3-(norborn-5-en-2-yl)propionic acid | 853737-08-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3-(norborn-5-en-2-yl)propionic acid
• 英文别名: 3-(Norborn-5-en-2-yl)propionsaeure；3-{Bicyclo[2.2.1]hept-5-EN-2-YL}propanoic acid；3-(2-bicyclo[2.2.1]hept-5-enyl)propanoic acid
• CAS: 853737-08-3
• 化学式: C₁₀H₁₄O₂
• 分子量: 166.22
• InChiKey: STAXVPTUONLACL-UHFFFAOYSA-N

物化性质

• 沸点：
  299.1±9.0 °C(Predicted)
• 密度：
  1.129±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-(norborn-5-en-2-yl)propionic acid 在 硫酸 作用下， 反应 20.0h， 以0.16 g的产率得到3-((1R^*,2R^*,4S^*)-2-Hydroxybicyclo[2.2.1]heptan-2-yl)propanoic acid 1,4-lactone
  参考文献：
  名称：

  Sadikun, Amirin bin; Davies, David I., Journal of the Chemical Society. Perkin transactions I, 1982, # 10, p. 2461 - 2466

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(norborn-5-en-2-yl)ethyl cyanide 在 氢氧化钾 作用下， 反应 40.0h， 以83%的产率得到3-(norborn-5-en-2-yl)propionic acid
  参考文献：
  名称：

  Sadikun, Amirin bin; Davies, David I., Journal of the Chemical Society. Perkin transactions I, 1982, # 10, p. 2461 - 2466

  摘要：

  DOI：

文献信息

• DIAZIRINE COMPOUNDS AND COMPOSITIONS DERIVED THEREFROM
  申请人：PROMERUS, LLC

  公开号：US20160083352A1

  公开（公告）日：2016-03-24

  A series of diazirine compounds of formula (I) having utility as photocrosslinkers are disclosed. Where, A, L, z, Ar x and R y are as defined herein. Also disclosed are the photodefinable compositions containing these compounds.

  揭示了一系列具有光交联剂作用的二氮烯化合物的化学式（I），其中A、L、z、Arx和Ry的定义如本文所述。还揭示了含有这些化合物的光可定义组合物。
• Radiation-sensitive resin composition
  申请人：——

  公开号：US20030219680A1

  公开（公告）日：2003-11-27

  A radiation-sensitive resin composition suitable as a chemically-amplified resist is provided. The composition comprised (A) a resin insoluble or scarcely soluble in alkali, but becoming alkali soluble by the action of an acid, and (B) a photoacid generator. The resin comprises a recurring unit of the following formula (I), 1 wherein R 1 is typically a hydrogen atom and the —C (R 5 ) 3 structure is a 2-methyl-2-tricyclodecanyl group, 2-ethyl-2-tricyclodecanyl group, 2-methyl-2-adamantyl group, 2-ethyl-2-adamantyl group, 1-methylcyclopentyl group, 1-ethylcyclopentyl group, 1-methylcyclohexyl group, or 1-ethylcyclohexyl group.

  提供一种适用于化学放大光刻胶的辐射敏感树脂组合物。该组合物包含(A)一种碱不溶或难溶的树脂，但在酸的作用下变得碱溶，以及(B)一种光酸发生剂。该树脂包含以下式(I)的重复单元，其中R1通常是氢原子，而—C(R5)3结构是2-甲基-2-三环己基基团、2-乙基-2-三环己基基团、2-甲基-2-金刚烷基团、2-乙基-2-金刚烷基团、1-甲基环戊基团、1-乙基环戊基团、1-甲基环己基团或1-乙基环己基团。
• Preparation of Norbornane-based PAC Ballasts
  申请人：Bell Andrew

  公开号：US20120135352A1

  公开（公告）日：2012-05-31

  Embodiments in accordance with the present invention provide for norbornane-type ballast materials, norbornane-type photoactive compounds derived from such ballast materials and alkali-soluble positive-tone polymer compositions that encompass such norbornane-type photoactive compounds and one of a PBO or PNB resin.

