2-tert-Butyl-4,7-dihydro-1,5,6-trioxa-indene | 166757-97-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 2-tert-Butyl-4,7-dihydro-1,5,6-trioxa-indene
• 英文别名: 2-Tert-butyl-4,7-dihydrofuro[2,3-d][1,2]dioxine
• CAS: 166757-97-7
• 化学式: C₁₀H₁₄O₃
• 分子量: 182.219
• InChiKey: KHMCZYAUHJGJIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  31.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-tert-Butyl-4,7-dihydro-1,5,6-trioxa-indene 生成 5-tert-Butyl-furan-2,3-dicarbaldehyde 、 [5-Tert-butyl-2-(hydroxymethyl)furan-3-yl]methanol 、 5-tert-Butyl-2-hydroxymethyl-furan-3-carbaldehyde 、 5-tert-Butyl-3-hydroxymethyl-furan-2-carbaldehyde
  参考文献：
  名称：

  Reaction of Furan-Based o-Quinodimethanes with Triplet Oxygen. Formation of Cyclic Peroxides,1

  摘要：

  Formation of cyclic peroxides 2a, 2b, and 2c from the reactions of 2,3-dimethylene-2,3-dihydrofuran (1a) and the 5-methyl (1b) and 5-tert-butyl (1c) derivatives with triplet oxygen is reported. Thermolysis of cyclic peroxide 2c gives dialdehyde 5, hydroxy aldehydes 6 and 7, and diol 8 as products.

  DOI：

  10.1021/jo00122a024
• 作为产物：
  描述：

  (5-tert-Butyl-2-methyl-3-furyl)methyl benzoate 在 氧气 作用下， 以 二硫化碳 、 氘代氯仿 为溶剂， 反应 3.0h， 生成 2-tert-Butyl-4,7-dihydro-1,5,6-trioxa-indene
  参考文献：
  名称：

  Reaction of Furan-Based o-Quinodimethanes with Triplet Oxygen. Formation of Cyclic Peroxides,1

  摘要：

  Formation of cyclic peroxides 2a, 2b, and 2c from the reactions of 2,3-dimethylene-2,3-dihydrofuran (1a) and the 5-methyl (1b) and 5-tert-butyl (1c) derivatives with triplet oxygen is reported. Thermolysis of cyclic peroxide 2c gives dialdehyde 5, hydroxy aldehydes 6 and 7, and diol 8 as products.

  DOI：

  10.1021/jo00122a024

文献信息

• Reaction of Furan-Based o-Quinodimethanes with Triplet Oxygen. Formation of Cyclic Peroxides,1
  作者：Chin-Hsing Chou、Walter S. Trahanovsky

  DOI：10.1021/jo00122a024

  日期：1995.9

  Formation of cyclic peroxides 2a, 2b, and 2c from the reactions of 2,3-dimethylene-2,3-dihydrofuran (1a) and the 5-methyl (1b) and 5-tert-butyl (1c) derivatives with triplet oxygen is reported. Thermolysis of cyclic peroxide 2c gives dialdehyde 5, hydroxy aldehydes 6 and 7, and diol 8 as products.