2-methylamino-4,6-bis(phenylamino)-1,3,5-triazine | 17654-47-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-methylamino-4,6-bis(phenylamino)-1,3,5-triazine
• 英文别名: N-methyl-N',N''-diphenyl-[1,3,5]triazine-2,4,6-triamine；2,4-Dianilino-6-methylamino-s-triazin；6-N-methyl-2-N,4-N-diphenyl-1,3,5-triazine-2,4,6-triamine
• CAS: 17654-47-6
• 化学式: C₁₆H₁₆N₆
• 分子量: 292.343
• InChiKey: VBKXLWCLQXUCPC-UHFFFAOYSA-N

物化性质

• 沸点：
  510.7±33.0 °C(Predicted)
• 密度：
  1.324±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  74.8
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2,4-二氯-6-(甲基氨基)-1,3,5-三嗪 、 苯胺 以 四氢呋喃 为溶剂， 反应 18.0h， 生成 2-methylamino-4,6-bis(phenylamino)-1,3,5-triazine
  参考文献：
  名称：

  Heads vs. tails: a double-sided study of the influence of substituents on the glass-forming ability and stability of aminotriazine molecular glasses

  摘要：

  众所周知，甲氧基氨基三嗪衍生物可自发形成长寿命玻璃相。人们已经研究了各种结构元素在其玻璃相形成过程中所起的作用，但取代两个芳基氨基取代基的效果在很大程度上仍然未知。我们合成了一个 4,6-双（芳基氨基）- 或 4,6-双（烷基氨基）-1,3,5-三嗪衍生物库，这些衍生物在 2 位上具有甲基氨基或乙基取代基，并对它们的玻璃形成特性进行了研究。虽然在所研究的衍生物中，3,5-二取代芳基基团被证明是促进玻璃形成的最佳基团，但研究发现玻璃形成能力和稳定性在很大程度上受到三嗪环 2 位上 "头基 "的影响，不同头基的玻璃形成行为存在巨大差异。

  DOI：

  10.1039/c3nj00709j

文献信息

• PHOTOPROTECTIVE COMPOSITIONS COMPRISING PHOTOSENSITIVE 1,3,5-TRIAZINE COMPOUNDS, DIBENZOYLMETHANE COMPOUNDS AND SILICEOUS S-TRIAZINES SUBSTITUTED WITH TWO AMINOBENZOATE OR AMINOBENZAMIDE GROUPS
  申请人：L'OREAL

  公开号：US20170135933A1

  公开（公告）日：2017-05-18

  UV-photoprotective, topically applicable cosmetic/dermatological compositions contain: (a) at least one dibenzoylmethane compound, (b) at least one 1,3,5-triazine compound that is photosensitive in the presence of a dibenzoylmethane compound, and (c) at least one siliceous s-triazine compound substituted with two aminobenzoate or aminobenzamide groups, or a tautomeric form thereof, the 1,3,5-triazine compounds being improvedly photostable in such compositions.

  UV-光保护，可局部应用的化妆品/皮肤科组合物包含： (a) 至少一种二苯甲酮化合物， (b) 至少一种1,3,5-三嗪化合物，在二苯甲酮化合物存在时对光敏感，以及 (c) 至少一种含有两个氨基苯甲酸酯或氨基苯酰胺基团的硅质s-三嗪化合物，或其互变异构体，这些1,3,5-三嗪化合物在这种组合物中具有改进的光稳定性。
• Retardation film, method for producing the same, polarizing plate and liquid crystal display
  申请人：Inagaki Shinji

  公开号：US20070134446A1

  公开（公告）日：2007-06-14

  A method of producing a long roll retardation film comprising the sequential steps of: (a) casting a film forming material on an endless support to form a long roll film; (b) stretching the long roll film in a lateral direction of the long roll film while both edges of the long roll film are held employing a plurality of clips for each of the edges in a tenter (First Process); (c) reducing distances in the lateral direction between the clips holding the both edges of the long roll film while the edges of the long roll film are held continuously from First Process with the clips (Second Process); (d) enlarging the distances in the lateral direction between the clips holding the both edges of the long roll film while the edges of the long roll film are held continuously from Second Process with the clips (Third Process).

  一种制造长卷延迟膜的方法，包括以下步骤：(a)在无限支撑上铸造成膜形成材料，形成长卷膜;(b)在张力机上用多个夹子夹住长卷膜的两个边缘，沿长卷膜的横向方向拉伸长卷膜（第一步骤）;(c)在第一步骤中，保持夹子夹住长卷膜的两个边缘，同时减小夹子之间的横向距离（第二步骤）;(d)在第二步骤中，保持夹子夹住长卷膜的两个边缘，同时增大夹子之间的横向距离（第三步骤）。
• PROSTAGLANDIN TRANSPORTER INHIBITORS AND USES THEREOF
  申请人：Albert Einstein College of Medicine, Inc.

  公开号：EP2488032B1

  公开（公告）日：2016-11-02
• METHOD FOR MANUFACTURING AN OPTICAL FILM HAVING A CONVEXOCONCAVE STRUCTURE, OPTICAL FILM, WIRE GRID POLARIZER AND RETARDATION FILM
  申请人：SATO Akira

  公开号：US20070252293A1

  公开（公告）日：2007-11-01

  A manufacturing method of an optical film provided with a convexoconcave structure, comprises the steps of: coating a resin solution including a first resin solved by a solvent onto an endless or roll-like mold provided with a convexoconcave structure, and forming a resin solution layer on the mold; laminating a film substrate onto the resin solution layer to make a laminated film before the solvent in the resin solution layer is completely dried, the film substrate including a second resin, which is capable of absorving the solution or is soluble by the solvent; and peeling the laminated film from the mold before the solvent in the laminated film is completely dried.
• Optical Film, Method of Producing the Same and Image Displaying Apparatus Employing the Optical Film
  申请人：Yajima Takatoshi

  公开号：US20090286098A1

  公开（公告）日：2009-11-19

  A method for producing an optical film, characterized by extruding a melt containing a cellulose ester resin from a casting die to thereby form a long length cellulose ester film at a draw ratio of 5 to 30, slitting both sides of the long length cellulose ester film and winding the same in roll form, and while unrolling the long length cellulose ester film from the roll, carrying out continuous coating of the surface hereof with an optical function layer.