N,N'-difurfurylidenebenzidine | 6264-56-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-difurfurylidenebenzidine
• 英文别名: Bisfurfurylidenebenzidine；1-(furan-2-yl)-N-[4-[4-(furan-2-ylmethylideneamino)phenyl]phenyl]methanimine
• CAS: 6264-56-8
• 化学式: C₂₂H₁₆N₂O₂
• 分子量: 340.381
• InChiKey: GABRIJCNEJQZLY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  亚磷酸二异丙酯 、 N,N'-difurfurylidenebenzidine 在 sodium isopropylate 作用下， 反应 2.0h， 以71%的产率得到4,4'-bis[N-methyl(diisopropoxyphosphonyl)-1-(2-furyl)]benzidine
  参考文献：
  名称：

  NOVEL DIESTERS OF AMINOPHOSPHONIC ACIDS CONTAINING FURAN AND BENZIDINE RESIDUE

  摘要：

  4,4'-Bis[N-methyl(diethoxyphosphonyl)-1-(2-furyl)]benzidine and 4,4'-bis[N-methyl(diisopropoxyphosphonyl)-1-(2-furyl)]benzidine have been synthesized through addition of diethyl phosphite and diisopropyl phosphite, respectively, to the Schiff base N,N'-difurfurylidenebenzidine. The compounds have been characterized by elemental analysis, TLC and IR spectra. A comparable study of their H-1-NMR spectra and H-1-NMR spectra of 4,4'-bis[N-methyl(diethoxyphosphonyl)-1-phenyl]benzidine has been carried out. Some H-1-NMR data of 4,4'-bis[N-methyl(dimethoxyphosphonyl)-1-phenyl]diaminodiphenylmethane, 4,4'-bis [N-methyl(diethoxyphosphonyl)-1-phenyl]diaminodiphenylmethane, and 4,4'-bis [N-methyl(diisopropoxyphosphonyl)-1-phenyl]diaminodiphenylmethane in DMSO-d(6) solution are also presented.

  DOI：

  10.1080/10426509908044976
• 作为产物：
  描述：

  糠醛 、 联苯胺 在 溶剂黄146 作用下， 以89%的产率得到N,N'-difurfurylidenebenzidine
  参考文献：
  名称：

  Pui, Aurel; Malutan, Theodor; Tataru, Lucia, Polyhedron, 2011, vol. 30, p. 2127 - 2131

  摘要：

  DOI：

文献信息

• NOVEL DIESTERS OF AMINOPHOSPHONIC ACIDS CONTAINING FURAN AND BENZIDINE RESIDUE
  作者：I. Kraicheva

  DOI：10.1080/10426509908044976

  日期：1999.12

  4,4'-Bis[N-methyl(diethoxyphosphonyl)-1-(2-furyl)]benzidine and 4,4'-bis[N-methyl(diisopropoxyphosphonyl)-1-(2-furyl)]benzidine have been synthesized through addition of diethyl phosphite and diisopropyl phosphite, respectively, to the Schiff base N,N'-difurfurylidenebenzidine. The compounds have been characterized by elemental analysis, TLC and IR spectra. A comparable study of their H-1-NMR spectra and H-1-NMR spectra of 4,4'-bis[N-methyl(diethoxyphosphonyl)-1-phenyl]benzidine has been carried out. Some H-1-NMR data of 4,4'-bis[N-methyl(dimethoxyphosphonyl)-1-phenyl]diaminodiphenylmethane, 4,4'-bis [N-methyl(diethoxyphosphonyl)-1-phenyl]diaminodiphenylmethane, and 4,4'-bis [N-methyl(diisopropoxyphosphonyl)-1-phenyl]diaminodiphenylmethane in DMSO-d(6) solution are also presented.
• Pui, Aurel; Malutan, Theodor; Tataru, Lucia, Polyhedron, 2011, vol. 30, p. 2127 - 2131
  作者：Pui, Aurel、Malutan, Theodor、Tataru, Lucia、Malutan, Corina、Humelnicu, Doina、Carja, Gabriela

  DOI：——

  日期：——