  本发明实施例提供了诺博烷型镇流材料，从这种镇流材料衍生出的诺博烷型光活性化合物以及包括这种诺博烷型光活性化合物和PBO或PNB树脂之一的碱溶性正向型聚合物组合物。
• MODIFIED CYCLOOLEFIN ADDITION POLYMER AND CURABLE RESIN COMPOSITION CONTAINING THE SAME
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0997482A1

  公开（公告）日：2000-05-03

  A curable resin composition comprising a modified cycloolefin addition polymer (A) obtained by introducing a functional group into a cycloolefin addition polymer containing a repeating unit (a) derived from a cycloolefin monomer having an organic group having at least 4 carbon atoms at its side chain at a rate of introduction of the functional group of 0.1 to 50 mol% based on the whole repeating unit of the cycloolefin addition polymer, and a hardening agent (B), and a modified cycloolefin addition polymer (A) obtained by introducing a functional group into a cycloolefin addition polymer containing a repeating unit (a) derived from a cycloolefin monomer having an organic group having at least 4 carbon atoms at its side chain at a rate of introduction of the functional group of 0.1 to 50 mol% based on the whole repeating unit of the cycloolefin addition polymer, and having a weight average molecular weight (Mw) of 1,000 to 1,000,000.

  一种可固化的树脂组合物，它包括一种改性环烯烃加成聚合物 (A)，该改性环烯烃加成聚合物是通过向环烯烃加成聚合物中引入官能团而获得的，环烯烃加成聚合物含有一个重复单元 (a)，该重复单元来源于环烯烃单体，该环烯烃单体具有一个有机基团，该有机基团在其侧链上至少有 4 个碳原子，官能团的引入率为 0.1 至 50 摩尔%（以环烯烃加成聚合物的整个重复单元为基数）的环烯烃加成聚合物和硬化剂 (B)，以及一种改性环烯烃加成聚合物 (A)，该改性环烯烃加成聚合物是通过在环烯烃加成聚合物中引入一个官能团而获得的，该环烯烃加成聚合物含有从环烯烃单体衍生而来的重复单元 (a)，该环烯烃单体在其侧链上具有至少 4 个碳原子的有机基团，官能团的引入率为 0.1至50摩尔％，且其重量平均分子量(Mw)为1,000至1,000,000。
• Cyclic olefin addition copolymer and process for producing same, crosslinking composition, crosslinked product and process for producing same, and optically transparent material and application thereof
  申请人：JSR Corporation

  公开号：EP1293521A2

  公开（公告）日：2003-03-19

  The present invention provides a cyclic olefin addition copolymer which has a reactive silyl group having a specific structure, excels in optical transparency, heat resistance, and adhesion, and is capable of producing a crosslinked product having improved dimensional stability, solvent resistance, and chemical resistance. The present invention also provides a process for producing the cyclic olefin addition copolymer, a crosslinking composition, a crosslinked product and a process for producing the same, and an optically transparent material (transparent resin film) comprising the cyclic olefin addition copolymer. The optically transparent material excels in optical transparency and heat resistance, exhibits improved dimensional stability, adhesion, solvent resistance, and chemical resistance, and is capable of improving fragility and preventing occurrence of cracks in the film.

  本发明提供了一种环状烯烃加成共聚物，该共聚物具有具有特定结构的活性硅基，在光学透明性、耐热性和粘附性方面表现优异，并且能够生产出具有更好的尺寸稳定性、耐溶剂性和耐化学性的交联产品。本发明还提供了环烯烃加成共聚物的生产工艺、交联组合物、交联产品及其生产工艺，以及包含环烯烃加成共聚物的光学透明材料（透明树脂薄膜）。这种光学透明材料具有出色的光学透明度和耐热性，尺寸稳定性、粘附性、耐溶剂性和耐化学性均有改善，并能提高脆性和防止薄膜出现裂缝。