(Z)-4-chloro-benzenediazo hydroxide | 36966-92-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (Z)-4-chloro-benzenediazo hydroxide
• 英文别名: (Z)-4-Chlor-benzoldiazohydroxid；4-Chlor-benzol-normaldiazohydroxyd-(1)；4-Chlor-benzol-normaldiazotat；p-Chlor-benzolnormaldiazotat；4-Chlor-benzol-syn-diazotat；N-(4-chlorophenyl)nitrous amide
• CAS: 36966-92-4
• 化学式: C₆H₅ClN₂O
• 分子量: 156.572
• InChiKey: LPEQVCQBHZAYLO-UHFFFAOYSA-N

物化性质

• 沸点：
  218.4±42.0 °C(Predicted)
• 密度：
  1.34±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  41.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (Z)-4-chloro-benzenediazo hydroxide 生成 (Z)-(4-chloro-phenyl)-diazenecarbonitrile
  参考文献：
  名称：

  Bamberger, Chemische Berichte, 1920, vol. 53, p. 2320

  摘要：

  DOI：
• 作为产物：
  描述：

  4-氯-偶氮苯 在 hydroxide 作用下， 生成 (Z)-4-chloro-benzenediazo hydroxide
  参考文献：
  名称：

  Goodman, Paul D.; Kemp, Terence J.; Moira, Peter Pinot de, Journal of the Chemical Society. Perkin transactions II, 1981, p. 1221 - 1229

  摘要：

  DOI：

文献信息

• Rh(II)-catalyzed intramolecular annulation of N-sulfonyl 1,2,3-triazoles with indole derivatives: a new method for synthesis pyranoindoles
  作者：Hui Xie、Jian-Xin Yang、Pranjal Protim Bora、Qiang Kang

  DOI：10.1016/j.tet.2016.04.017

  日期：2016.6

  for the synthesis of Z-alkenyl-pyranoindoles had been developed by utilizing Rh(II)-catalyzed intramolecular cyclization of N-sulfonyl-1,2,3-triazoles with indole derivatives. A variety of pyranoindoles were obtained in 44–93% yields. Moreover, a more convenient synthesis of pyranoindoles starting from terminal alkyne was realized via a Cu–Rh sequentially catalyzed one-pot cascade reaction.

  通过利用Rh（II）催化的带有吲哚衍生物的N-磺酰基-1,2,3-三唑的分子内环化作用，已经开发了直接和高度立体选择性的合成Z-烯基-吡喃并吲哚的方法。以44–93％的产率获得了多种吡喃吲哚。此外，通过铜-Rh顺序催化的一锅级联反应，实现了从末端炔烃开始更方便地合成吡喃并吲哚。
• Intermediate Sanctions: A Comparative Analysis of the Probability and Severity of Recidivism
  作者：Jeffery T. Ulmer

  DOI：10.1111/j.1475-682x.2001.tb01107.x

  日期：2001.4

  Social scientists have a longstanding concern with the relationship between criminal sanctions and offenders’future behavior. This paper uses data from a sample of 528 adult felony offenders to compare the relative probability of rearrest, the severity of rearrest, and the likelihood of probation revocation for offenders with a sentence of incarceration, work release, house arrest, and traditional probation—or a combination of these sentences. Consistent with previous research, prior record, gender, offense type, and education were significantly related to the probability and severity of rearrest. Furthermore, no matter which other sanction it was paired with, house arrest was associated with reduced chances of rearrest and lower rearrest severity. The influence of one of these sanction combinations was gender‐specific: incarceration followed by house arrest was associated with reduced odds of rearrest for women but not for men. However, house arrest was associated with the considerably increased likelihood of probation revocation. In addition, these effects remain after controlling for potential selection bias stemming from the sentencing decision. This paper concludes by discussing the theoretical and correctional implications of these findings and directions for future research.

  社会科学家长期关注刑事制裁与罪犯未来行为之间的关系。本文利用 528 名成年重罪罪犯的样本数据，比较了被判处监禁、劳动改造、软禁和传统缓刑或这些刑罚组合的罪犯再次被捕的相对概率、再次被捕的严重程度和缓刑撤销的可能性。与之前的研究一致，前科、性别、犯罪类型和教育程度与再次被捕的可能性和严重程度有显著关系。此外，无论软禁与其他哪种刑罚搭配，都会降低再次被捕的几率和再次被捕的严重程度。其中一种处罚组合的影响是有性别差异的：监禁后软禁与女性再次被捕的几率降低有关，但与男性再次被捕的几率降低无关。然而，软禁与缓刑撤销的可能性大大增加有关。此外，在控制了判决决定可能产生的选择偏差后，这些影响依然存在。本文最后讨论了这些发现的理论和矫正影响以及未来研究的方向。
• Goodman, Paul D.; Kemp, Terence J.; Moira, Peter Pinot de, Journal of the Chemical Society. Perkin transactions II, 1981, p. 1221 - 1229
  作者：Goodman, Paul D.、Kemp, Terence J.、Moira, Peter Pinot de

  DOI：——

  日期：——
• Lewis; Suhr, Chemische Berichte, 1958, vol. 91, p. 2350,2353,2358
  作者：Lewis、Suhr

  DOI：——

  日期：——
• Hantzsch, Chemische Berichte, 1898, vol. 31, p. 640
  作者：Hantzsch

  DOI：——

  日期：——