2-azido-4'-methyl-1,1'-biphenyl | 1140969-84-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-azido-4'-methyl-1,1'-biphenyl
• 英文别名: 1-Azido-2-(4-methylphenyl)benzene
• CAS: 1140969-84-1
• 化学式: C₁₃H₁₁N₃
• 分子量: 209.25
• InChiKey: ZPAFJACHQCZLHE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  14.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-azido-4'-methyl-1,1'-biphenyl 以 四氢呋喃 为溶剂， 反应 4.0h， 以88%的产率得到2-甲基咔唑
  参考文献：
  名称：

  光化学分子内胺化反应合成杂环

  摘要：

  可以在良好地形成优异的产率多环杂环通过在连续流动反应器中的LED紫色辐射下相应的取代的芳基叠氮化的光化学转化。该实验装置可耐受紫外线敏感的官能团，同时在较短的反应时间内即可提供多种咔唑以及吲哚和吡咯骨架。推测光化学方法是通过与涉及过渡金属催化的叠氮化物活化的其他方法不同的机理来进行的。

  DOI：

  10.1039/c7gc02261a
• 作为产物：
  描述：

  4-甲基-联苯-2-胺 在 溶剂黄146 、 sodium nitrite 、 sodium azide 作用下， 以 水 为溶剂， 反应 2.0h， 以79%的产率得到2-azido-4'-methyl-1,1'-biphenyl
  参考文献：
  名称：

  光化学分子内胺化反应合成杂环

  摘要：

  可以在良好地形成优异的产率多环杂环通过在连续流动反应器中的LED紫色辐射下相应的取代的芳基叠氮化的光化学转化。该实验装置可耐受紫外线敏感的官能团，同时在较短的反应时间内即可提供多种咔唑以及吲哚和吡咯骨架。推测光化学方法是通过与涉及过渡金属催化的叠氮化物活化的其他方法不同的机理来进行的。

  DOI：

  10.1039/c7gc02261a

文献信息

• Continous process and system for producing polymers maleic anhydride & certain alpha-olefins
  申请人：S.C. JOHNSON & SON, INC.

  公开号：EP0303057A2

  公开（公告）日：1989-02-15

  A continuous process and system for producing a polymer comprising maleic anhydride and alpha-olefin monomeric units is disclosed. The process comprises combining monomeric reactants comprising the maleic anhydride and the alpha-olefin, in the presence of a minimal effective amount of a solvent, to produce a polymerizable reaction mixture. The solvent is present in minimal amounts, namely, at about 2 to about 9 weight percent, based upon the weight of the reaction mixture. The polymerizable reaction mixture is heated; and at least one thermally-decomposable initiator is added to the thus-heated, polymerizable reaction mixture to initiate the polymerization reaction. The presence of the initiator causes the maleic anhydride and the alpha-olefin to polymerize, thereby producing the desired polymer. An effective additional amount of the monomeric reactants as well as an additional effective amount of solvent, are controllably and substantially continuously added to the reaction mixture, for maintaining the desired polymerization reaction. The produced polymer is therafter continuously removed from the reaction mixture.

  本发明公开了一种生产包含马来酸酐和α-烯烃单体单元的聚合物的连续工艺和系统。该工艺包括在最低有效量的溶剂存在下，将包含马来酸酐和α-烯烃的单体反应物结合在一起，生成可聚合反应混合物。溶剂的用量极少，即以反应混合物的重量为基准，约为 2 至 9 重量百分比。加热可聚合反应混合物，并向加热的可聚合反应混合物中加入至少一种热分解引发剂，以引发聚合反应。引发剂的存在使马来酸酐和α-烯烃发生聚合反应，从而生成所需的聚合物。将有效量的额外单体反应物和有效量的额外溶剂可控地持续添加到反应混合物中，以维持所需的聚合反应。之后，从反应混合物中连续除去生成的聚合物。
• Process for preparing oligomeric copolymers of the pibsa-type in specific solvents
  申请人：CHEVRON U.S.A. INC.

  公开号：EP0644208A2

  公开（公告）日：1995-03-22

  A process for preparing an oligomeric copolymer of an unsaturated acidic reactant and a high molecular weight olefin having a sufficient number of carbon atoms such that the resulting copolymer is soluble in lubricating oil and wherein at least 20 weight percent of the total olefin comprises an alkylvinylidene isomer, which process comprises reacting the high molecular weight olefin with the unsaturated acidic reactant in the presence of a free radical initiator and a solvent selected from: (a) polyisobutenyl succinic anhydride (PIBSA), (b) polyPIBSA, or (c) a mixture comprising polyisobutene and a copolymer prepared by reacting a high molecular weight olefin, wherein at least 20 weight percent of the total olefin comprises an alkylvinylidene isomer, and an unsaturated acidic reactant in the presence of a free radical initiator.

