N'-[1-Ethyl-2-methyl-pent-(Z)-ylidene]-N,N-dimethyl-hydrazine | 1027895-96-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N'-[1-Ethyl-2-methyl-pent-(Z)-ylidene]-N,N-dimethyl-hydrazine
• 英文别名: N-methyl-N-[(Z)-4-methylheptan-3-ylideneamino]methanamine
• CAS: 1027895-96-0
• 化学式: C₁₀H₂₂N₂
• 分子量: 170.298
• InChiKey: QTUSMHVGDURZKH-KHPPLWFESA-N

物化性质

• 沸点：
  219.6±23.0 °C(Predicted)
• 密度：
  0.83±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  15.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N'-[1-Ethyl-2-methyl-pent-(Z)-ylidene]-N,N-dimethyl-hydrazine 在 sodium periodate 作用下， 以 甲醇 、 phosphate buffer 为溶剂， 反应 3.0h， 生成 4-甲基-3-庚酮
  参考文献：
  名称：

  Identification and Assignment of the Absolute Configuration of Biologically Active Methyl-Branched Ketones from Limnephilid Caddis Flies

  摘要：

  Glands of the 4th and 5th abdominal sternite of the caddis flies Potamophylax latipennis, Potamophylax cingulatus, and Glyphotaelius pellucidus contain (S)-4-methyl-3-heptanone (4a), (4S,6S)-4,6-dimethyl-3-octanone (4b), and (4S,6S)-4,6-dimethyl-3-nonanone (4c). As shown by gas chromatography coupled with electrophysiological recordings, these ketones elicit a strong response in the insects' antennae. The structural assignment of the compounds was achieved on the basis of mass spectra, enantioselective synthesis, and gas chromatography on a chiral stationary phase.

  DOI：

  10.1002/1099-0690(200108)2001:16<3175::aid-ejoc3175>3.0.co;2-4
• 作为产物：
  描述：

  3-戊酮 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 12.0h， 生成 N'-[1-Ethyl-2-methyl-pent-(Z)-ylidene]-N,N-dimethyl-hydrazine
  参考文献：
  名称：

  Identification and Assignment of the Absolute Configuration of Biologically Active Methyl-Branched Ketones from Limnephilid Caddis Flies

  摘要：

  Glands of the 4th and 5th abdominal sternite of the caddis flies Potamophylax latipennis, Potamophylax cingulatus, and Glyphotaelius pellucidus contain (S)-4-methyl-3-heptanone (4a), (4S,6S)-4,6-dimethyl-3-octanone (4b), and (4S,6S)-4,6-dimethyl-3-nonanone (4c). As shown by gas chromatography coupled with electrophysiological recordings, these ketones elicit a strong response in the insects' antennae. The structural assignment of the compounds was achieved on the basis of mass spectra, enantioselective synthesis, and gas chromatography on a chiral stationary phase.

  DOI：

  10.1002/1099-0690(200108)2001:16<3175::aid-ejoc3175>3.0.co;2-4