benzo[d][1,3]dioxol-5-ylmethyl 4-nitrobenzoate | 1002007-39-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzo[d][1,3]dioxol-5-ylmethyl 4-nitrobenzoate
• 英文别名: 1,3-Benzodioxol-5-ylmethyl 4-nitrobenzoate
• CAS: 1002007-39-7
• 化学式: C₁₅H₁₁NO₆
• 分子量: 301.255
• InChiKey: AGYZSEHLJMFSJQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  90.6
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  胡椒醇 、 对硝基苯甲酸 在 C₁₈H₂₀N₂O₄ 、 Nb-TPP 作用下， 以 四氢呋喃 为溶剂， 以78%的产率得到benzo[d][1,3]dioxol-5-ylmethyl 4-nitrobenzoate
  参考文献：
  名称：

  Monomer-on-Monomer (MoM) Mitsunobu Reaction: Facile Purification Utilizing Surface-Initiated Sequestration

  摘要：

  A monomer-on-monomer (MoM) Mitsunobu reaction utilizing norbornenyl-tagged (Nb-tagged) reagents is reported, whereby purification was rapidly achieved by employing ring-opening metathesis polymerization, which was initiated by any of three methods utilizing Grubbs catalyst: (i) free catalyst in solution, (ii) surface-initiated catalyst-armed silica, or (iii) surface-initiated catalyst-armed Co/C magnetic nanoparticles.

  DOI：

  10.1021/ol1022382

文献信息

• Monomer-on-Monomer (MoM) Mitsunobu Reaction: Facile Purification Utilizing Surface-Initiated Sequestration
  作者：Pradip K. Maity、Alan Rolfe、Thiwanka B. Samarakoon、Saqib Faisal、Ryan D. Kurtz、Toby R. Long、Alexander Schätz、Daniel L. Flynn、Robert N. Grass、Wendelin J. Stark、Oliver Reiser、Paul R. Hanson

  DOI：10.1021/ol1022382

  日期：2011.1.7

  A monomer-on-monomer (MoM) Mitsunobu reaction utilizing norbornenyl-tagged (Nb-tagged) reagents is reported, whereby purification was rapidly achieved by employing ring-opening metathesis polymerization, which was initiated by any of three methods utilizing Grubbs catalyst: (i) free catalyst in solution, (ii) surface-initiated catalyst-armed silica, or (iii) surface-initiated catalyst-armed Co/C magnetic nanoparticles.