  一种制备不饱和酸性反应物与高分子量烯烃的低聚物共聚物的工艺，高分子量烯烃具有足够数量的碳原子，使所得到的共聚物可溶于润滑油，其中烯烃总量的至少 20 重量％由亚烷基乙烯基异构体组成，该工艺包括在自由基引发剂和选自下列物质的溶剂存在下，使高分子量烯烃与不饱和酸性反应物反应： (a) 聚异丁烯基丁二酸酐 (PIBSA)、 (b) 聚异丁烯基丁二酸酐（PIBSA），或 (c) 由聚异丁烯和一种共聚物组成的混合物，该共聚物是在自由基引发剂存在 下，通过使一种高分子量烯烃（其中至少 20%的烯烃总重量由一种亚烷基 乙烯异构体组成）和一种不饱和酸性反应物发生反应而制备的。
• Post-treated dispersants
  申请人：ETHYL PETROLEUM ADDITIVES LIMITED

  公开号：EP0733697A1

  公开（公告）日：1996-09-25

  Oil soluble dispersants suitable for incorporation into lubricating oils and having improved compatibility with fluoroelastomers are made by reacting a polyamine with a terpolymeric acylating agent derived from a high molecular weight polyolefin containing at least 30% of terminal vinylidene radicals, an α-olefin of up to 28 carbon atoms, and an unsaturated acidic reactant, followed by post-treatment with at least one post-treating agent.

  适用于掺入润滑油且与氟橡胶的兼容性更好的油溶性分散剂是通过以下方法制成的：将多胺与一种三元共聚酰化剂反应，该酰化剂来源于一种含有至少 30% 乙烯基末端基的高分子量聚烯烃、一种碳原子数不超过 28 个的α-烯烃和一种不饱和酸性反应剂，然后用至少一种后处理剂进行后处理。
• Lubricating oil dispersants
  申请人：ETHYL PETROLEUM ADDITIVES LIMITED

  公开号：EP0733696A1

  公开（公告）日：1996-09-25

  Oil soluble dispersants suitable for incorporation into lubricating oils and having improved compatibility with fluoroelastomers are made by reacting a polyamine with a terpolymeric acylating agent derived from a high molecular weight polyolefin containing at least 30% of terminal vinylidene radicals, an α-olefin of up to 28 carbon atoms, and an unsaturated acidic reactant, the polyamine being reacted initially with less than all of the terpolymeric acylating agent and then with at least one further charges of the said acylating agent.

  适用于掺入润滑油且与氟橡胶的兼容性更好的油溶性分散剂是通过以下方法制成的：将多胺与三聚酰化剂反应，三聚酰化剂来源于含有至少 30% 乙烯基末端基的高分子量聚烯烃、碳原子数不超过 28 个的α-烯烃和不饱和酸性反应剂，多胺最初与小于全部的三聚酰化剂反应，然后与至少一种上述酰化剂的进一步加料反应。
• Copolymers of atactic propene polymers, dispersants derived therefrom and lubricating oils and fuel compositions containing the dispersants
  申请人：ETHYL CORPORATION

  公开号：EP0767182A2

  公开（公告）日：1997-04-09

  A novel copolymer of an unsaturated acidic reactant and an atactic vinyl terminated propene polymer (VTPP) and its use in preparation of fuel and lubricant additives is taught. The VTPP has a major amount of polymer chains containing terminal vinyl unsaturation, a number average molecular weight of at least 500, and comprises at least 70 weight per cent propene and 0 to 30 weight per cent of at least one olefin selected from the group consisting of C2 and C4 to C10 olefins. The unsaturated acidic reactant comprises at least one unsaturated C4 to C10 carboxylic or dicarboxylic acid or anhydride. An oil soluble dispersant additive of the invention useful in oleaginous compositions is prepared by contacting the atactic VTPP copolymer with at least one nucleophilic reagent selected from the group consisting of amines, alcohols, metal reactants and mixtures thereof under conditions effective to form adducts of the nucleophilic reagent with the copolymer. The novel dispersants made from the copolymers and terpolymers of the invention can be polymeric succinic ester-amide dispersants, polymeric succinimide dispersants, polymeric succinic amide-triazole dispersants, or polymeric succinic triazole dispersants. Fuel and lubricant compositions containing such additives are a part of the invention.

  本发明涉及一种新型不饱和酸性反应剂与无机乙烯基封端丙烯聚合物（VTPP）的共聚物及其在制备燃料和润滑油添加剂中的应用。VTPP 具有大量含有乙烯基不饱和末端的聚合物链，平均分子量至少为 500，由至少 70% 的丙烯和 0-30% 的至少一种烯烃组成，这些烯烃选自由 C2 和 C4 至 C10 烯烃组成的组。不饱和酸性反应剂包括至少一种不饱和 C4 至 C10 羧酸或二羧酸或酸酐。本发明的油溶性分散剂添加剂可用于含油组合物，其制备方法是将无活性 VTPP 共聚物与至少一种亲核试剂接触，该亲核试剂选自由胺、醇、金属反应物及其混合物组成的组，接触条件应能有效地使亲核试剂与共聚物形成加合物。由本发明的共聚物和三元共聚物制成的新型分散剂可以是聚合琥珀酸酯-酰胺分散剂、聚合琥珀酰亚胺分散剂、聚合琥珀酸酰胺-三唑分散剂或聚合琥珀酸三唑分散剂。含有此类添加剂的燃料和润滑油组合物是本发明的一部分。