1,4-dibromo-decane | 70690-25-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 英文名称: 1,4-dibromo-decane
• 英文别名: 1,4-Dibrom-decan；1,4-Dibromodecane
• CAS: 70690-25-4
• 化学式: C₁₀H₂₀Br₂
• 分子量: 300.077
• InChiKey: GEUKNIUPSVPXSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,4-dibromo-decane 在 氢氧化钾 、 乙醇 作用下， 生成 2-hexyl-adipic acid
  参考文献：
  名称：

  Franke; Kroupa, Monatshefte fur Chemie, 1930, vol. 56, p. 349

  摘要：

  DOI：
• 作为产物：
  描述：

  1-methoxy-decan-4-ol 在 氢溴酸 、 三溴化磷 作用下， 生成 1,4-dibromo-decane
  参考文献：
  名称：

  Synthesis of 2- and 3-alkyl(cycloalkyl, phenyl)thiophanes

  摘要：

  DOI：

  10.1007/bf00963318

文献信息

• Electrophotographic organophotoreceptors with novel charge transport compounds
  申请人：SAMSUNG Electronics Co. Ltd.

  公开号：US20030219662A1

  公开（公告）日：2003-11-27

  Charge transport compounds are described that have a multiple number of hydrazone-bridged heterocyclic groups (especially julolidine groups, carbazole groups, triarylamine groups and (N,N-disubstituted)arylamine groups such as dialkarylamine groups (e.g. dimethylphenylamine; methylethylphenylamine, dipropylphenylamine, ethylepropylphenylamine, ethylbutylnaphthylamine, etc.), alkyldiarylamine groups (e.g. methyldiphenylamino, ethyldiphenylamino, etc), and triarylamino groups (e.g., triphenyl amino, trinaphthylamino, etc)) connected by a central bridging group. An example of charge transport compounds are those having the following generic formula: (R-Q)n-Y  Formula I wherein R is selected from the group consisting of julolidine ring groups, carbazole ring groups, and and (N,N-disubstituted)arylamine groups; Q comprises an aromatic hydrazone linking group, such as 1 Y comprises a bridging group between R-Q- groups, such as a bond, carbon atom, nitrogen atom, oxygen atom, sulfur atom, a methylene group; Z is an aryl group, preferably a phenyl group or naphthyl group; X is a linking group, preferably a methylene group, and for example having the formula —(CH 2 ) m — (branched or linear), where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by an oxygen atom, a carbonyl group, urethane, urea, an ester group, a —NR 6 group, a CHR 7 group, or a CR 8 R 9 group where R 6 , R 7 , R 8 , and R 9 are, independently, H, an alkyl group, or aryl group; and n is an integer between 2 and 6, inclusive. An organic photoreceptor includes that compound and (b) a charge generating compound; and (c) an electrically conductive substrate.

  描述了一种具有多个醛肼桥联杂环基团（尤其是茱萸啉基团、咔唑基团、三芳基胺基团和（N，N-二取代）芳胺基团，例如二芳基胺基团（例如二甲基苯胺；甲基乙基苯胺、二丙基苯胺、乙基丙基苯胺、乙基丁基萘胺等）、烷基二芳基胺基团（例如甲基二苯胺基、乙基二苯胺基等）和三芳基胺基团（例如三苯基氨基、三萘基氨基等））的电荷传输化合物，它们由中心桥接基团连接。电荷传输化合物的一个例子是具有以下通用式的化合物：（R-Q）n-Y Formula I，其中R选自茱萸啉环基团、咔唑环基团和（N，N-二取代）芳胺基团的群体；Q包括芳香醛肼连接基团，例如1；Y包括连接R-Q-基团的桥接基团，例如键、碳原子、氮原子、氧原子、硫原子、亚甲基基团；Z是芳基团，优选为苯基或萘基；X是连接基团，优选为亚甲基基团，例如具有公式—（CH2）m—（支链或直链），其中m是0到20之间的整数，包括，其中一个或多个亚甲基基团可选择地被氧原子、羰基、脲、尿素、酯基、—NR6基团、CHR7基团或CR8R9基团（其中R6、R7、R8和R9独立地为H、烷基或芳基）所替代；n是2到6之间的整数。有机光感受器包括该化合物和（b）电荷生成化合物；以及（c）电导基板。
• Charge transport compound, elctrophotographic organophotoreceptor comprising the same, and electrographic imaging apparatus and method
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：EP1202120A2

  公开（公告）日：2002-05-02

  A charge transport compound having hydrazone-bridged heterocyclic groups connected by a central bridging group, and an organophotoreceptor including the same are provided. The charge transport compound has formula (1) below:         (R-Q)n-Y     (1) where R is selected from the group consisting of julolidine ring groups, carbazole ring groups, and triarylmethane ring groups; Q is an aromatic hydrazone linking group having the following formula: where Z is an aromatic group, preferably a C6 to C20 aryl group, and X is a linking group, Y, a bridging group between R-Q- groups, is a chemical bond, carbon atom, nitrogen atom, oxygen atom, sulfur atom, a branched or linear-(CH2)p- group where p is an integer from 0 to 10, a C6-C20 aryl group, a C5-C20 cycloalkyl group, a cyclosiloxyl group, a heterocyclic group, or a CR10 group where R10 is hydrogen atom, a C1-C20 alkyl group, or a C6-C20 aryl group, and n is an integer from 2 to 6. The organophotoreceptor includes the charge transport compound, a charge generating compound, and a conductive substrate.

