2,3-bis-n-decyloxyanthracene | 134589-26-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,3-bis-n-decyloxyanthracene
• 英文别名: 2,3-bis(decyloxy)anthracene；2,3-di-n-decyloxyanthracene；2,3-di(decyloxy)anthracene；2,3-Didecyloxyanthracene；DDOA；Anthracene, 2,3-bis(decyloxy)-；2,3-didecoxyanthracene
• CAS: 134589-26-7
• 化学式: C₃₄H₅₀O₂
• 分子量: 490.77
• InChiKey: IGLNPUKXMDPAAI-UHFFFAOYSA-N

物化性质

• 沸点：
  603.3±28.0 °C(Predicted)
• 密度：
  0.976±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  13.1
• 重原子数：
  36
• 可旋转键数：
  20
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,3-bis-n-decyloxyanthracene 在 palladium on activated charcoal 氢气 作用下， 以 乙醇 为溶剂， 反应 72.0h， 以50%的产率得到2,3-Didecoxy-9,10-dihydroanthracene
  参考文献：
  名称：

  A new example of small molecular non-hydrogen bonding gelators for organic solvents

  摘要：

  Two novel low molecular weight gelling agents 1 and 2 for organic sovents are presented. These molecules, which do not contain hydrogen bonding groups, can gelify reversibly a great variety of solvents. (C) 1997 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)00409-7
• 作为产物：
  描述：

  癸基溴 在 sodium tetrahydroborate 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 、 异丙醇 为溶剂， 生成 2,3-bis-n-decyloxyanthracene
  参考文献：
  名称：

  A novel small molecular luminescent gelling agent for alcohols

  摘要：

  2,3-双正癸氧基蒽在极低浓度下就能与醇类形成热可逆凝胶；电子吸收光谱和荧光发射研究表明，凝胶网络由与醇类共存的芳香族成分的头尾集合体组成，系统的组织主要依靠偶极力和范德华相互作用。

  DOI：

  10.1039/c39910000416

文献信息

• Trans-1,2-cyclohexane bis(urea-urethane) compounds
  申请人：Goredema Adela

  公开号：US20060122416A1

  公开（公告）日：2006-06-08

  Disclosed are trans-1,2-cyclohexane bis(urea-urethane) compounds of the formulae wherein R 1 and R′ 1 each, independently of the other, is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, R 2 and R′ 2 each, independently of the other, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, R 3 and R′ 3 each, independently of the other, is a hydrogen atom or an alkyl group, R 4 and R′ 4 each, independently of the other, is a hydrogen atom, a fluorine atom, an alkyl group, or a phenyl group, n is an integer of 0, 1, 2, 3, or 4, and R 5 is an alkyl group, an aryl group, an arylalkyl group, an alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group.

  揭示了具有以下结构的trans-1,2-环己烷双(脲-脲酮)化合物，其中R1和R′1各自独立地是一个烷基基团、芳基基团、芳基烷基基团或烷基芳基基团，R2和R′2各自独立地是一个烷基基团、芳基基团、芳基烷基基团或烷基芳基基团，R3和R′3各自独立地是氢原子或烷基基团，R4和R′4各自独立地是氢原子、氟原子、烷基基团或苯基团，n为0、1、2、3或4的整数，R5是一个烷基基团、芳基基团、芳基烷基基团、烷基芳基基团或除烷基、芳基、芳基烷基或烷基芳基基团之外的取代基。
• Different synthetic routes towards efficient organogelators: 2,3-substituted anthracenes
  作者：Jean-Luc Pozzo、Gilles M. Clavier、Michel Colomes、Henri Bouas-Laurent

  DOI：10.1016/s0040-4020(97)00297-4

  日期：1997.5

  synthetic approaches towards 2,3-substituted anthracenes are reported and discussed in terms of selectivity and viability. This allowed us to introduce a variety of substituents as sidearms. Promising results have been found using a tandem Diels-Alder aromatization reaction using 2,3-dimethoxybutadiene 9 as a key intermediate. However, for multigram preparations the Friedel-Crafts approach is preferred

  报告了关于2，3-取代的蒽的三种合成方法，并在选择性和生存力方面进行了讨论。这使我们可以引入各种取代基作为侧链。使用串联的Diels-Alder芳构化反应（使用2,3-二甲氧基丁二烯9作为关键中间体）发现了令人鼓舞的结果。但是，对于多谱图制备，首选Friedel-Crafts方法。
• Alkylated urea and triaminotriazine compounds and phase change inks containing same
  申请人：Xerox Corporation

