acetic acid-(1-tert-butyl-3,3-dimethyl-butyl ester) | 58286-93-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: acetic acid-(1-tert-butyl-3,3-dimethyl-butyl ester)
• 英文别名: Essigsaeure-(1-tert-butyl-3,3-dimethyl-butylester)；3-Acetoxy-2,2,5,5-tetramethylhexan；2,2,5,5-Tetramethylhexan-3-yl acetate
• CAS: 58286-93-4
• 化学式: C₁₂H₂₄O₂
• 分子量: 200.321
• InChiKey: ZFQMLMSMSTWQRJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  acetic acid-(1-tert-butyl-3,3-dimethyl-butyl ester) 以90%的产率得到(E)-2,2,5,5-tetramethylhex-3-ene
  参考文献：
  名称：

  Wallace, Timothy W.; Wardell, Ian; Li, Ke-Dong, Journal of the Chemical Society. Perkin transactions I, 1995, # 18, p. 2293 - 2308

  摘要：

  DOI：
• 作为产物：
  描述：

  叔丁乙酸甲酯 、 叔丁基氯化镁 在 乙醚 作用下， 生成 acetic acid-(1-tert-butyl-3,3-dimethyl-butyl ester)
  参考文献：
  名称：

  Synthesis and Some Reactions of cis- and trans-Di-t-butylethylenes

  摘要：

  DOI：

  10.1021/ja01516a600

文献信息

• BLEND OF IONIC (CO)POLYMER RESINS AND MATRIX (CO)POLYMERS
  申请人：Goldbach James

  公开号：US20080242805A1

  公开（公告）日：2008-10-02

  The invention relates to polymeric resin blends containing polyelectrolyte resins blended into a polymer or copolymer matrix. Specifically, the polyelectrolyte resins are (co)polymers without hydrolyzable groups. The matrix polymer is a tough, and highly chemical-resistant (co)polymer, preferably a fluoropolymer. The polymeric resin blend is useful for forming films, and especially films useful for MEAs for use in fuel cells.

  该发明涉及将聚电解质树脂混合到聚合物或共聚物基质中的聚合物树脂混合物。具体而言，聚电解质树脂是没有水解基团的(共)聚合物。基质聚合物是一种坚韧、高化学抗性的(共)聚合物，最好是氟聚合物。聚合物树脂混合物适用于制备薄膜，尤其是用于燃料电池MEA的薄膜。
• INSTRUMENT FOR CAPTURING FREE THROMBI
  申请人：Inoue Kanji

  公开号：US20140142613A1

  公开（公告）日：2014-05-22

  An instrument captures free thrombi by inhibiting blood coagulation reaction at the stage of primary hemostasis, in which platelets are involved, and at the stage of coagulation thrombus formation, in which blood coagulation factors are involved, thereby securely capturing free thrombi and extending the available time of the instrument.

  这个仪器通过抑制血液凝固反应阶段的原始止血和凝血血栓形成阶段中涉及到的血小板和血液凝血因子，从而安全地捕获自由血栓，并延长仪器的可用时间。
• ORGANOSILOXANE GRAFT POLYVINYL ALCOHOL POLYMER AND METHOD OF PRODUCING THE SAME
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP3246342A1

  公开（公告）日：2017-11-22

  The present invention is an organosiloxane graft polyvinyl alcohol polymer containing a structural unit shown by the following general formula (1), wherein M1 and M2 represent a hydrogen atom, an acetyl group, or a siloxane group shown by the following general formula (2), provided that at least one of M1 and M2 is a siloxane group shown by the general formula (2); and A represents a single bond or a linking group. There can be provided an organosiloxane graft polyvinyl alcohol polymer that has general characteristics such as film-forming property and transparency as well as high solubility with respect to an organic solvent and excellent handleability as a liquid material.

  本发明是一种有机硅氧烷接枝聚乙烯醇聚合物，含有如下通式（1）所示的结构单元、 其中 M1 和 M2 代表氢原子、乙酰基或下式通式（2）所示的硅氧烷基团，但 M1 和 M2 中至少有一个是通式（2）所示的硅氧烷基团；A 代表单键或连接基团。 本发明可提供一种有机硅氧烷接枝聚乙烯醇聚合物，该聚合物具有成膜性和透明性等一般特性，对有机溶剂的溶解度高，作为液体材料具有良好的可操作性。
• RADICALLY CURABLE ORGANOSILOXANE GRAFT POLYVINYL ALCOHOL POLYMER AND PROCESS FOR PRODUCING SAME
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP3527598A1

  公开（公告）日：2019-08-21

  The present invention is a radically curable organosiloxane graft polyvinyl alcohol polymer having structural units represented by both of the following general formula (1) and general formula (2). The present invention provides a radically curable organosiloxane graft polyvinyl alcohol polymer having general properties such as film-forming property and transparency, excellent handleability as a liquid material since solubility in an organic solvent is high, and both of solvent resistance and moldability of the obtained film.

  本发明是一种可辐射固化的有机硅氧烷接枝聚乙烯醇聚合物，其结构单元由以下通式(1)和通式(2)表示。本发明提供了一种可辐射固化的有机硅氧烷接枝聚乙烯醇聚合物，它具有成膜性和透明性等一般特性，由于在有机溶剂中的溶解度高，因此作为液体材料具有极佳的可操作性，并且所获得的薄膜具有耐溶剂性和成型性。
• Organosiloxane graft polyvinyl alcohol polymer and method of producing the same
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10208138B2

  公开（公告）日：2019-02-19

  An organosiloxane graft polyvinyl alcohol polymer contains a structural unit shown by the following general formula (1), wherein M1 and M2 represent a hydrogen atom, an acetyl group, or a siloxane group shown by the following general formula (2), provided that at least one of M1 and M2 is a siloxane group shown by the general formula (2); and A represents a single bond or a linking group, wherein R1 represents a monovalent organic group having 1 to 6 carbon atoms; R2, R3, and R4 each represent a monovalent organic group having 1 to 6 carbon atoms or a siloxy group shown by —OSiR5R6R7, where R5, R6, and R7 each represent a monovalent organic group having 1 to 6 carbon atoms; “n” represents an integer of 1 to 10; and “a” represents an integer of 0 to 2.

  有机硅氧烷接枝聚乙烯醇聚合物含有如下通式（1）所示的结构单元、 其中 M1 和 M2 代表氢原子、乙酰基或下式通式（2）所示的硅氧烷基团，条件是 M1 和 M2 中至少有一个是通式（2）所示的硅氧烷基团；A 代表单键或连接基团、 其中 R1 代表具有 1 至 6 个碳原子的一价有机基团；R2、R3 和 R4 各自代表具有 1 至 6 个碳原子的一价有机基团或由 -OSiR5R6R7 所示的硅氧基，其中 R5、R6 和 R7 各自代表具有 1 至 6 个碳原子的一价有机基团；"n "代表 1 至 10 的整数；"a "代表 0 至 2 的整数。