  本研究提供了一种电荷传输化合物，该化合物具有通过中心桥接基团连接的肼桥接杂环基团，并提供了包括该化合物的有机光感受器。电荷传输化合物具有下式（1）： (R-Q)n-Y (1) 其中，R 选自由唑环基团、咔唑环基团和三芳基甲烷环基团组成的组；Q 是具有下式的芳香族腙连接基团： 其中 Z 是芳香基团，最好是 C6 至 C20 芳基，X 是连接基团，Y 是 R-Q- 基团间的桥接基团，是化学键、碳原子、氮原子、氧原子、硫原子、支链或线性-(CH2)p-基团，其中 p 是 0 至 10 的整数、C6-C20 芳基、C5-C20 环烷基、环硅氧基、杂环基或 CR10 基团，其中 R10 为氢原子、C1-C20 烷基或 C6-C20 芳基，且 n 为 2 至 6 的整数。有机光感受器包括电荷传输化合物、电荷产生化合物和导电基底。
• Electrophotographic organophotoreceptors with charge transport compounds
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP1482378A1

  公开（公告）日：2004-12-01

  The present invention provides charge transport compounds that have a multiple number of hydrazone-bridged heterocyclic groups (especially julolidine groups, carbazole groups, triarylamine groups and (N,N-disubstituted)arylamine groups such as dialkarylamine groups (e.g. dimethylphenylamine; methylethylphenylamine, dipropylphenylamine, ethylepropylphenylamine, ethylbutylnaphthylamine, etc.), alkyldiarylamine groups (e.g. methyldiphenylamino, ethyldiphenylamino, etc), and triarylamino groups (e.g., triphenyl amino, trinaphthylamino, etc)) connected by a central bridging group. An example of charge transport compounds are those having the following generic formula:         (R-Q)n-Y     (I) wherein R is selected from the group consisting of julolidine ring groups, carbazole ring groups, and and (N,N-disubstituted)arylamine groups; Q comprises an aromatic hydrazone linking group, such as Y comprises a bridging group between R-Q- groups, such as a bond, carbon atom, nitrogen atom, oxygen atom, sulfur atom, a methylene group; Z is an aryl group, preferably a phenyl group or naphthyl group; X is a linking group, preferably a methylene group, and for example having the formula         -(CH2)m- (branched or linear), where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by an oxygen atom, a carbonyl group, urethane, urea, an ester group, a -NR6 group, a CHR7 group, or a CR8R9 group where R6 , R7, R8, and R9 are, independently, H, an alkyl group, or aryl group; and n is an integer between 2 and 6, inclusive. An organic photoreceptor includes that (a) a charge transport compound and (b) a charge generating compound; and (c) an electrically conductive substrate. Corresponding electrophotographic apparatuses and imaging methods are also described.

  本发明提供了具有多个肼桥杂环基团（特别是久洛尼定基团、咔唑基团、三芳胺基团和(N,N-二取代)芳基胺基团，如二芳基胺基团（e.如二甲基苯胺、甲基乙基苯胺、二丙基苯胺、乙基丙基苯胺、乙基丁基萘胺等）、烷基二苯胺基团（如甲基二苯基氨基、乙基二苯基氨基等）和三芳基氨基基团（如三苯基氨基、三萘基氨基等）、三苯基氨基、三萘氨基等））通过中心桥基连接。电荷传输化合物的一个例子是具有以下通式的化合物： (R-Q)n-Y (I) 其中 R 选自由唑环基团、咔唑环基团和（N,N-二取代）芳胺基团组成的组； Q 包括芳香族腙连接基团，如 Y 包括 R-Q- 基团间的桥接基团，如键、碳原子、氮原子、氧原子、硫原子、亚甲基； Z 是芳基，最好是苯基或萘基； X 是连接基团，最好是亚甲基，例如具有以下式子 -(CH2)m- (支链或线性)，其中 m 是 0 至 20 之间的整数，一个或多个亚甲基可选地被氧原子、羰基、氨基甲酸酯、脲、酯基、-NR6 基团、CHR7 基团或 CR8R9 基团取代，其中 R6、R7、R8 和 R9 独立地为 H、烷基或芳基；以及 n 是 2 至 6 之间的整数。有机光感受器包括 (a) 电荷传输化合物和 (b) 电荷产生化合物；以及 (c) 导电基底。还描述了相应的电致发光装置和成像方法。
• Electrophotographic organophotoreceptors with change transport compounds
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP1553457A2

  公开（公告）日：2005-07-13

  The present invention provides charge transport compounds that have a multiple number of hydrazone-bridged (N,N-disubstituted)arylamine groups connected by a central bridging group. Examples of charge transport compounds of this invention are those having the following generic formula:         (R-Q)n-Y    where R is an (N,N-disubstituted)arylamine group;    Q comprises an aromatic hydrazone linking group;    Y comprises a bridging group between R-Q- groups; and n is an integer between 2 and 6. An organic photoreceptor includes (a) that compound and (b) a charge generating compound; and (c) an electrically conductive substrate. Corresponding electrophotographic apparatuses and imaging methods (processes) are described.

  本发明提供的电荷传输化合物具有多个由中心桥接基团连接的肼桥接（N,N-二取代）芳胺基团。本发明电荷传输化合物的例子包括具有以下通式的化合物： (R-Q)n-Y 其中 R 为(N,N-二取代)芳胺基团； Q 包括一个芳香族腙连接基团； Y 包括 R-Q- 基团之间的桥接基团；以及 n 是 2 至 6 之间的整数。 有机光感受器包括 (a) 该化合物和 (b) 产生电荷的化合物；以及 (c) 导电基底。描述了相应的电致发光装置和成像方法（过程）。
• Studien �ber 1,4- und 1,5-Oxidoverbindungen
  作者：Adolf Franke、Alfred Kroupa、Otto Schmid

  DOI：10.1007/bf01518111

  日期：1935.12