methyl 5-(1,3-dioxolan-2-yl)pentanoate | 15138-56-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: methyl 5-(1,3-dioxolan-2-yl)pentanoate
• CAS: 15138-56-4
• 化学式: C₉H₁₆O₄
• 分子量: 188.224
• InChiKey: XDQVHLIZESHFTK-UHFFFAOYSA-N

物化性质

• 沸点：
  241.2±15.0 °C(Predicted)
• 密度：
  1.058±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  methyl 5-(1,3-dioxolan-2-yl)pentanoate 在 盐酸 作用下， 反应 0.33h， 生成 6-氧代己酸甲酯
  参考文献：
  名称：

  Electrochemical transformations of monooxa- and dioxabicycloalkenes and-bicycloalkanes

  摘要：

  Electrolysis of 2-oxa- and 2,5-dioxabicyclo[n.4.0]alk-1(6)-enes (n = 4, 10) under conditions of direct undivided anodic oxidation in methanol results in their electrochemical mono- and dimethoxylation; electrolysis of the corresponding 2-oxa- and 2,5-dioxabicycloalkanes involves electrochemical cleavage of the bridging carbon-carbon bonds followed by electrooxidative transformation into methyl omega-(2-methoxytetrahydrofuryl)-, omega-(dimethoxymethyl)-, and omega-(1,3-dioxolan-2-yl)alkanoates.

  DOI：

  10.1007/bf02494854
• 作为产物：
  描述：

  6-氧代己酸甲酯 、 乙二醇 在 sodium hydrogen sulfate 、 silica gel 作用下， 反应 0.08h， 以85%的产率得到methyl 5-(1,3-dioxolan-2-yl)pentanoate
  参考文献：
  名称：

  Yadav; Reddy, B. V. Subba; Srinivas, Synlett, 2000, # 5, p. 701 - 703

  摘要：

  DOI：

文献信息

• Yadav; Reddy, B. V. Subba; Srinivas, Synlett, 2000, # 5, p. 701 - 703
  作者：Yadav、Reddy, B. V. Subba、Srinivas、Ramalingam

  DOI：——

  日期：——
• Electrochemical transformations of monooxa- and dioxabicycloalkenes and-bicycloalkanes
  作者：Yu. N. Ogibin、A. O. Terent'ev、A. I. Ilovaisky、G. I. Nikishin

  DOI：10.1007/bf02494854

  日期：1999.11

  Electrolysis of 2-oxa- and 2,5-dioxabicyclo[n.4.0]alk-1(6)-enes (n = 4, 10) under conditions of direct undivided anodic oxidation in methanol results in their electrochemical mono- and dimethoxylation; electrolysis of the corresponding 2-oxa- and 2,5-dioxabicycloalkanes involves electrochemical cleavage of the bridging carbon-carbon bonds followed by electrooxidative transformation into methyl omega-(2-methoxytetrahydrofuryl)-, omega-(dimethoxymethyl)-, and omega-(1,3-dioxolan-2-yl)alkanoates.