4-(4-trifluoromethylbenzylsulfanyl)phenol | 108789-39-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(4-trifluoromethylbenzylsulfanyl)phenol
• 英文别名: 4-[[4-(trifluoromethyl)phenyl]methylsulfanyl]phenol
• CAS: 108789-39-5
• 化学式: C₁₄H₁₁F₃OS
• 分子量: 284.302
• InChiKey: SFDAJMPTPPKJMH-UHFFFAOYSA-N

物化性质

• 沸点：
  380.1±42.0 °C(Predicted)
• 密度：
  1.35±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  45.5
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4-(4-trifluoromethylbenzylsulfanyl)phenol 在 双氧水 、 溶剂黄146 作用下， 以 水 为溶剂， 反应 3.0h， 生成 4-[(4-trifluoromethylphenyl)methanesulfonyl]phenol
  参考文献：
  名称：

  NOVEL COMPOUNDS CAPABLE OF FORMING PHOTOCONVERTIBLE ORGANIC THIN FILMS AND ARTICLES HAVING ORGANIC THIN FILMS

  摘要：

  公开号：

  EP1589020B1
• 作为产物：
  描述：

  1-溴-三氟对二甲苯 在 氢氧化钾 作用下， 以 甲醇 为溶剂， 反应 18.5h， 生成 4-(4-trifluoromethylbenzylsulfanyl)phenol
  参考文献：
  名称：

  NOVEL COMPOUNDS CAPABLE OF FORMING PHOTOCONVERTIBLE ORGANIC THIN FILMS AND ARTICLES HAVING ORGANIC THIN FILMS

  摘要：

  公开号：

  EP1589020B1

文献信息

• Novel compounds capable of forming photoconvertible organic thin film and articles having organic thin film
  申请人：Saso Haruo

  公开号：US20060138400A1

  公开（公告）日：2006-06-29

  The present invention relates to a compound which is flexibly amenable to the alteration, without impairing its photosensitivity, of its structural moiety which affects film forming ability and the resulting surface properties, the compound being capable of undergoing surface alteration by irradiation with relatively low energy wavelength, and of forming an organic thin film on a substrate with good reproducibility, and an organic thin film formed body, the compound being represented by formula (1). (In the formula, X represents a heteroatom-containing functional group capable of interacting with a surface of a metal or a metallic oxide, R represents a C1 to C20 alkyl group, a C1 to C20 alkoxy group, an aryl group, or a C1 to C20 alkoxycarbonyl group; n represents an integer of 1 to 30, and m represents an integer of 0 to 5; G1 represents a single bond or a bivalent hydrocarbon radical having carbon atoms of 1 to 3; Ar represents an aromatic group which may have a substituent; G2 represents O, S, or Nr.)

  本发明涉及一种化合物，该化合物易于改变其影响薄膜形成能力和表面性质的结构基团，而不会损害其光敏性，该化合物能够通过较低能量波长的辐射进行表面改性，并能够在衬底上形成具有良好重现性的有机薄膜，以及由该化合物形成的有机薄膜形成体，该化合物由式（1）表示。（在公式中，X表示能够与金属或金属氧化物表面相互作用的含杂原子的官能团，R表示C1至C20烷基，C1至C20烷氧基，芳基或C1至C20烷氧羰基；n表示1至30的整数，m表示0至5的整数；G1表示单键或具有1至3个碳原子的双价碳氢基团；Ar表示可能具有取代基的芳基；G2表示O、S或Nr。）
• Compounds for forming photoconvertible organic thin film and organic thin film formed body
  申请人：Nippon Soda Co., Ltd.

  公开号：US07470803B2

  公开（公告）日：2008-12-30

  The present invention relates to a compound which is flexibly amenable to the alteration, without impairing its photosensitivity, of its structural moiety which affects film forming ability and the resulting surface properties, the compound being capable of undergoing surface alteration by irradiation with relatively low energy wavelength, and of forming an organic thin film on a substrate with good reproducibility, and an organic thin film formed body, the compound being represented by formula (1). (In the formula, X represents a heteroatom-containing functional group capable of interacting with a surface of a metal or a metallic oxide, R represents a C1 to C20 alkyl group, a C1 to C20 alkoxy group, an aryl group, or a C1 to C20 alkoxycarbonyl group; n represents an integer of 1 to 30, and m represents an integer of 0 to 5; G1 represents a single bond or a bivalent hydrocarbon radical having carbon atoms of 1 to 3; Ar represents an aromatic group which may have a substituent; G2 represents O, S, or Nr.)

  本发明涉及一种化合物，其能够灵活地改变其结构基团，而不会影响其光敏性，该结构基团影响薄膜形成能力和所得到的表面性质，该化合物能够通过较低能量波长的辐照而发生表面改变，并且能够在基底上形成有良好再现性的有机薄膜，以及形成的有机薄膜体，该化合物由式（1）表示。（在式中，X表示能够与金属或金属氧化物表面相互作用的含杂原子的功能基团，R表示C1至C20烷基，C1至C20烷氧基，芳基或C1至C20烷氧羰基；n表示1至30的整数，m表示0至5的整数；G1表示单键或具有1至3个碳原子的双价碳氢基团；Ar表示可以有取代基的芳基；G2表示O、S或Nr。）
• US7470803B2
  申请人：——

  公开号：US7470803B2

  公开（公告）日：2008-12-30
• NOVEL COMPOUNDS CAPABLE OF FORMING PHOTOCONVERTIBLE ORGANIC THIN FILMS AND ARTICLES HAVING ORGANIC THIN FILMS
  申请人：NIPPON SODA CO., LTD.

  公开号：EP1589020B1

  公开（公告）日：2013-06-05