3-(o-chlorophenyl)-5-(2-arsonophenylazo)rhodanine | 1122513-14-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3-(o-chlorophenyl)-5-(2-arsonophenylazo)rhodanine
• 英文别名: 2ClRAAP；[2-[[3-(2-Chlorophenyl)-4-oxo-2-sulfanylidene-1,3-thiazolidin-5-yl]diazenyl]phenyl]arsonic acid；[2-[[3-(2-chlorophenyl)-4-oxo-2-sulfanylidene-1,3-thiazolidin-5-yl]diazenyl]phenyl]arsonic acid
• CAS: 1122513-14-7
• 化学式: C₁₅H₁₁AsClN₃O₄S₂
• 分子量: 471.777
• InChiKey: HWENHLYAPYJXKA-UHFFFAOYSA-N

物化性质

• 沸点：
  697.9±65.0 °C(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.38
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  160
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  3-(2-chlorophenyl)-2-thioxothiazolidin-4-one 、 2-氨基苯胂酸 在 盐酸 、 sodium nitrite 、 氨 作用下， 以 水 为溶剂， 生成 3-(o-chlorophenyl)-5-(2-arsonophenylazo)rhodanine
  参考文献：
  名称：

  Catalytic dynamic spectrofluorimetry determination of trace antimony using new type arsenoxylphenylazo rhodanine

  摘要：

  A precise, simple, new spectrofluorimetry method is proposed for determination of trace antimony which is based on the reaction between potassium periodate and the new type fluorescent reagent 3-o-chlorophenyl-5-(2'-arsenoxylphenylazo) rhodanine (2ClRAAP). The possible mechanism is proposed. The fluorescence intensity is investigated to be sharply enhanced by the oxidation of 3-o-chlorophenyl-5-(2'-arsenoxylphenylazo) rhodanine by potassium periodate with antimony as catalyst in the buffer medium of potassium hydrogen phthalate-sodium hydroxide (pH 5.2). Under the optimum conditions the great increase of fluorescence intensity has a linear relationship against the concentration of antimony in the range of 0.2-10 mu g L-1 with a detection limit of 1.65 x 10(-10) g mL(-1). This proposed method led to the satisfied determination of antimony in environment water. (C) 2008 Published by Elsevier B.V.

  DOI：

  10.1016/j.saa.2008.06.047

文献信息

• Catalytic dynamic spectrofluorimetry determination of trace antimony using new type arsenoxylphenylazo rhodanine
  作者：Jing-hua Yu、Ping Dai、Shen-guang Ge、Yuan-na Zhu、Li-na Zhang、Xiao-liang Cheng

  DOI：10.1016/j.saa.2008.06.047

  日期：2009.2

  A precise, simple, new spectrofluorimetry method is proposed for determination of trace antimony which is based on the reaction between potassium periodate and the new type fluorescent reagent 3-o-chlorophenyl-5-(2'-arsenoxylphenylazo) rhodanine (2ClRAAP). The possible mechanism is proposed. The fluorescence intensity is investigated to be sharply enhanced by the oxidation of 3-o-chlorophenyl-5-(2'-arsenoxylphenylazo) rhodanine by potassium periodate with antimony as catalyst in the buffer medium of potassium hydrogen phthalate-sodium hydroxide (pH 5.2). Under the optimum conditions the great increase of fluorescence intensity has a linear relationship against the concentration of antimony in the range of 0.2-10 mu g L-1 with a detection limit of 1.65 x 10(-10) g mL(-1). This proposed method led to the satisfied determination of antimony in environment water. (C) 2008 Published by Elsevier B.V.