methyl tridecyl sulfide | 62155-09-3

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: methyl tridecyl sulfide
• 英文别名: methyl-tridecyl-sulfide；methyl-tridecyl sulfide；Methyl-tridecyl-sulfid；Tridecane, 1-(methylthio)-；1-methylsulfanyltridecane
• CAS: 62155-09-3
• 化学式: C₁₄H₃₀S
• 分子量: 230.458
• InChiKey: QVXOOYOFFITGCV-UHFFFAOYSA-N

物化性质

• 熔点：
  -7.15°C (estimate)
• 沸点：
  282.46°C (estimate)
• 密度：
  0.8430

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  15
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  methyl tridecyl sulfide 在 tetrabutylammonium phosphomolybdate 过氧化脲素 作用下， 反应 31.0h， 以81%的产率得到1-Methanesulfonyl-tridecane
  参考文献：
  名称：

  Tetrabutylammonium phosphomolybdate on fluorapatite: an efficient solid catalyst for solvent-free selective oxidation of sulfides

  摘要：

  A new synthetic method of sulfoxides and sulfones using solvent-free oxidations of sulfides with urea-hydrogen peroxide complex (urea-H2O2) and tetrabutylammonium phosphomolybdate catalyst on fluorapatite ((Bu4N)(3)[PMo12O40]/FAp). In the solid-phase system the oxidations of aromatic and alkyl sulfides proceeded at 4-25degreesC and the corresponding sulfoxides or sulfones were selectively obtained in good yields by controlling the amount of urea-H2O2. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.11.002
• 作为产物：
  描述：

  (2-thiapropyl)magnesium chloride 、 溴代十二烷 以 四氢呋喃 为溶剂， 以76%的产率得到methyl tridecyl sulfide
  参考文献：
  名称：

  高效生成甲基(ORp-甲苯基)硫甲基格氏试剂的改进方法及其在有机合成中的应用

  摘要：

  建立了以高收率将氯甲基硫醚转化为相应格氏试剂 (2) 的最佳条件，并且 (2) 显示与各种官能团如卤代烷、醛和亚磺酸酯反应，揭示它在有机合成中的用途。

  DOI：

  10.1246/cl.1982.1697

文献信息

• DIBENZORYLENETETRACARBOXIMIDES AS INFRARED ABSORBERS
  申请人：Koenemann Martin

  公开号：US20100048904A1

  公开（公告）日：2010-02-25

  Dibenzorylenetetracarboximides of the general formula I in which the variables are each defined as follows: R′ are identical or different radicals: hydrogen; optionally substituted aryloxy, arylthio, hetaryloxy or hetarylthio; R are identical or different radicals: hydrogen; optionally substituted C 1 -C 30 -alkyl, C 3 -C 8 -cycloalkyl, aryl or hetaryl; m, n are each independently 0 or 1.

  一般式I的二苯并咔唑四羧酰亚胺中，变量定义如下：R′为相同或不同的基团：氢；可选择取代的芳氧基、芳硫基、杂芳氧基或杂芳硫基；R为相同或不同的基团：氢；可选择取代的C1-C30烷基、C3-C8环烷基、芳基或杂芳基；m，n各自独立地为0或1。
• LIQUID CRYSTALLINE RYLENE TETRACARBOXYLIC ACID DERIVATIVES AND USE THEREOF
  申请人：Koenemann Martin

  公开号：US20110042651A1

  公开（公告）日：2011-02-24

  The present invention relates to liquid-crystalline rylenetetracarboxylic acid derivatives, to processes for their preparation and to their use as n-type organic semiconductors for producing organic field-effect transistors and solar cells.

  本发明涉及液晶芳纶四羧酸衍生物，其制备方法以及作为n型有机半导体用于制造有机场效应晶体管和太阳能电池的用途。
• [EN] OLIGOCONDENSED PERYLENE BISIMIDES<br/>[FR] BISIMIDES DE PÉRYLÈNE OLIGOCONDENSÉS
  申请人：BASF SE

  公开号：WO2010111822A1

  公开（公告）日：2010-10-07

  The present invention relates to oligocondensed perylene bisimides, a method for their production and their use.

  本发明涉及寡聚化的苝二酰亚胺，其生产方法及其用途。
• Flüssig-kristalline Rylentetracarbonsäurederivate und deren Verwendung
  申请人：BASF Aktiengesellschaft

  公开号：EP1843407A1

  公开（公告）日：2007-10-10

  Die vorliegende Erfindung betrifft flüssig-kristalline Rylentetracarbonsäurederivate, Verfahren zu ihrer Herstellung und deren Verwendung als organische Halbleiter vom n-Typ zur Herstellung von organischen Feldeffekttransistoren und von Solarzellen.

  本发明涉及液晶烯丙基四羧酸衍生物、其制备工艺以及用作生产有机场效应晶体管和太阳能电池的 n 型有机半导体。
• Activity of Sulfonium Bisphosphonates on Tumor Cell Lines
  作者：Yonghui Zhang、Michael P. Hudock、Kilannin Krysiak、Rong Cao、Kyle Bergan、Fenglin Yin、Annette Leon、Eric Oldfield

  DOI：10.1021/jm700991k

  日期：2007.11.1

  We investigated three series of sulfonium bisphosphonates for their activity in inhibiting the growth of three human tumor cell lines. The first series consisted of 6 cyclic sulfonium bisphosphonates, the most active species having an (average) IC50 of 89,mu M. The second consisted of 10 phenylalkyl and phenylalkoxy bisphosphonates, the most active species having an IC50 of 18,mu M. The third series consisted of 17 n-alkyl sulfonium bisphosphonates, the most active species having an IC50 of similar to 240 nM. Three QSAR models showed that the experimental cell growth inhibition results could be well predicted. We also determined the structures of one sulfonium bisphosphonate bound to farnesyl diphosphate synthase, finding that it binds exclusively to the dimethylallyl diphosphate binding site. These results are of interest since they show that sulfonium bisphosphonates can have potent activity against a variety of tumor cell lines, the most active species having IC50 values much lower than conventional nitrogen-containing bisphosphonates.