2-Mercaptoethyl methacrylate | 44836-12-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-Mercaptoethyl methacrylate
• 英文别名: 2-sulfanylethyl 2-methylprop-2-enoate
• CAS: 44836-12-6
• 化学式: C₆H₁₀O₂S
• 分子量: 146.21
• InChiKey: UHSAXACYGOKSED-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  27.3
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• [EN] POLYMERIZABLE COMPOUNDS WITH QUADRUPLE HYDROGEN BOND FORMING GROUPS<br/>[FR] COMPOSES POLYMERISABLES AVEC GROUPES FORMANT DES LIAISONS HYDROGENE QUADRUPLES
  申请人：KODAK POLYCHROME GRAPHICS LLC

  公开号：WO2004043935A1

  公开（公告）日：2004-05-27

  QHB-Modified free radical polymerizable compounds and free radical polymerizable compositions that comprise these compounds are disclosed. A QBH-modified free radical polymerizable compound has at least one moiety that comprises at least one free radical polymerizable group; a supporting backbone, and at least one and preferably at least two moieties capable of forming four or more, typically four, hydrogen bonds with similar or complementary units on other molecules or portions of molecules. Free radical polymerizable compositions that contain these compounds may be used in any of the well-knows applications for free radical polymerizable compositions. They are especially useful for the formation of imageable elements useful as lithographic printing plate precursors.

  修改后的自由基可聚合化合物和包含这些化合物的自由基可聚合化组合物已被披露。一种QBH修饰的自由基可聚合化合物至少具有一个包含至少一个自由基可聚合基团的基团；一个支撑骨架，以及至少一个并且最好至少两个能够与其他分子或分子部分上的类似或互补单元形成四个或更多，通常为四个，氢键的基团。包含这些化合物的自由基可聚合化组合物可用于任何已知的自由基可聚合化组合物的应用中。它们特别适用于形成可用作平版印刷版前体的可成像元素。
• Reactive Dyes For Contact Lenses
  申请人：Xu Yuan

  公开号：US20140200287A1

  公开（公告）日：2014-07-17

  A method for preparing a polymerizable monomer-dye compound is provided in which a monomer, a reactive dye, and base are combined under substantially anhydrous reaction conditions to form the polymerizable monomer-dye compound, wherein the monomer comprises a pendant reactive group that covalently links to the reactive dye to form the monomer-dye compound.

  提供了一种制备可聚合单体染料化合物的方法，其中，在基本无水反应条件下，将单体、反应性染料和碱性物质结合起来形成可聚合单体染料化合物，其中，单体包括一个悬挂的反应性基团，该反应性基团共价连接到反应性染料上形成单体染料化合物。
• COATINGS THAT PROVIDE HYDROPHILIC SURFACE
  申请人：EMPIRE TECHNOLOGY DEVELOPMENT LLC

  公开号：US20160075906A1

  公开（公告）日：2016-03-17

  Hydrophilic coating compositions and methods to make and use the compositions are disclosed. The compositions include a polymer comprising one or more cyanate groups and a blocking agent contacting at least one of one or more cyanate groups. When exposed to atmospheric water, the blocked cyanate moieties at the surface may hydrolyze to expose hydrophilic groups. Thus, the hydrophobic polymeric surface may change to a hydrophilic surface upon reacting with atmospheric water and moisture.

  本发明公开了亲水性涂层组合物的制备方法及其使用方法。该组合物包括聚合物，该聚合物包含一个或多个氰酸酯基团和至少与一个或多个氰酸酯基团接触的阻断剂。当暴露于大气水分时，表面的阻断氰酸酯基团可能水解以暴露出亲水基团。因此，与大气水分反应后，疏水性聚合物表面可能变为亲水性表面。
• Polymerization method utilizing a three-phase emulsion system
  申请人：CALGON CORPORATION

  公开号：EP0034087A2

  公开（公告）日：1981-08-19

  Polymerization method utilizing a three-phase system: water-in-oil-in-water or oil-in-water-in-oil comprising the steps a) adding the monomer material to be polymerized into the innermost water or oil phase; b) adding, with mechanical agitation, the product of Step a to the middle oil or water phase, said phase containing appropriate surfactant, whereby an emulsion is formed; c) adding, with mechanical agitation, the emulsion product of Step b to the outermost water or oil phase, said phase containing appropriate surfactant, wherein polymerization proceeds in the innermost water or oil phase until complete.

  利用三相系统的聚合方法：水包油或油包水的聚合方法，包括以下步骤 a) 将待聚合的单体材料加入最内层的水相或油相； b) 在机械搅拌下，将步骤 a 的产物加入中间的油相或水相，所述相含有适当的表面活性剂，从而形成乳液； c) 在机械搅拌下，将步骤 b 的乳液产物加入最外层的水相或油相，所述相含有适当的表面活性剂，聚合作用在最内层的水相或油相中进行，直至完成。
• Structural adhesive compositions, three component redox catalyst systems and their use in bonding metal surfaces together
  申请人：LORD CORPORATION

  公开号：EP0167223A1

  公开（公告）日：1986-01-08

  Two-package, equal-mix acrylic adhesive compositions are provided, containing as a curing agent a mixture of peroxygen compound, an organic thiol and certain metal ion-containing compounds. Also provided is a three-component oxidation-reduction catalyst system consisting of an organic hydroperoxide, an organic thiol and an inorganic or organic compound of a metal having a standard reduction potential of from +0.9 to -0.5

  提供了双包装、等量混合的丙烯酸粘合剂组合物，其中含有过氧化合物、有机硫醇和某些含金属离子化合物的混合物作为固化剂。 还提供了一种三组分氧化还原催化剂系统，该系统由有机过氧化氢、有机硫醇和无机或有机金属化合物组成，其标准还原电位为 +0.9 至 -0.5