2-(2-Methoxyethoxy)-5-nitrobenzenesulfonyl chloride | 69920-06-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(2-Methoxyethoxy)-5-nitrobenzenesulfonyl chloride
• CAS: 69920-06-5
• 化学式: C₉H₁₀ClNO₆S
• mdl: MFCD10693048
• 分子量: 295.701
• InChiKey: ZUHJONSUZIRGOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.333
• 拓扑面积：
  107
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2-(2-Methoxyethoxy)-5-nitrobenzenesulfonyl chloride 在 manganese(IV) oxide 、 sodium hydroxide 作用下， 以 甲醇 、 丙酮 为溶剂， 反应 1.67h， 生成 N-(4-tert-butyl-3-hexadecoxy-3-methoxy-6-oxocyclohexa-1,4-dien-1-yl)-2-(2-methoxyethoxy)-5-nitrobenzenesulfonamide
  参考文献：
  名称：

  Synthesis and reactions of o-benzoquinone monosulfonimides

  摘要：

  DOI：

  10.1021/jo00150a008
• 作为产物：
  描述：

  2-chloro-5-nitrobenzenesulphonic acid sodium salt 在 sodium oxide 、 sodium hydroxide 、 三氯氧磷 作用下， 以 环丁砜 、 乙腈 为溶剂， 反应 3.67h， 生成 2-(2-Methoxyethoxy)-5-nitrobenzenesulfonyl chloride
  参考文献：
  名称：

  A Convenient Preparation of Arenesulfonyl Chlorides from the Sodium Sulfonates and Phosphoryl Chloride/ Sulfolane

  摘要：

  DOI：

  10.1055/s-1982-29823

文献信息

• 2-Alkoxyalkoxy-5-nitrobenzenesulfonic acid and salt thereof
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04246414A1

  公开（公告）日：1981-01-20

  A 2-alkoxyalkoxy-5-nitrobenzenesulfonic acid or a salt thereof represented by the following general formula (I): ##STR1## wherein R.sup.1 represents an alkylene group having 2 or more carbon atoms; R.sup.2 represents an alkyl group; and M represents an inorganic or organic cation. The compound represented by the general formula (I) is useful as an intermediate for a dye releasing redox compound which is suitable for use in the color diffusion transfer process.

  2-烷氧基烷氧基-5-硝基苯磺酸的或其盐，其由以下通式(I)表示：##STR1## 其中，R1代表具有2个或更多碳原子的烷基；R2代表烷基；M代表无机或有机阳离子。由通式(I)表示的化合物作为染料释放氧化还原化合物的中间体很有用，该氧化还原化合物适用于彩色扩散转移过程。
• 2-Alkoxyalkoxy-5-aminobenzenesulfonic acid
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04233237A1

  公开（公告）日：1980-11-11

  A 2-alkoxyalkoxy-5-aminobenzenesulfonic acid represented by the following general formula (I): ##STR1## wherein R.sup.1 represents an alkylene group having 2 or more carbon atoms; and R.sup.2 represents an alkyl group. The compound can be used as an intermediate in the production of a dye releasing redox compound.

  以下是通式（I）所代表的2-烷氧基烷氧基-5-氨基苯磺酸：##STR1## 其中，R1代表具有2个或更多碳原子的烷基；而R2代表烷基。该化合物可用作染料释放氧化还原化合物的生产中间体。
• Photographic light-sensitive sheet for the color diffusion transfer
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04268624A1

  公开（公告）日：1981-05-19

  A photographic light-sensitive sheet for the color diffusion transfer process which comprises a support having thereon at least one light-sensitive silver halide emulsion layer having associated therewith a dye image providing material represented by the following general formula: ##STR1## wherein Q.sup.1 represents a hydrogen atom, a halogen atom, a sulfamoyl group represented by the formula --SO.sub.2 NR.sup.3 R.sup.4 wherein R.sup.3 represents a hydrogen atom or an alkyl group; R.sup.4 represents a hydrogen atom or an alkyl group, an aralkyl group or an aryl group; and R.sup.3 and R.sup.4 may combine directly or through an oxygen atom to form a ring; a group represented by the formula --SO.sub.2 R.sup.5 wherein R.sup.5 represents an alkyl group or a benzyl group; a carboxy group, a group represented by the formula --COOR.sup.6 wherein R.sup.6 represents an alkyl group, a phenyl group or a substituted phenyl group or a group represented by the formula --CONR.sup.3 R.sup.4 wherein R.sup.3 and R.sup.4 each has the same meaning as defined above; Q.sup.2 is positioned at the 5- or the 8-position to the hydroxy group and represents a hydroxy group, a group represented by the formula --NHCOR.sup.4a or a group represented by the formula --NHSO.sub.2 R.sup.4a wherein R.sup.4a has the same meaning as R.sup.4 defined above, except for the absence of a hydrogen atom; R.sup.1a represents an alkylene group having 2 or more carbon atoms; R.sup.2a represents an alkyl group; Y represents a moiety which releases or provides, as a result of development processing under alkaline conditions, an azo dye having a different diffusibility from that of said dye image-providing material; m is 0 or 1; q is 0 or 1; J represents a divalent group selected from a sulfonyl group and a carbonyl group; Z represents a hydrogen atom, an alkyl group or a substituted alkyl group; X.sup.1 represents a divalent bonding group represented by the formula --A.sub. 1 --(L).sub.n --(A.sub.2).sub.p -- wherein A.sub.1 and A.sub.2 are the same or different and each represents an alkylene group or an arylene group; L represents a divalent group selected from an oxy group, a carbonyl group, a carboxyamido group, a carbamoyl group, a sulfonamido group, a sulfamoyl group, a sulfinyl group and a sulfonyl group, and n and p each represents 0 or 1; and G represents a hydroxyl group, a salt thereof, or a hydrolyzable acyloxy group represented by the formula ##STR2## wherein E represents an alkyl group, a substituted alkyl group or an aryl group. The compound is a dye image providing material which provides a magenta dye image having superior properties.

