2-甲基-4-硝基-2,4-二氮杂戊烷 | 104892-75-3

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 中文名称: 2-甲基-4-硝基-2,4-二氮杂戊烷
• 英文名称: 2-methyl-4-nitro-2,4-diazapentane
• 英文别名: 2-nitro-4-methyl-2,4-diazapentane；N-[(Dimethylamino)methyl]-N-methylnitramide
• CAS: 104892-75-3
• 化学式: C₄H₁₁N₃O₂
• 分子量: 133.15
• InChiKey: JEWQLSPLGQWXLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N,N-二甲基三甲基硅胺 、 2-nitro-1-trimethylsiloxy-2-azapropane 反应 2.0h， 以90%的产率得到2-甲基-4-硝基-2,4-二氮杂戊烷
  参考文献：
  名称：

  Investigation of the alkylation ability of silylated nitroalcohols

  摘要：

  Beta-nitrosubstituted trimethylsilylated alcohols RCH2-O-SiMe3 [R = N(NO2)Me, C(NO2)Me2, C(NO2)2Me, C(NO2)3] have been studied. It has been shown that the trimethylsiloxy group is sufficiently reactive only in the N-nitro derivative in which it can be replaced by a chlorine atom or dimethylamino group upon the action of trimethylchlorosilane or pentamethyldisilazane, respectively.

  DOI：

  10.1007/bf00702022

文献信息

• Nonaqueous condensation of silylated C- and N-nitro compounds with trimethylsiloxymethyldialkylamines
  作者：A. V. Kalinin、�. T. Apasov、S. L. Ioffe、V. P. Kozyukov、Vik P. Kozyukov

  DOI：10.1007/bf00956826

  日期：1985.11
• KALININ, A. V.;APASOV, EH. T.;IOFFE, S. L.;KOZYUKOV, V. P.;KOZYUKOV, VIK.+, IZV. AN CCCP. CEP. XIM., 1985, N 11, 2635-2636
  作者：KALININ, A. V.、APASOV, EH. T.、IOFFE, S. L.、KOZYUKOV, V. P.、KOZYUKOV, VIK.+

  DOI：——

  日期：——
• Investigation of the alkylation ability of silylated nitroalcohols
  作者：E. T. Apasov、A. V. Kalinin、S. L. Ioffe、V. A. Tartakovskii

  DOI：10.1007/bf00702022

  日期：1993.7

  Beta-nitrosubstituted trimethylsilylated alcohols RCH2-O-SiMe3 [R = N(NO2)Me, C(NO2)Me2, C(NO2)2Me, C(NO2)3] have been studied. It has been shown that the trimethylsiloxy group is sufficiently reactive only in the N-nitro derivative in which it can be replaced by a chlorine atom or dimethylamino group upon the action of trimethylchlorosilane or pentamethyldisilazane, respectively.