calcium chloride 、 锌 作用下， 以 乙醇 为溶剂， 反应 0.33h， 生成 2-(4-Tert-butyl-2,6-dimethylphenyl)iminoacenaphthylen-1-one
  参考文献：
  名称：

  Oligomerization of Ethylene Using New Tridentate Iron Catalysts Bearing α-Diimine Ligands with Pendant S and P Donors

  摘要：

  Stoichiometric Schiff base condensations of sterically bulky primary amines with acenaphthene quinone yield isolable monoimines In the presence of iron(II) chloride the remaining ketone reacts with a second primary amine bearing a pendant donor atom to give asymmetric tridentate a diimine complexes that possess remarkable structural variability A series of NNP and NNS tridentate iron(II) complexes are prepared these coordination compounds become active catalysts for ethylene oligomerization when activated with methylalumoxanes X ray crystallographic studies of the precatalyst complexes confirm that the ligand binds in a tridentate fashion Correlations between the precatalyst solid state structures and catalyst activity and a olefin product distribution are explored

  DOI：

  10.1021/om1007743