  一种用于彩色扩散转移过程的摄影感光片，其包括支撑体，其上至少有一个与之相关联的染料图像提供物的感光银卤化物乳剂层，所述染料图像提供物由以下通式表示：##STR1##其中Q1表示氢原子、卤原子、由式--SO.sub.2 NR.sup.3 R.sup.4表示的磺酰胺基团，其中R.sup.3表示氢原子或烷基；R.sup.4表示氢原子、烷基、芳基烷基或芳基基团；R.sup.3和R.sup.4可以直接或通过氧原子结合形成环；由式--SO.sub.2 R.sup.5表示的基团，其中R.sup.5表示烷基或苄基；羧基、由式--COOR.sup.6表示的基团，其中R.sup.6表示烷基、苯基或取代苯基；或由式--CONR.sup.3 R.sup.4表示的基团，其中R.sup.3和R.sup.4与上述定义相同；Q2位于羟基的5位或8位，表示羟基、由式--NHCOR.sup.4a表示的基团或由式--NHSO.sub.2 R.sup.4a表示的基团，其中R.sup.4a与上述定义相同，但没有氢原子；R.sup.1a表示具有2个或更多碳原子的烷基；R.sup.2a表示烷基；Y表示一种基团，在碱性条件下的显影处理后释放或提供一种与所述染料图像提供物的扩散性不同的偶氮染料；m为0或1；q为0或1；J表示选择自磺酰基和羰基的二价基团；Z表示氢原子、烷基或取代烷基；X.sup.1表示由式--A.sub.1--(L).sub.n--(A.sub.2).sub.p--表示的二价键合基团，其中A.sub.1和A.sub.2相同或不同，每个表示烷基或芳基；L表示选择自氧基、羰基、羧酰胺基团、氨基甲酰基团、磺酰胺基团、磺酰基团、亚砜基团和磺酰基团的二价基团，n和p各表示0或1；G表示羟基、其盐或由式表示的可水解酰氧基团##STR2##其中E表示烷基、取代烷基或芳基。该化合物是提供具有优越性质的品红染料图像的染料图像提供物。
• Photographic light-sensitive element for the color diffusion transfer
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04268625A1

  公开（公告）日：1981-05-19

  A photographic light-sensitive element for the color diffusion transfer process which comprises a support having thereon at least one light-sensitive silver halide emulsion layer with at least one of the silver halide emulsion layers having associated therewith a dye releasing redox compound represented by the following general formula: D-Redox Moiety wherein D represents a dye moiety and Redox Moiety represents a group represented by the following general formula (I): ##STR1## wherein X.sup.1 represents an --SO.sub.2 -- group or a --CO-- group; R.sup.1 represents an unsubstituted straight chain alkylene group having 2 or more carbon atoms or an unsubstituted branched chain alkylene group having 2 or more carbon atoms with the proviso the branched chain alkylene group is incapable of forming an acetal linkage; R.sup.2 represents an alkyl group; and Y represents an o- or p-hydroxyarylsulfamoyl group having a ballast group bonded thereto.

  一种用于彩色扩散转移过程的照相感光元素，包括一个支撑体，其上至少有一层感光银卤化物乳剂层，其中至少一个银卤化物乳剂层与下列通式所代表的染料释放氧化还原化合物相关联：D-Redox Moiety，其中D代表染料基团，Redox Moiety代表下列通式（I）所代表的基团：##STR1## 其中X1代表--SO2--基团或--CO--基团；R1代表未取代的直链烷基，其具有2个或更多个碳原子或未取代的支链烷基，其具有2个或更多个碳原子，但该支链烷基不能形成缩醛键；R2代表烷基基团；Y代表与球团基团键合的o-或p-羟基芳基磺酰基团。
• FUJITA, SHINSAKU, J. ORG. CHEM., 1983, 48, N 2, 177-183
  作者：FUJITA, SHINSAKU

  DOI：——

  日期：——