(p,p'-diphenylmethylenediphosphinato)lead(II) | 569650-21-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (p,p'-diphenylmethylenediphosphinato)lead(II)
• 英文别名: lead(II)(P,P'-diphenylmethylenediphosphinic acid(2-))；4,6-Diphenyl-1,3,4lambda5,6lambda5,2lambda2-dioxadiphosphaplumbinane 4,6-dioxide；4,6-diphenyl-1,3,4λ5,6λ5,2λ2-dioxadiphosphaplumbinane 4,6-dioxide
• CAS: 569650-21-1
• 化学式: C₁₃H₁₂O₄P₂*Pb
• 分子量: 501.383
• InChiKey: ACKYVVXTTRWUCY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.73
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  lead(II) nitrate 、 P,P'-diphenyl-methylenediphosphinic acid 以 水 为溶剂， 以63%的产率得到(p,p'-diphenylmethylenediphosphinato)lead(II)
  参考文献：
  名称：

  A new lead(II) inorganic–organic hybrid of the P,P′-diphenylmethylene-diphosphinate ligand: synthesis and X-ray characterization of the [Pb(CH2(P(Ph)O2)2)] complex

  摘要：

  By reaction of lead(II) nitrate with P, P'-diphenylmethylenediphosphinic acid in water solution a new inorganic-organic hybrid of formula [Pb(CH2(P(Ph)O-2)(2))] has been synthesized and structurally characterized. The complex displays a polymeric columnar structure, the column being formed by two intersecting sinusoidal ribbons of lead(II) ions bridged by bifunctional phosphinate ligands. The intersections of the ribbons are constituted by dimeric units of pentacoordinated lead(II) ions. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00037-6

文献信息

• A new lead(II) inorganic–organic hybrid of the P,P′-diphenylmethylene-diphosphinate ligand: synthesis and X-ray characterization of the [Pb(CH2(P(Ph)O2)2)] complex
  作者：Franco Cecconi、Carlo A Ghilardi、Stefano Midollini、Annabella Orlandini

  DOI：10.1016/s1387-7003(03)00037-6

  日期：2003.5

  By reaction of lead(II) nitrate with P, P'-diphenylmethylenediphosphinic acid in water solution a new inorganic-organic hybrid of formula [Pb(CH2(P(Ph)O-2)(2))] has been synthesized and structurally characterized. The complex displays a polymeric columnar structure, the column being formed by two intersecting sinusoidal ribbons of lead(II) ions bridged by bifunctional phosphinate ligands. The intersections of the ribbons are constituted by dimeric units of pentacoordinated lead(II) ions. (C) 2003 Elsevier Science B.V. All rights reserved.