bis(4-formylphenyl)hexanedioate | 118677-45-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: bis(4-formylphenyl)hexanedioate
• 英文别名: Bis(4-formylphenyl) hexanedioate
• CAS: 118677-45-5
• 化学式: C₂₀H₁₈O₆
• mdl: MFCD00366736
• 分子量: 354.359
• InChiKey: UUKJTEWPOFXMNT-UHFFFAOYSA-N

物化性质

• 沸点：
  553.3±45.0 °C(Predicted)
• 密度：
  1.256±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  26
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  86.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  bis(4-formylphenyl)hexanedioate 、 对氮蒽蓝 以 甲苯 为溶剂， 反应 4.0h， 以97%的产率得到hexanediacid-bis<4-N-(4-phenylazophenyl)iminomethylphenyl>ester
  参考文献：
  名称：

  Kossmehl, Gerhard; Bahr, Juergen, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1991, vol. 46, # 2, p. 245 - 254

  摘要：

  DOI：
• 作为产物：
  描述：

  对羟基苯甲醛 、 己二酰氯 在 N,N-二甲基甲酰胺 吡啶 作用下， 以76%的产率得到bis(4-formylphenyl)hexanedioate
  参考文献：
  名称：

  Kossmehl, Gerhard; Bahr, Juergen, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1991, vol. 46, # 2, p. 245 - 254

  摘要：

  DOI：

文献信息

• N-BRIDGED POLYNITRONS AND THE USE THEREOF AS CROSS-LINKING AGENTS, IN PARTICULAR IN COATING MATERIALS AND ADHESIVES
  申请人：Dickmeis Marcus

  公开号：US20130018140A1

  公开（公告）日：2013-01-17

  The invention relates to N-bridged polynitrons and their use for cross-linking of unsaturated polymers, as well as a curable composition comprising (a) a N-bridged polynitron, (b) an unsaturated polymer or a mixture of polymers, wherein at least one unsaturated polymer contains unsaturated functions or functional groups which can react with the polynitron, (c) optionally fillers, (d) optionally pigments, (e) optionally additives such as plasticizers, stabilizers, photoinitiators, and (f) optionally, other cross-linking agents such as polyisocyanates, bisdienes, polyoxaziridines, and their use as adhesives, rubber, filling, sprayable thick-layer filler, ink, paint, powder paint, waterborne paint or solvent based paint. Further, the invention relates to cross-linking products obtainable by curing the curable composition according to the present invention.

  该发明涉及N-桥联聚硝基化合物及其在交联不饱和聚合物中的应用，以及包括（a）N-桥联聚硝基化合物、（b）不饱和聚合物或聚合物混合物的可固化组合物，其中至少一种不饱和聚合物含有可以与聚硝基化合物发生反应的不饱和功能或官能团，（c）可选填料，（d）可选颜料，（e）可选添加剂如增塑剂、稳定剂、光引发剂，以及（f）可选其他交联剂如聚异氰酸酯、双二烯、聚噁唑烷等，并将其用作粘合剂、橡胶、填料、喷涂厚层填料、墨水、油漆、粉末涂料、水性涂料或溶剂基涂料。此外，该发明涉及通过固化根据本发明的可固化组合物获得的交联产品。
• Asymmetric Aldol Polymerization of Bis(trimethylsilylketene thioacetal) and Dialdehyde
  作者：Kenichi Komura、Shinichi Itsuno

  DOI：10.1246/cl.2001.730

  日期：2001.7

  Asymmetric repetitive Mukaiyama aldol reaction between bis(trimethylsilylketene thioacetal) and dialdehydes proceeded in the presence of chiral oxazaborolidinone to afford optically active poly(β-hydroxy thioester)s. Degree of asymmetric induction during polymerization was evaluated both by a model reaction and chiral HPLC analysis of degradation products of the chiral polymers.

  在手性噁唑烷酮的存在下，双（三甲基硅酮硫代乙醛）与二醛发生了不对称重复向山醛反应，生成了具有光学活性的聚（β-羟基硫酯）。聚合过程中的不对称诱导程度通过模型反应和手性聚合物降解产物的手性 HPLC 分析进行了评估。
• Synthesis and Characterization of Cholesterol-Based Tetramers
  作者：K. C. Majumdar、S. Ponra、S. Chakravorty

  DOI：10.1080/15421406.2010.504628

  日期：2010.10.14

  Novel symmetrical liquid-crystal tetramers were designed and synthesized. The length of the central spacer and the outer spacers has been varied. The molecular structures of the target compounds were confirmed by Fourier transform infrared and proton nuclear magnetic resonance spectroscopy. The thermal phase behavior of the tetramers was investigated by polarizing optical microscopy and differential scanning calorimetry. All of the liquid-crystal tetramers showed either a chiral nematic mesophase or chiral nematic and smectic mesophases.
• Al-Dujaili, Amar H.; Jenkins, D.; Walton, David R. M., Molecular Crystals and Liquid Crystals (1969-1991), 1988, vol. 164, p. 67 - 76
  作者：Al-Dujaili, Amar H.、Jenkins, D.、Walton, David R. M.

  DOI：——

  日期：——
• Kossmehl, Gerhard; Bahr, Juergen, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1991, vol. 46, # 2, p. 245 - 254
  作者：Kossmehl, Gerhard、Bahr, Juergen

  DOI：——

  日期：——