N-(biphenyl-4-yl)benzene-1,2-diamine | 208187-62-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(biphenyl-4-yl)benzene-1,2-diamine
• 英文别名: 2-N-(4-phenylphenyl)benzene-1,2-diamine
• CAS: 208187-62-6
• 化学式: C₁₈H₁₆N₂
• 分子量: 260.338
• InChiKey: IOJRXUXJIUMCMS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  10-甲基吩噻嗪-3,7-二氨基醛 、 N-(biphenyl-4-yl)benzene-1,2-diamine 在 sodium metabisulfite 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以78%的产率得到3,7-bis(1-(biphenyl-4-yl)benzimidazol-2-yl)-10-methylphenothiazine
  参考文献：
  名称：

  Electroluminescence Characteristics of a New Green-Emitting Phenothiazine Derivative with Biphenyl Benzimidazole Substituent

  摘要：

  We report on the synthesis and electroluminescence characteristics of a new green-emitting material, 3,7-bis(1-(biphenyl-4-yl)benzimidazol-2-yl) 10-methylphenothiazine (PhBBMP) containing the electron-donating phenothiazine core and the electron-accepting biphenyl benzimidazole substituent. An optimized OLED device with the structure of [ITO/NPB (40 nm)/PhBBMP (30 nm)/BCP (10 nm)/TPBI (30 nm)/LiF (1 nm)/Al (100 nm)] exhibited a luminous efficiency of 4.5 cd/A and an external quantum efficiency of 0.9% at 100mA/cm(2), and the maximum luminance of 12,000 cd/m(2) with the CIE 1931 chromaticity coordinates of (0.21, 0.54). A more balanced charge carrier injection and the charge confinement in the emitting layer cooperatively contributed to improve the performance of the device prepared with the PhBBMP emitting layer.

  DOI：

  10.1080/15421401003608378

文献信息

• [EN] MATERIALS FOR ORGANIC ELECTROLUMINESCENT DEVICES<br/>[FR] MATÉRIAUX POUR DISPOSITIFS ÉLECTROLUMINESCENTS ORGANIQUES
  申请人：MERCK PATENT GMBH

  公开号：WO2018091435A1

  公开（公告）日：2018-05-24

  The present invention relates to compounds of the formula (1) which are suitable for use in electronic devices, in particular organic electroluminescent devices, and to electronic devices, which comprise these compounds.

  本发明涉及适用于电子设备，特别是有机电致发光器件的化合物的公式（1），以及包含这些化合物的电子设备。
• Organic element for electroluminescent devices
  申请人：Helber J. Margaret

  公开号：US20050170203A1

  公开（公告）日：2005-08-04

  Disclosed is an electroluminescent device comprising a light emitting layer comprising a boron complex wherein the boron is bonded to a nitrogen atom of a 6-membered heteroaromatic ring group and to a nitrogen atom of a 5-membered heteroaromatic ring group, provided that the 5- and 6-membered heteroaromatic ring groups are further connected by an imine group, and provided that the 5-membered heteroaromatic ring group contains at least one additional heteroatom that is divalent or trivalent, and a process or device employing the device.

  本发明公开了一种电致发光装置，其包括一个发光层，该发光层包含一个硼配合物，其中硼与一个6元杂芳环基团的氮原子和一个5元杂芳环基团的氮原子结合，前提是5元和6元杂芳环基团由亚胺基进一步连接，并且5元杂芳环基团包含至少一个二价或三价的其他杂原子，以及使用该装置的过程或装置。
• MATERIALS FOR ORGANIC ELECTROLUMINESCENT DEVICES
  申请人：Merck Patent GmbH

  公开号：EP3541890B1

  公开（公告）日：2020-10-28
• US7070868B2
  申请人：——

  公开号：US7070868B2

  公开（公告）日：2006-07-04
• [EN] ORGANIC ELEMENT FOR ELECTROLUMINESCENT DEVICES<br/>[FR] ELEMENT ORGANIQUE POUR DISPOSITIFS ELECTROLUMINESCENTS
  申请人：EASTMAN KODAK CO

  公开号：WO2005075599A1

  公开（公告）日：2005-08-18

  Disclosed is an electroluminescent device comprising a light emitting layer comprising a boron complex wherein the boron is bonded to a nitrogen atom of a 6-membered heteroaromatic ring group and to a nitrogen atom of a 5-membered heteroaromatic ring group, and provided that the 5- and 6-membered heteroaromatic ring groups are further connected by an imine group, and provided that the 5-membered heteroaromatic ring group contains at least one additional heteroatom that is divalent or, trivalent, and a process or device employing the device.