9,9-bis-(N-carbazolyl-decyl)-2,7-dibromofluorene | 811862-27-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 9,9-bis-(N-carbazolyl-decyl)-2,7-dibromofluorene
• 英文别名: 9,9'-((2,7-dibromo-9H-fluorene-9,9-diyl)bis(decane-10,1-diyl))bis(9H-carbazole)；9,9’-((2,7-dibromo-9H-fluorene-9,9-diyl)bis(decane-10,1-diyl))bis(9H-carbazole)；9,9-Bis(N-carbazolyl-decyl)-2,7-dibromofluorene；9-[10-[2,7-dibromo-9-(10-carbazol-9-yldecyl)fluoren-9-yl]decyl]carbazole
• CAS: 811862-27-8
• 化学式: C₅₇H₆₂Br₂N₂
• 分子量: 934.941
• InChiKey: JXGPGEZNJZQGHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19.8
• 重原子数：
  61
• 可旋转键数：
  22
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,10-二溴癸烷 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 96.0h， 生成 9,9-bis-(N-carbazolyl-decyl)-2,7-dibromofluorene
  参考文献：
  名称：

  接枝有环金属化铱配合物和电荷传输部分的聚芴的高效红光发射

  摘要：

  我们报告了一种设计电致发光聚合物的新途径，通过将作为掺杂剂和电荷传输部分的高效磷光有机金属络合物接枝到具有单层/单聚合物的聚合物发光二极管 (PLED) 的全共轭聚合物的烷基侧链上。所研究的聚合物体系包括聚芴 (PF) 作为基础共轭聚合物，咔唑 (Cz) 作为电荷传输部分和通过与 PF 主链形成电复合物而产生绿色发射源，以及作为磷光的环金属化铱 (Ir) 配合物掺杂剂。除了来自PF主链的能量从绿色Ir配合物或芴主链和侧链咔唑部分之间形成的电复合物转移到红色Ir配合物之外，还可以显着提高器件性能，

  DOI：

  10.1021/ja0211151

文献信息

• Electroluminescent conjugated polymers containing phosphorescent moieties and the application thereof in LED
  申请人：National Tsing Hua University

  公开号：US20040260047A1

  公开（公告）日：2004-12-23

  This invention provides a new electroluminescent conjugated polymers grafted with highly efficient phosphorescent organometallic complexes (such as iridium, platinum, osmium, rubidium, etc.) and charge transport moieties (such as oxadiazole, thiadiazole, triazole, pyridine, pyrimidine, substituted or non-substituted tertiary arylamines, substituted or non-substituted quarternary arylammonium salts, substituted or non-substituted tertiary heterocyclic aromatic amines, substituted or non-substituted quarternary heterocyclic aromatic ammonium, etc.). The emissive polymers (fully conjugated or limited conjugating length) covering the full visible range can be prepared. The polymeric light emitting diodes with these materials can be used as indicators, light source and display for cellular phones, digital camera, pager, portable computer, personal data acquisition (PDA), watch, hand-held videogame, billboard, etc.

  该发明提供了一种新的电致发光共轭聚合物，其搭载高效的磷光有机金属络合物（如铱、铂、锇、铷等）和电荷传输基团（如氧化二唑、噻二唑、三唑、吡啶、嘧啶、取代或非取代的三级芳香胺、取代或非取代的季铵芳香基盐、取代或非取代的三级杂环芳香胺、取代或非取代的季杂环芳香铵等）。可以制备覆盖整个可见光范围的发射聚合物（完全共轭或有限共轭长度）。使用这些材料制作的聚合物发光二极管可以用作手机、数码相机、寻呼机、便携式电脑、个人数据采集器（PDA）、手持视频游戏、广告牌等的指示器、光源和显示器。
• Electroluminescent conjugated polymers containing phosphorescent moieties and the application thereof in led
  申请人：National Tsing Hua University

  公开号：US07098295B2

  公开（公告）日：2006-08-29

  This invention provides a new electroluminescent conjugated polymers grafted with highly efficient phosphorescent organometallic complexes (such as iridium, platinum, osmium, rubidium, etc.) and charge transport moieties (such as oxadiazole, thiadiazole, triazole, pyridine, pyrimidine, substituted or non-substituted tertiary arylamines, substituted or non-substituted quarternary arylammonium salts, substituted or non-substituted tertiary heterocyclic aromatic amines, substituted or non-substituted quarternary heterocyclic aromatic ammonium, etc.). The emissive polymers (fully conjugated or limited conjugating length) covering the full visible range can be prepared. The polymeric light emitting diodes with these materials can be used as indicators, light source and display for cellular phones, digital camera, pager, portable computer, personal data acquisition (PDA), watch, hand-held videogame, billboard, etc.

  本发明提供了一种新的电致发光共轭聚合物，其搭载了高效的螯合有机金属复合物（如铱、铂、锇、铷等）和电荷传输基元（如噁二唑、噻二唑、三唑、吡啶、嘧啶、取代或非取代的三级芳胺、取代或非取代的季铵芳基盐、取代或非取代的三级杂环芳基胺、取代或非取代的季杂环芳基铵等）。可制备覆盖整个可见光范围的发光聚合物（完全共轭或有限共轭长度）。使用这些材料制成的聚合物发光二极管可用作手机、数码相机、寻呼机、便携式电脑、个人数据采集器（PDA）、手持游戏机、广告牌等的指示器、光源和显示器。
• New bead type and high symmetrical diallyl-POSS based emissive conjugated polyfluorene
  作者：Jin Huang、Weina Wang、Jiangjiang Gu、Weizhi Li、Qiuhong Zhang、Yin Ding、Kai Xi、Youxuan Zheng、Xudong Jia

  DOI：10.1016/j.polymer.2014.10.071

  日期：2014.12

  A new bead type and diallyl-POSS based polyfluorene (P2) with high symmetrical structure was synthesized via Heck coupling reaction between oligomeric alkynyl fluorene (P1) and diallyl polyhedral oligomeric silsesquioxanes (diallyl-POSS). The molecular weight and the conjugated length of P1 and P2 were well controlled to acquire good solubility and excellent optical property. The bead-type POSS based polymer was characterized by gel permeation chromatography (GPC), FT-IR, H-1 NMR and photo-luminescence (PL) spectra. High Resolution Transmission Electron Microscopy (HRTEM) micrographs showed that diallyl-POSS were uniformly nano-dispersed in the polymer matrix. Compared with P1, the POSS based polyfluorene P2 exhibited not only a higher thermal stability, but also an improved photophysical property in solution and solid states. The incorporation of diallyl-POSS resulted effectively in inhibiting the strong stacking/dipole-dipole interaction between fluorescent groups in the polyfluorene. The experimental results indicate that the bi-functional FOSS based light-emitting polymers with high symmetrical structure can have great potential in optical materials and devices, such as OPV or PLED, etc. (C) 2014 Elsevier Ltd. All rights reserved.
• US7098295B2
  申请人：——

  公开号：US7098295B2

  公开（公告）日：2006-08-29
• US7220819B2
  申请人：——

  公开号：US7220819B2

  公开（公告）日：2007-05-22