[(1S)-1-phenylbut-3-enyl] prop-2-enoate | 913723-02-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(1S)-1-phenylbut-3-enyl] prop-2-enoate
• CAS: 913723-02-1
• 化学式: C₁₃H₁₄O₂
• 分子量: 202.253
• InChiKey: MFTKUQUWOPHFNJ-LBPRGKRZSA-N

物化性质

• 沸点：
  280.1±19.0 °C(Predicted)
• 密度：
  1.015±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  [(1S)-1-phenylbut-3-enyl] prop-2-enoate 在 RuCl2(1,3-dimesityl-imidazolidin-2-yl)(PCy3)(=CHPh) 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 (-)-6(S)-Phenyl-5,6-dihydro-2H-pyran-2-one
  参考文献：
  名称：

  Efficient Total Syntheses and Structural Verification of Both Diospongins A and B via a Common δ-Lactone Intermediate

  摘要：

  The total syntheses of the two aryl C-glycoside natural products diospongins A and B are described. The key reactions involved stereoselective reductions of the appropriate oxocarbenium cations that were derived from a common delta-lactone intermediate.

  DOI：

  10.1021/jo061296f
• 作为产物：
  描述：

  (S)-1-苯基-3-丁烯-1-醇 、 丙烯酰氯 在 4-二甲氨基吡啶 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 [(1S)-1-phenylbut-3-enyl] prop-2-enoate
  参考文献：
  名称：

  Efficient Total Syntheses and Structural Verification of Both Diospongins A and B via a Common δ-Lactone Intermediate

  摘要：

  The total syntheses of the two aryl C-glycoside natural products diospongins A and B are described. The key reactions involved stereoselective reductions of the appropriate oxocarbenium cations that were derived from a common delta-lactone intermediate.

  DOI：

  10.1021/jo061296f

文献信息

• Efficient Total Syntheses and Structural Verification of Both Diospongins A and B via a Common δ-Lactone Intermediate
  作者：Kailas B. Sawant、Michael P. Jennings

  DOI：10.1021/jo061296f

  日期：2006.9.1

  The total syntheses of the two aryl C-glycoside natural products diospongins A and B are described. The key reactions involved stereoselective reductions of the appropriate oxocarbenium cations that were derived from a common delta-lactone intermediate.