ethyl-phenyl-dithiocarbamic acid | 13074-40-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ethyl-phenyl-dithiocarbamic acid
• 英文别名: Aethyl-phenyl-dithiocarbamidsaeure；N-Aethyl-dithiocarbanilsaeure；Aethylphenylcarbaminsaeure；Lead(2+) ethylphenyldithiocarbamate；ethyl(phenyl)carbamodithioic acid
• CAS: 13074-40-3
• 化学式: C₉H₁₁NS₂
• 分子量: 197.325
• InChiKey: BDSYEKLSEKMQDH-UHFFFAOYSA-N

物化性质

• 熔点：
  60-61 °C
• 沸点：
  269.9±23.0 °C(Predicted)
• 密度：
  1.210±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  36.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-(phenylsulfamoyl)benzene-1,2-dicarbonyl chloride 、 ethyl-phenyl-dithiocarbamic acid 以55%的产率得到
  参考文献：
  名称：

  KALAIYA, S. B.;SHAH, V. H.;PARIKH, A. R., J. INST. CHEM., 62,(1990) N, C. 192-194

  摘要：

  DOI：
• 作为产物：
  描述：

  二硫化碳 、 N-乙基苯胺 在 氨 、 水 作用下， 生成 ethyl-phenyl-dithiocarbamic acid
  参考文献：
  名称：

  Heller, Journal fur praktische Chemie (Leipzig 1954), 1903, vol. <2>67, p. 286

  摘要：

  DOI：

文献信息

• Synthesis, spectroscopic characterization and anticancer potential studies of organoruthenium(II) arene dithiocarbamate complexes
  作者：Athandwe M. Paca、Saheed O. Benson、Amos A. Fatokun、Peter A. Ajibade

  DOI：10.1080/17415993.2023.2253343

  日期：2024.1.2

  Four organoruthenium(II) arene dithiocarbamate complexes: RuCl(piperidine dithiocarbamate)(p-cymene), C1; RuCl(1-phenylpiperazine dithiocarbamate)(p-cymene), C2, RuCl(ethylphenyl dithiocarbamate)(p...

  四种有机钌(II)芳烃二硫代氨基甲酸酯络合物：RuCl(哌啶二硫代氨基甲酸酯)(对伞花烃)，C1； RuCl(1-苯基哌嗪二硫代氨基甲酸酯)(对伞花烃), C2, RuCl(乙基苯基二硫代氨基甲酸酯)(p...
• Melt-processable fluorine-containing resin composition
  申请人：Daikin Kogyo Co., Ltd.

  公开号：EP0007514A1

  公开（公告）日：1980-02-06

  A melt-processable fluorine-containing resin composition having an improved thermal stability which comprises (A) a tetrafluoroethylene copolymer, a chlorotrifluoroethylene homo- or co-polymer, or a vinylidene fluoride homo- or co-polymer and (B) a mixture, as a thermal stabilizer, of (a) an amine antioxidant, (b) an organosulfurous compound and at least one member selected from the group consisting of (c) carbon black and (d) metal powder of Group VIII of the Perodic Table. The composition can be advantageously processed without causing any trouble even at an optimum sintering temperature of the fluorine-containing resin. Figure 1 is a graph showing the sintering of such resin compositions under varied temperature and time conditions.

  一种可熔融加工的含氟树脂组合物，具有更好的热稳定性，该组合物包括(A)四氟乙烯共聚物、氯三氟乙烯均聚物或共聚物或偏氟乙烯均聚物或共聚物和(B)作为热稳定剂的混合物，混合物包括(a)胺抗氧化剂、(b)有机硫化合物和至少一种选自(c)炭黑和(d)过碘表第八族金属粉末的成员。 即使在含氟树脂的最佳烧结温度下，该组合物也可进行有利的加工而不会产生任何问题。 图 1 显示了这种树脂组合物在不同温度和时间条件下的烧结情况。
• Chlorinated rubber and polyvinyl chloride composition containing the same
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0091973A1

  公开（公告）日：1983-10-26

  A chlorinated rubber having a chlorine content of about 5 through about 50% by weight and a Mooney viscosity (ML1+4at 100°C) of about 20 through about 150 is presented. This chlorinated rubber is derived from the chlorination of (i) a copolymer rubber of ethylene and 1-butene having a mol ratio of ethylene/1-butene of about 85/15 through about 95/5 or (ii) a copolymer rubber of ethylene 1-butene and 5-ethylidene-2-norbornene having a mol ratio of ethylene/1-butene of about 85/15 through about 95/5 and a content of the 5-ethylidene-2-norbornene of 20% by weight or less based on the weight of the copolymer. The incorporation of the chlorinated rubber into a polyvinyl chlorid composition results in the remarkable improvement of the impact resistance and flexibility, both at a low temperature, of the polyvinyl chloride.

  介绍一种氯化橡胶，其氯含量约为 5%至 50%（按重量计），门尼粘度（100°C 时 ML1+4）约为 20 至 150。这种氯化橡胶由以下橡胶氯化而成：(i) 乙烯和 1-丁烯的共聚橡胶，乙烯/1-丁烯的摩尔比约为 85/15 至约 95/5；或 (ii) 乙烯-1-丁烯和 5-亚乙基-2-降冰片烯的共聚橡胶，乙烯/1-丁烯的摩尔比约为 85/15 至约 95/5，5-亚乙基-2-降冰片烯的含量为共聚物重量的 20%或以下。在聚氯乙烯组合物中加入氯化橡胶，可显著提高聚氯乙烯在低温下的抗冲击性和柔韧性。
• METHOD FOR PRODUCING PNEUMATIC TIRES
  申请人：THE YOKOHAMA RUBBER CO., LTD.

  公开号：EP0774340A1

  公开（公告）日：1997-05-21

  A process for producing a pneumatic tire using, as an air permeation preventive layer, a strip-shaped or cylindrical-shaped single-layer or multiple-layer thermoplastic film, comprising: applying, to at least a part of the joining portion of the thermoplastic film or tire member facing the thermoplastic film, a tackifier-adhesive composition containing a polymer component having an absolute value of the difference of the critical surface tension with the rubber component of the tire member and the polymer component of the surface layer of the thermoplastic film of not more than 6 mN/m, respectively.

  一种使用条形或圆柱形单层或多层热塑性薄膜作为防透气层生产充气轮胎的工艺，包括 在热塑性塑料薄膜的连接部分或轮胎部件面向热塑性塑料薄膜的连接部分的至少一部分涂抹增粘剂-粘合剂组合物，该组合物含有聚合物成分，其与轮胎部件的橡胶成分和热塑性塑料薄膜表层的聚合物成分的临界表面张力之差的绝对值分别不超过 6 mN/m。
• THERMOPLASTIC ELASTOMER COMPOSITION, PROCESS FOR THE PREPARATION THEREOF, HOSE MADE BY USING THE COMPOSITION, AND PROCESS FOR THE PRODUCTION THEREOF
  申请人：THE YOKOHAMA RUBBER CO., LTD.

  公开号：EP0821035A1

  公开（公告）日：1998-01-28

  A thermoplastic elastomer composition which, when used for the inner tube and/or outer cover of a hose, can improve the hose flexibility at an ordinary temperature and low temperature, oil resistance, and cold resistance and can reduce the production costs since it does not require a vulcanization step and a hose having said properties using this elastomer composition for its inner tube and/or outer cover and a process and apparatus for the production thereof.

  一种热塑性弹性体组合物，当用于软管的内管和/或外盖时，可提高软管在常温和低温下的柔韧性、耐油性和耐寒性，并可降低生产成本，因为它不需要硫化步骤。