  公开号：US20040075723A1

  公开（公告）日：2004-04-22

  Disclosed are compounds of the formulae 1 2 wherein Z is a group of the formula —OR 1 , a group of the formula —SR 1 , or a group of the formula —NR 1 R 2 , Y is a group of the formula —OR 3 , a group of the formula —SR 3 , or a group of the formula —NR 3 R 4 , n is an integer representing the number of repeat —(CH 2 )— or —(CH 2 CH 2 O)— units, wherein, provided that at least one of R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 is a hydrogen atom, provided that at least one of R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 is other than a hydrogen atom, and provided that at least one Z or Y within the compound is a group of the formula —NR 1 R 2 or a group of the formula —NR 3 R 4 , R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 each, independently of the others, is (i) a hydrogen atom, (ii) an alkyl group, (iii) an aryl group, (iv) an arylalkyl group, or (v) an alkylaryl group, and wherein R 7 can also be (vi) an alkoxy group, (vii) an aryloxy group, (viii) an arylalkyloxy group, (ix) an alkylaryloxy group, (x) a polyalkyleneoxy group, (xi) a polyaryleneoxy group, (xii) a polyarylalkyleneoxy group, (xiii) a polyalkylaryleneoxy group, (xiv) a silyl group, (xv) a siloxane group, (xvi) a polysilylene group, (xvii) a polysiloxane group, or (xviii) a group of the formula 3 wherein r is an integer representing a number of repeat —CH 2 — groups, wherein s is an integer representing a number of repeating —CH 2 — groups, and wherein X is (a) a direct bond, (b) an oxygen atom, (c) a sulfur atom, (d) a group of the formula —NR 40 — wherein R 40 is a hydrogen atom, an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, or (e) a group of the formula —CR 50 R 60 — wherein R 50 and R 60 each, independently of the other, is a hydrogen atom, an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and wherein R 6 can also be 4 Also disclosed are phase change ink compositions comprising a colorant and a phase change ink carrier comprising a material of this formula.

  揭示了以下式的化合物，其中 Z 是以下式的基团之一：—OR1、—SR1，或者—NR1R2；Y 是以下式的基团之一：—OR3、—SR3，或者—NR3R4；n 是表示重复单元数目的整数，其中至少其中一个 R1、R2、R3、R4、R5 和 R6 是氢原子，至少其中一个 R1、R2、R3、R4、R5 和 R6 不是氢原子，以及至少化合物中的一个 Z 或 Y 是以下式的基团之一：—NR1R2 或者—NR3R4，R1、R2、R3、R4、R5、R6 和 R7 每个独立地是 (i) 氢原子、(ii) 烷基基团、(iii) 芳基团、(iv) 芳基烷基团，或者 (v) 烷基芳基团，其中 R7 也可以是 (vi) 烷氧基团、(vii) 芳氧基团、(viii) 芳基烷氧基团、(ix) 烷基芳氧基团、(x) 聚烷氧基团、(xi) 聚芳氧基团、(xii) 聚芳基烷氧基团、(xiii) 聚烷芳氧基团、(xiv) 硅基团、(xv) 硅氧烷基团、(xvi) 聚硅烷基团、(xvii) 聚硅氧烷基团，或者 (xviii) 以下式的基团之一：3，其中 r 是表示重复 —CH2— 基团数目的整数，s 是表示重复 —CH2— 基团数目的整数，X 是 (a) 直接键、(b) 氧原子、(c) 硫原子、(d) —NR40— 基团，其中 R40 是氢原子、烷基基团、芳基团、芳基烷基团，或者烷基芳基团，或者 (e) —CR50R60— 基团，其中 R50 和 R60 每个独立地是氢原子、烷基基团、芳基团、芳基烷基团，或者烷基芳基团，而 R6 也可以是。还揭示了包括颜料和相变墨 carrier 的相变墨组成物，其中 carrier 包含此式的材料。
• ALKYLATED TETRAKIS(TRIAMINOTRIAZINE) COMPOUNDS AND PHASE CHANGE INKS CONTAINING SAME
  申请人：Xerox Corporation

  公开号：US20040050295A1

  公开（公告）日：2004-03-18

  Disclosed are compounds of the formulae 1 wherein, provided that at least one of R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 is a hydrogen atom, and provided that at least one of R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 is not a hydrogen atom, R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 each, independently of the others, is (i) a hydrogen atom, (ii) an alkyl group, (iii) an aryl group, (iv) an arylalkyl group, or (v) an alkylaryl group. Also disclosed are phase change ink compositions comprising a colorant and a phase change ink carrier comprising a material of this formula.

  揭示的是以下化合物的结构式，其中，假设至少有一个R1、R2、R3、R4、R5和R6是氢原子，并且假设至少有一个R1、R2、R3、R4、R5和R6不是氢原子，R1、R2、R3、R4、R5和R6中的每一个，独立于其他者，是（i）氢原子，（ii）烷基基团，（iii）芳基团，（iv）芳基烷基团，或（v）烷基芳基团。还揭示了包括颜料和相变墨水载体的相变墨水组合物，其中相变墨水载体包括这种结构的材料。
• Bis[urea-urethane] compounds
  申请人：Goredema Adela

  公开号：US20060122427A1

  公开（公告）日：2006-06-08

  Disclosed is a bis(urea-urethane) compound of the formula wherein R 1 and R 1 ′ each, independently of the other, is an alkyl group, wherein at least one of R 1 and R 1 ′ has at least about 6 carbon atoms, R 2 and R 2 ′ each, independently of the other, is an alkylene group, wherein at least one of R 2 and R 2 ′ has at least about 3 carbon atoms, R 3 is an alkylene group having at least about 2 carbon atoms, and R 4 and R 5 each, independently of the other, is a hydrogen atom or an alkyl group, and wherein R 1 and R 1 ′ each contain no more than 2 fully fluorinated carbon atoms.

  公开的是一种双（脲-脲基）尿素化合物，其化学式为：其中R1和R1'各自独立地为烷基，其中至少有一个R1和R1'含有至少约6个碳原子，R2和R2'各自独立地为亚烷基，其中至少有一个R2和R2'含有至少约3个碳原子，R3是含有至少约2个碳原子的亚烷基，R4和R5各自独立地为氢原子或烷基，并且其中R1和R1'各自不含有超过2个全氟碳原子。