[β-(10-Phenothiazyl)propoxy]phosphonic acid dichloride | 334990-68-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: [β-(10-Phenothiazyl)propoxy]phosphonic acid dichloride
• 英文别名: β-(10-phenothiazyl)propoxyphosphonic acid dichloride；10-(3-Dichlorophosphoryloxypropyl)phenothiazine
• CAS: 334990-68-0
• 化学式: C₁₅H₁₄Cl₂NO₂PS
• 分子量: 374.227
• InChiKey: OCTODIZZKLEFFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  54.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [β-(10-Phenothiazyl)propoxy]phosphonic acid dichloride 在 水 作用下， 以40%的产率得到[β-(10-Phenothiazyl)propoxy]phosphonic acid
  参考文献：
  名称：

  Electrochromic compound

  摘要：

  用于电致变色器件的化合物。 该化合物包括（1）β-(10-苯并噻吩基)丙氧基膦酸；（2）β-(10-苯并噻吩基)丙基膦酸；和（3）β-(10-苯并噻吩基)丙酸膦酸。

  公开号：

  US07358358B2
• 作为产物：
  描述：

  β-(10-Phenothiazyl)propionic acid ethyl ester 在 吡啶 、 lithium aluminium tetrahydride 、 三氯氧磷 作用下， 以 乙醚 、 氯仿 为溶剂， 反应 3.5h， 生成 [β-(10-Phenothiazyl)propoxy]phosphonic acid dichloride
  参考文献：
  名称：

  Ultrafast Electrochromic Windows Based on Redox-Chromophore Modified Nanostructured Semiconducting and Conducting Films

  摘要：

  Described is the construction of an ultrafast electrochromic window. One electrode of this window is based on a transparent nanostructured TiO2 (anatase) film (4.0 mum. thick) supported on conducting glass (F-doped tin oxide, 10 Ohm cm(-2), 0.5 mum thick) and modified by chemisorption of a monolayer of the redox chromophore bis(2-phosphonoethyl)-4,4'-bipyridinium dichloride. The other electrode is based on a transparent nanostructured SnO2 film (3.0 mum thick) supported on conducting glass (F-doped tin oxide, 10 Ohm cm-2, 0.5 mum thick) and modified by chemisorption of a monolayer of the redox chromophore [beta-(10-phenothiazyl)propoxy]phosphonic acid. The electrolyte used is LiClO4 (0.2 mol dm(-3)) in gamma -butyrolactone. The excellent performance of a 2.5 cm x 2.5 cm window over 10 000 electrochromic test cycles-switching times (coloring and bleaching) of less than 250 ms, coloration efficiency of 270 cm(2) C-1, steady-state currents (colored and bleached) of less than 6 muA cm(-2), and memory of greater than 600 s (time required for low end transmittance to increase by 5%)-suggest a practical technology.

  DOI：

  10.1021/jp001763b

文献信息

• US7253940B2
  申请人：——

  公开号：US7253940B2

  公开（公告）日：2007-08-07
• US7358358B2
  申请人：——

  公开号：US7358358B2

  公开（公告）日：2008-04-15
• US7576201B2
  申请人：——

  公开号：US7576201B2

  公开（公告）日：2009-08-18
• Electrochromic compound
  申请人：NTERA limited

  公开号：US07358358B2

  公开（公告）日：2008-04-15

  A compound for use in electrochromic devices. The compound includes (1) β-(10-phenothiazyl)propoxy phosphonic acid; (2) β-(10-phenothiazyl)propyl-phosphonic acid; and (3) β-(10-phenothiazyl)propionate phosphonic acid.

  用于电致变色器件的化合物。 该化合物包括（1）β-(10-苯并噻吩基)丙氧基膦酸；（2）β-(10-苯并噻吩基)丙基膦酸；和（3）β-(10-苯并噻吩基)丙酸膦酸。
• Ultrafast Electrochromic Windows Based on Redox-Chromophore Modified Nanostructured Semiconducting and Conducting Films
  作者：David Cummins、Gerrit Boschloo、Michael Ryan、David Corr、S. Nagaraja Rao、Donald Fitzmaurice

  DOI：10.1021/jp001763b

  日期：2000.12.1

  Described is the construction of an ultrafast electrochromic window. One electrode of this window is based on a transparent nanostructured TiO2 (anatase) film (4.0 mum. thick) supported on conducting glass (F-doped tin oxide, 10 Ohm cm(-2), 0.5 mum thick) and modified by chemisorption of a monolayer of the redox chromophore bis(2-phosphonoethyl)-4,4'-bipyridinium dichloride. The other electrode is based on a transparent nanostructured SnO2 film (3.0 mum thick) supported on conducting glass (F-doped tin oxide, 10 Ohm cm-2, 0.5 mum thick) and modified by chemisorption of a monolayer of the redox chromophore [beta-(10-phenothiazyl)propoxy]phosphonic acid. The electrolyte used is LiClO4 (0.2 mol dm(-3)) in gamma -butyrolactone. The excellent performance of a 2.5 cm x 2.5 cm window over 10 000 electrochromic test cycles-switching times (coloring and bleaching) of less than 250 ms, coloration efficiency of 270 cm(2) C-1, steady-state currents (colored and bleached) of less than 6 muA cm(-2), and memory of greater than 600 s (time required for low end transmittance to increase by 5%)-suggest a practical technology.