octadecyl-phenyl sulfide | 60835-11-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: octadecyl-phenyl sulfide
• 英文别名: Octadecyl-phenyl-sulfid；(Octadecylsulfanyl)benzene；octadecylsulfanylbenzene
• CAS: 60835-11-2
• 化学式: C₂₄H₄₂S
• 分子量: 362.663
• InChiKey: MONXDINEKYBHCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.3
• 重原子数：
  25
• 可旋转键数：
  18
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  octadecyl-phenyl sulfide 在 potassium permanganate 、 溶剂黄146 作用下， 生成 n-十八烷基苯基砜
  参考文献：
  名称：

  Alkylation with Long Chain p-Toluenesulfonates. II. Reaction of n-Octadecyl p-Toluenesulfonate with Mercaptans and Thiophenols¹

  摘要：

  DOI：

  10.1021/ja01154a122
• 作为产物：
  描述：

  n-octadecylphenylsulfoxide 在 sodium tetrahydroborate 、 nickel dichloride 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以96%的产率得到octadecyl-phenyl sulfide
  参考文献：
  名称：

  Deoxygenation of sulfoxides and selenoxides with nickel boride

  摘要：

  The deoxygenations of a variety of acyclic sulfoxides and selenoxides have been reported with nickel boride in THF at 0-5 degrees C in nearly quantitative yields. The deoxygenations are proposed to proceed by an oxidative-addition and reductive-elimination mechanism. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)00623-6

文献信息

• Gasparrini, F.; Giovannoli, M.; Maresca, L., Synthetic Communications, 1984, vol. 14, # 12, p. 1111 - 1118
  作者：Gasparrini, F.、Giovannoli, M.、Maresca, L.、Natile, G.、Palmieri, G.

  DOI：——

  日期：——
• A general procedure for the selective oxidation of sulfides to sulfoxides by nitric acid: tetrabromoaurate(III) catalyst in a biphasic system
  作者：Francesco Gasparrini、Mario Giovannoli、Domenico Misiti、Giovanni Natile、Gianni Palmieri

  DOI：10.1021/jo00291a043

  日期：1990.2
• Hydrozirconation of oleyl sulphides and oleyl phenylsulphone
  作者：Susanne Karlsson、Anders Hallberg、Salo Gronowitz

  DOI：10.1016/0022-328x(92)80095-f

  日期：1992.6

  The hydrozirconation of 9-(Z)-octadecenylmethyl-sulphide, 9-(Z)-octadecenyl phenyl sulphide and 9-(Z)-octadecenyl phenyl sulphone have been studied. These compounds underwent substantial elimination of the functional group, yielding after hydrolysis, along with saturated and unsaturated sulphides and sulphones, large amounts of octadecane. The saturated analogues (dodecylmethyl-sulphide, octadecyl phenyl sulphide and octadecyl phenyl sulphone) were unaffected by the hydrozirconation reagent under similar conditions.
• GASPARRINI, F.;GIOVANNOLI, M.;MARESCA, L.;NATILE, G.;PALMIERI, G., SYNTH. COMMUN., 1984, 14, N 12, 1111-1117
  作者：GASPARRINI, F.、GIOVANNOLI, M.、MARESCA, L.、NATILE, G.、PALMIERI, G.

  DOI：——

  日期：——
• Procédé de stabilisation des mélanges de chloration du phenol et/ou de chlorophenols
  申请人：RHONE-POULENC CHIMIE

  公开号：EP0262061B1

  公开（公告）日：1993-02-24